Nylon–MOF Composites through Postsynthetic Polymerization

Kalaj, Mark; Denny, Jr., Michael S.; Bentz, Kyle C.; Palomba, Joseph M.; Cohen, Seth M.

doi:10.1002/ange.201812655

Nylon–MOF Composites through Postsynthetic Polymerization

Journal Article · Mon Jan 21 00:00:00 EST 2019 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201812655· OSTI ID:1491432

Kalaj, Mark ^[1]; Denny, Jr., Michael S. ^[1]; Bentz, Kyle C. ^[1]; Palomba, Joseph M. ^[1]; ^[1]

Department of Chemistry and Biochemistry University of California, San Diego La Jolla CA 92093 USA

Abstract

Hybridization of metal–organic frameworks (MOFs) and polymers into composites yields materials that display the exceptional properties of MOFs with the robustness of polymers. However, the realization of MOF–polymer composites requires efficient dispersion and interactions of MOF particles with polymer matrices, which remains a significant challenge. Herein, we report a simple, scalable, bench‐top approach to covalently tethered nylon–MOF polymer composite materials through an interfacial polymerization technique. The copolymerization of a modified UiO‐66‐NH ₂ MOF with a growing polyamide fiber (PA‐66) during an interfacial polymerization gave hybrid materials with up to around 29 weight percent MOF. The covalent hybrid material demonstrated nearly an order of magnitude higher catalytic activity for the breakdown of a chemical warfare simulant (dimethyl‐4‐nitrophenyl phosphate, DMNP) compared to MOFs that are non‐covalently, physically entrapped in nylon, thus highlighting the importance of MOF–polymer hybridization.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02-08ER46519

OSTI ID:: 1491432

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 8 Vol. 131; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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