Electroless deposition of metal on 3D-printed polymeric structures

Robinson, David; Jones, Christopher G.

Electroless deposition of metal on 3D-printed polymeric structures

Patent · Tue Dec 03 00:00:00 EST 2019

OSTI ID:1600352

Robinson, David; Jones, Christopher G.

A process for metallizing a three-dimensional-printed polymeric structure includes soaking the three-dimensional-printed polymeric structure in a metal salt solution; transferring the three-dimensional polymeric structure to a solution comprising a first reducing agent; soaking the three-dimensional polymeric structure in a metal plating bath, the metal plating bath comprising a coordinating agent, a palladium or platinum salt, a pH buffer component, and a second reducing agent, to form a metal plated polymeric structure. A metal plated porous structure and an apparatus for improving metallization are also disclosed.

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Research Organization:: National Technology & Engineering Solutions of Sandia, LLC, Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

DOE Contract Number:: NA0003525

Assignee:: National Technology & Engineering Solutions of Sandia, LLC (Albuquerque, NM)

Patent Number(s):: 10,494,721

Application Number:: 15/671,345

OSTI ID:: 1600352

Country of Publication:: United States

Language:: English

References (27)

Electroless Deposition of Palladium and Platinum Ohno, Izumi Ohno Modern Electroplating, p. 477-482 https://doi.org/10.1002/9780470602638.ch20	other	October 2010
Palladium‐catalyzed electroless plating of gold on latex particle surfaces Kim, Hyungsoo; Daniels, Eric S.; Dimonie, Victoria L. Journal of Applied Polymer Science, Vol. 112, Issue 2 https://doi.org/10.1002/app.29392	journal	January 2009
3D Amino‐Induced Electroless Plating: A Powerful Toolset for Localized Metallization on Polymer Substrates Garcia, Alexandre; Berthelot, Thomas; Viel, Pascal ChemPhysChem, Vol. 12, Issue 16 https://doi.org/10.1002/cphc.201100562	journal	September 2011
Fabrication of 3D metal/polymer microstructures by site-selective metal coating Takeyasu, N.; Tanaka, T.; Kawata, S. Applied Physics A, Vol. 90, Issue 2 https://doi.org/10.1007/s00339-007-4298-9	journal	October 2007
Covalent assembly of metal nanoparticles on cellulose fabric and its antimicrobial activity Park, Sung Yong; Chung, Jae Woo; Priestley, Rodney D. Cellulose, Vol. 19, Issue 6 https://doi.org/10.1007/s10570-012-9773-6	journal	September 2012
Plating on acrylonitrile–butadiene–styrene (ABS) plastic: a review Olivera, Sharon; Muralidhara, Handanahally Basavarajaiah; Venkatesh, Krishna Journal of Materials Science, Vol. 51, Issue 8 https://doi.org/10.1007/s10853-015-9668-7	journal	January 2016
Polymer pretreatments for enhanced adhesion of metals deposited by the electroless process Charbonnier, M.; Romand, M. International Journal of Adhesion and Adhesives, Vol. 23, Issue 4 https://doi.org/10.1016/S0143-7496(03)00045-9	journal	January 2003
Process of direct copper plating on ABS plastics Gui-xiang, Wang; Ning, Li; Hui-li, Hu Applied Surface Science, Vol. 253, Issue 2 https://doi.org/10.1016/j.apsusc.2005.12.106	journal	November 2006
Electrodeposition and electroless plating of hierarchical metal superstructures composed of 1D nano- and microscale building blocks Muench, Falk; Felix, Eva-Maria; Rauber, Markus Electrochimica Acta, Vol. 202 https://doi.org/10.1016/j.electacta.2016.03.188	journal	June 2016
Electroless Pd membrane deposition on alumina modified porous Hastelloy substrate with EDTA-free bath Ryi, Shin-Kun; Xu, Nong; Li, Anwu International Journal of Hydrogen Energy, Vol. 35, Issue 6 https://doi.org/10.1016/j.ijhydene.2010.01.054	journal	March 2010
Investigations on metallization in FDM build ABS part using electroless deposition method Equbal, Azhar; Sood, Anoop Kumar Journal of Manufacturing Processes, Vol. 19 https://doi.org/10.1016/j.jmapro.2015.03.002	journal	August 2015
30 years of electroless plating for semiconductor and polymer micro-systems Shacham-Diamand, Y.; Osaka, T.; Okinaka, Y. Microelectronic Engineering, Vol. 132 https://doi.org/10.1016/j.mee.2014.09.003	journal	January 2015
Effects of process parameters on the synthesis of palladium membranes Dogan, Meltem; Kilicarslan, Saliha Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 266, Issue 15 https://doi.org/10.1016/j.nimb.2008.05.011	journal	August 2008
Influence of the polymer pre-treatment before its electroless metallization Nicolas-Debarnot, Dominique; Pascu, Mihaela; Vasile, Cornelia Surface and Coatings Technology, Vol. 200, Issue 14-15 https://doi.org/10.1016/j.surfcoat.2005.01.095	journal	April 2006
A novel surface activation method for Ni/Au electroless plating of acrylonitrile–butadiene–styrene Tang, Xuejiao; Wang, Jingang; Wang, Chengjun Surface and Coatings Technology, Vol. 206, Issue 6 https://doi.org/10.1016/j.surfcoat.2011.08.064	journal	December 2011
Simple, Benign, Aqueous-Based Amination of Polycarbonate Surfaces VanDelinder, Virginia; Wheeler, David R.; Small, Leo J. ACS Applied Materials & Interfaces, Vol. 7, Issue 10 https://doi.org/10.1021/am508797h	journal	March 2015
Binding catalytic sites to the surface of porous polymers and some catalytic applications Ruckenstein, E.; Hong, L. Chemistry of Materials, Vol. 4, Issue 1 https://doi.org/10.1021/cm00019a026	journal	January 1992
Route to Three-Dimensional Metallized Microstructures Using Cross-Linkable Epoxide SU-8 Chen, Yun-Sheng; Tal, Amir; Kuebler, Stephen M. Chemistry of Materials, Vol. 19, Issue 16 https://doi.org/10.1021/cm0710812	journal	August 2007
Selective Functionalization of 3-D Polymer Microstructures Farrer, Richard A.; LaFratta, Christopher N.; Li, Linjie Journal of the American Chemical Society, Vol. 128, Issue 6 https://doi.org/10.1021/ja0583620	journal	February 2006
Dendrimer-Mediated Immobilization of Catalytic Nanoparticles on Flat, Solid Supports Sun, Li; Crooks, Richard M. Langmuir, Vol. 18, Issue 21 https://doi.org/10.1021/la020498d	journal	September 2002
Electroless plating of polymers: XPS study of the initiation mechanisms Charbonnier, M.; Alami, M.; Romand, M. Journal of Applied Electrochemistry, Vol. 28, Issue 4, p. 449-453 https://doi.org/10.1023/A:1003204909001	journal	March 1998
Multiscale metallic metamaterials Zheng, Xiaoyu; Smith, William; Jackson, Julie Nature Materials, Vol. 15, Issue 10 https://doi.org/10.1038/nmat4694	journal	July 2016
Ultralight Metallic Microlattices Schaedler, T. A.; Jacobsen, A. J.; Torrents, A. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1211649	journal	November 2011
Barrel Plating by Means of Electroless Palladium Rhoda, R. N. Journal of The Electrochemical Society, Vol. 108, Issue 7 https://doi.org/10.1149/1.2428193	journal	January 1961
Electroless Metallization of Stereolithographic Photocurable Resins for 3D Printing of Functional Microdevices Bernasconi, R.; Credi, C.; Tironi, M. Journal of The Electrochemical Society, Vol. 164, Issue 5 https://doi.org/10.1149/2.0081705jes	journal	January 2017
Electroless Plating of NiP and Cu on Polylactic Acid and Polyethylene Terephthalate Glycol-Modified for 3D Printed Flexible Substrates Bernasconi, R.; Natale, G.; Levi, M. Journal of The Electrochemical Society, Vol. 163, Issue 9 https://doi.org/10.1149/2.1201609jes	journal	January 2016
Efficient and Continuous Decomposition of Hydrogen Peroxide Using a Silica Capillary Coated with a Thin Palladium or Platinum Layer Javaid, Rahat; Qazi, Umair Yaqub; Kawasaki, Shin-Ichiro Bulletin of the Chemical Society of Japan, Vol. 88, Issue 7 https://doi.org/10.1246/bcsj.20150052	journal	July 2015

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