Product branching ratios of the NH({sup 3}{Sigma}{sup -}) + NO and NH({sup 3}{Sigma}{sup -}) + NO{sub 2} reactions
Journal Article
·
· Journal of Physical Chemistry
- North Dakota State Univ., Fargo, ND (United States)
The title reactions were studied at 298 K using time-resolved infrared diode laser spectroscopy. For the NH ({sup 3}{Sigma}{sup -}) + NO reaction, N{sub 2}O + H were found to be the primary products, with a branching ratio of 0.77 {+-} 0.08, in good agreement with other recent measurements. For the NH ({sup 3} {Sigma}{sup -}) + NO{sub 2} reaction, the measured branching ratio was 0.41 {+-} 0.15 into the N{sub 2}O + OH channel and 0.59 {+-} 0.15 into the NO + HNO channel. 45 refs., 5 figs., 3 tabs.
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- FG06-93ER14390
- OSTI ID:
- 159679
- Journal Information:
- Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 46 Vol. 99; ISSN JPCHAX; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
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