Structural Evolution During Perovskite Crystal Formation and Degradation: In Situ and Operando X–Ray Diffraction Studies

Mundt, Laura E.; Schelhas, Laura T.

doi:10.1002/aenm.201903074

Title: Structural Evolution During Perovskite Crystal Formation and Degradation: In Situ and Operando X–Ray Diffraction Studies

Journal Article · Mon Nov 25 00:00:00 EST 2019 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201903074· OSTI ID:1596308

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SLAC National Accelerator Lab., Menlo Park, CA (United States)

This review provides an update on the progress in understanding formation and degradation mechanisms in halide perovskites for photovoltaic applications, as supported by in situ and operando X–ray scattering techniques. The value of these real–time analyses is particularly high for gaining insights into the structural evolution during crystal formation and decomposition upon exposure to external stress factors. This type of analysis reveals the pathways between starting and end points of a process rather than being limited to comparing states before and after the process. Special attention is put on the successful efforts toward upscaling including deposition techniques that are compatible to roll–to–roll processing. These processes are realized using fast annealing procedures. The development of these processes strongly benefited from in situ studies exploring the direct transition from precursor to perovskite without going through observable crystalline intermediate phases. A particular focus of this review is the benefit of using in situ and operando X–ray scattering techniques to better understand and ultimately improve device stability. In conclusion, the difference between structural stability of thin films and structural stability under device operation is highlighted, convincingly demonstrating the indispensability of operando studies.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office

Grant/Contract Number:: AC02-76SF00515; AC36‐08‐GO28308

OSTI ID:: 1596308

Alternate ID(s):: OSTI ID: 1575780

Journal Information:: Advanced Energy Materials, Vol. 10, Issue 26; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 26 works

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Journal Article · Mon Mar 04 00:00:00 EST 2019 · Energy & Environmental Science · OSTI ID:1596308

Schelhas, Laura T.; Li, Zhen; Christians, Jeffrey A.; +9 more

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36 MATERIALS SCIENCE
halide perovskites
in situ
X‐ray scattering

Title: Structural Evolution During Perovskite Crystal Formation and Degradation: In Situ and Operando X–Ray Diffraction Studies

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