Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

A dual-layer structure with record-high solar reflectance for daytime radiative cooling

Journal Article · · Solar Energy
 [1];  [2];  [2]
  1. Georgia Inst. of Technology, Atlanta, GA (United States); Georgia Institute of Technology
  2. Georgia Inst. of Technology, Atlanta, GA (United States)
We demonstrate a diffusive solar reflector with record high reflectance when integrated over the wavelength region from 0.28-4.0 μm. The reflector has a dual-layer structure consisting of a polytetrafluoroethylene (PTFE) sheet on top of a silver film. The thickness of the PTFE varies from 0.25 mm to 1 mm. Spectral reflectance and transmittance of the PTFE sheets (with and without a silver film) were measured using a monochromator and a Fourier-transform infrared spectrometer, with integrating spheres, at wavelengths from 0.28 μm to 15 μm. The scattering and absorption coefficients of the PTFE samples were obtained by fitting the reflectance and transmittance spectra. Integration over the solar irradiation spectrum (AM1.5) reveals that the total solar reflectance is approximately 0.99 for the reflector. This is the highest solar reflectance reported to date. A Monte Carlo ray-tracing method and a modified two-flux model were used to calculate the reflectance and compare with the experiments to shed light on mechanisms for the high reflectance. Our measurements also suggest that PTFE has a high emittance around 0.9 in the mid-infrared region. Therefore, we conclude the proposed structure holds promise for passive daytime radiative cooling.
Research Organization:
Georgia Inst. of Technology, Atlanta, GA (United States)
Sponsoring Organization:
National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
SC0018369
OSTI ID:
1594763
Alternate ID(s):
OSTI ID: 1693670
Journal Information:
Solar Energy, Journal Name: Solar Energy Journal Issue: C Vol. 169; ISSN 0038-092X
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (31)

A Subambient Open Roof Surface under the Mid-Summer Sun journal May 2015
Radiative Cooling: Principles, Progress, and Potentials journal February 2016
Measurement and Modeling of the Emittance of Silicon Wafers with Anisotropic Roughness journal May 2007
Radiative Properties of Ceramic $$\hbox {Al}_{2}\hbox {O}_{3}$$, AlN, and $$\hbox {Si}_{3}\hbox {N}_{4}$$: I. Experiments journal May 2016
Radiative Properties of Ceramic $$\hbox {Al}_{2}\hbox {O}_{3}$$, AlN and $$\hbox {Si}_{3}\hbox {N}_{4}$$—II: Modeling journal June 2017
The radiative cooling of selective surfaces journal May 1975
Radiative cooling of TiO2 white paint journal January 1978
Characteristics of infrared sky radiation in the United States journal January 1984
Radiative cooling efficiency of white pigmented paints journal June 1993
MCML—Monte Carlo modeling of light transport in multi-layered tissues journal July 1995
Radiative cooling during the day: simulations and experiments on pigmented polyethylene cover foils journal April 1995
Thermal performance of radiative cooling panels journal June 1983
Infrared ellipsometric determination of the optical constants of polytetrafluoroethylene journal December 2003
Nanoparticle embedded double-layer coating for daytime radiative cooling journal January 2017
Radiative cooling as low-grade energy source: A literature review journal September 2017
The effects of particle size distribution on the optical properties of titanium dioxide rutile pigments and their applications in cool non-white coatings journal November 2014
Double-layer nanoparticle-based coatings for efficient terrestrial radiative cooling journal August 2017
Daytime Radiative Cooling Using Near-Black Infrared Emitters journal February 2017
Passive radiative cooling below ambient air temperature under direct sunlight journal November 2014
Radiative cooling to deep sub-freezing temperatures through a 24-h day–night cycle journal December 2016
Radiation Through a Foggy Atmosphere journal January 1905
Optical Properties of Ag and Cu journal November 1962
Optical Constants of the Noble Metals journal December 1972
Optical properties of Teflon® AF amorphous fluoropolymers journal July 2008
Light scattering of semitransparent sintered polytetrafluoroethylene films journal January 2008
Scalable-manufactured randomized glass-polymer hybrid metamaterial for daytime radiative cooling journal February 2017
Radiative cooling computed for model atmospheres journal January 1982
Determining the optical properties of turbid media by using the adding–doubling method journal January 1993
Optical constants of Cu, Ag, and Au revisited journal January 2015
Reflection properties of pressed polytetrafluoroethylene powder journal January 1981
Modified two-flux approximation for identification of radiative properties of absorbing and scattering media from directional-hemispherical measurements journal January 2006

Cited By (4)

Highly effective photon-to-cooling thermal device journal December 2019
Radiative sky cooling: Fundamental principles, materials, and applications journal June 2019
High-performance subambient radiative cooling enabled by optically selective and thermally insulating polyethylene aerogel journal October 2019
Metamaterial-Based Radiative Cooling: Towards Energy-Free All-Day Cooling journal December 2018

Similar Records

Bidirectional reflection of semitransparent polytetrafluoroethylene (PTFE) sheets on a silver film
Journal Article · Wed Nov 13 19:00:00 EST 2019 · International Journal of Heat and Mass Transfer · OSTI ID:1594790

Dependence of polytetrafluoroethylene reflectance on thickness at visible and ultraviolet wavelengths in air
Journal Article · Mon Jul 13 00:00:00 EDT 2020 · TBD · OSTI ID:1647060

Dependence of polytetrafluoroethylene reflectance on thickness at visible and ultraviolet wavelengths in air
Journal Article · Sun Nov 22 19:00:00 EST 2020 · Journal of Instrumentation · OSTI ID:1777153