Liquid cadmium cathode performance model based on the equilibrium behaviors of U and Pu in molten LiCl–KCl/Cd system at 500°C

Fredrickson, Guy L.; Yoo, Tae -Sic

doi:10.1016/j.jnucmat.2019.151883

Title: Liquid cadmium cathode performance model based on the equilibrium behaviors of U and Pu in molten LiCl–KCl/Cd system at 500°C

Journal Article · Wed Nov 06 00:00:00 EST 2019 · Journal of Nuclear Materials

DOI:https://doi.org/10.1016/j.jnucmat.2019.151883· OSTI ID:1578276

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Idaho National Lab. (INL), Idaho Falls, ID (United States)

The liquid cadmium cathode is a pyroprocessing technology used for the recovery of group actinide metals from the molten chloride salts that support uranium electrorefining. This article presents a model for the performance of a liquid cadmium cathode based on considerations of salt/alloy equilibrium thermodynamics, Cd-U-Pu phase diagram behaviors, and mass balance constraints. In conclusion, the model demonstrates how the salt/cadmium system responds as incremental additions of uranium are made to the liquid cadmium cathode.

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Research Organization:: Idaho National Lab. (INL), Idaho Falls, ID (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE)

Grant/Contract Number:: AC07-05ID14517

OSTI ID:: 1578276

Alternate ID(s):: OSTI ID: 1580291

Report Number(s):: INL/JOU-19-54973-Rev000; TRN: US2102194

Journal Information:: Journal of Nuclear Materials, Vol. 528, Issue C; ISSN 0022-3115

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 5 works

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References (95)

Analysis and modeling of the equilibrium behaviors of U and Pu in molten LiCl-KCl/Cd system at 500 °C Fredrickson, Guy L.; Yoo, Tae-Sic Journal of Nuclear Materials, Vol. 508 https://doi.org/10.1016/j.jnucmat.2018.05.037	journal	September 2018
Prediction of a Mutual Separation of Actinide and rare Earth Groups in a Multistage Reductive Extraction System Yoo, Jae-Hyung; Lee, Han-Soo; Kim, Eung-Ho Nuclear Engineering and Technology, Vol. 39, Issue 5 https://doi.org/10.5516/NET.2007.39.5.663	journal	October 2007
Electrode reaction of the Np ³⁺ /Np couple at liquid Cd and Bi electrodes in LiCl–KCl eutectic melts Shirai, O.; Uozumi, K.; Iwai, T. Journal of Applied Electrochemistry, Vol. 34, Issue 3 https://doi.org/10.1023/B:JACH.0000015615.17281.51	journal	March 2004
The thorium-cadmium phase diagram Palenzona, A.; Cirafici, S. Journal of the Less Common Metals, Vol. 77, Issue 2 https://doi.org/10.1016/0022-5088(81)90173-9	journal	February 1981
Electrochemical Behavior of Zr on a Liquid Cd Electrode in LiCl–KCl Eutectic Melts Murakami, Tsuyoshi; Kato, Tetsuya Journal of The Electrochemical Society, Vol. 155, Issue 7 https://doi.org/10.1149/1.2912230	journal	January 2008
Distillation of cadmium from uranium–plutonium–cadmium alloy Kato, Tetsuya; Iizuka, Masatoshi; Inoue, Tadashi Journal of Nuclear Materials, Vol. 340, Issue 2-3 https://doi.org/10.1016/j.jnucmat.2004.12.002	journal	April 2005
Cadmium-neptunium a partial phase diagram of the system Krumpelt, M.; Johnson, I.; Heiberger, J. J. Journal of the Less Common Metals, Vol. 18, Issue 1 https://doi.org/10.1016/0022-5088(69)90117-9	journal	May 1969
Pyrometallurgical Reprocessing of Fast Reactor Metallic Fuel—Development of a New Electrorefiner with a Ceramic Partition Koyama, Tadafumi; Fujita, Reiko; Hzuka, Masatoshi Nuclear Technology, Vol. 110, Issue 3 https://doi.org/10.13182/NT95-A35107	journal	June 1995
A Conceptual Study of Pyroprocessing for Recovering Actinides from Spent Oxide Fuels Yoo, Jae-Hyung; Seo, Chung-Seok; Kim, Eung-Ho Nuclear Engineering and Technology, Vol. 40, Issue 7 https://doi.org/10.5516/NET.2008.40.7.581	journal	December 2008
Thermodynamic Properties of U, Np, Pu, and Am in Molten LiCl‐KCl Eutectic and Liquid Cadmium Roy, J. J.; Grantham, L. F.; Grimmett, D. L. Journal of The Electrochemical Society, Vol. 143, Issue 8 https://doi.org/10.1149/1.1837035	journal	August 1996
Performance of the mesh-type liquid cadmium cathode structure for the electrodeposition of uranium from the molten salt Paek, Seungwoo; Kim, Si-Hyung; Yoon, Dal-Sung Radiochimica Acta, Vol. 98, Issue 12 https://doi.org/10.1524/ract.2010.1778	journal	January 2010
Electrodeposition of Uranium and Transuranic Elements onto Solid Cathode in LiCl-KCl/Cd System for Pyrometallurgical Partitioning Kinoshita, Kensuke; Inoue, Tadashi; Fusselman, S. P. Journal of Nuclear Science and Technology, Vol. 40, Issue 7 https://doi.org/10.1080/18811248.2003.9715387	journal	July 2003
On the Development of a Distillation Process for the Electrometallurgical Treatment of Irradiated Spent Nuclear fuel Westphal, Brian R.; Marsden, Kenneth C.; Price, John C. Nuclear Engineering and Technology, Vol. 40, Issue 3 https://doi.org/10.5516/NET.2008.40.3.163	journal	April 2008
The partial yttrium-cadmium phase diagram Ryba, E.; Kejriwal, P. K.; Elmendorf, R. Journal of the Less Common Metals, Vol. 18, Issue 4 https://doi.org/10.1016/0022-5088(69)90011-3	journal	August 1969
Thermochemical modelling of electrotransport of uranium and plutonium in an electrorefiner Nawada, H. P.; Bhat, N. P. Nuclear Engineering and Design, Vol. 179, Issue 1 https://doi.org/10.1016/S0029-5493(97)00245-8	journal	January 1998
Thermodynamic Properties of Lanthanides and Actinides for Reductive Extraction of Minor Actinides Toda, Taro; Maruyama, Takehiro; Moritani, Kimikazu Journal of Nuclear Science and Technology, Vol. 46, Issue 1 https://doi.org/10.1080/18811248.2007.9711502	journal	January 2009
Electrochemical behaviour of terbium in the eutectic LiCl-KCl in Cd liquid electrodes.- Evaluation of the thermochemical properties of the TbCdx intermetallic compounds Castrillejo, Y.; Hernández, P.; Fernández, R. Electrochimica Acta, Vol. 147 https://doi.org/10.1016/j.electacta.2014.10.005	journal	November 2014
Behavior of plutonium and americium at liquid cadmium cathode in molten LiCl–KCl electrolyte Iizuka, Masatoshi; Uozumi, Koich; Inoue, Tadashi Journal of Nuclear Materials, Vol. 299, Issue 1 https://doi.org/10.1016/S0022-3115(01)00667-5	journal	October 2001
The Cd−Tb (Cadmium-Terbium) system Gschneidner, K. A.; Calderwood, F. W. Journal of Phase Equilibria, Vol. 9, Issue 2 https://doi.org/10.1007/BF02890548	journal	April 1988
Engineering-scale distillation of cadmium for actinide recovery Westphal, B. R.; Price, J. C.; Vaden, D. Journal of Alloys and Compounds, Vol. 444-445 https://doi.org/10.1016/j.jallcom.2007.02.072	journal	October 2007
A Study of the Thermodynamic and Reducing Properties of Lithium in Cadmium at 773 K Lewis, M. A.; Johnson, T. R. Journal of The Electrochemical Society, Vol. 137, Issue 5 https://doi.org/10.1149/1.2086683	journal	May 1990
Thermodynamic investigations in the lanthanum–cadmium system Richter, Klaus W.; Besana, Sonia; Borzone, Gabriella Journal of Alloys and Compounds, Vol. 365, Issue 1-2 https://doi.org/10.1016/S0925-8388(03)00670-4	journal	February 2004
Development of Pyro-processing Fuel Cycle Technology for Closing Actinide Cycle Koyama, T.; Sakamura, Y.; Iizuka, M. Procedia Chemistry, Vol. 7 https://doi.org/10.1016/j.proche.2012.10.117	journal	January 2012
Pyroprocessing Technology Development at Kaeri Lee, Han-Soo; Park, Geun-Il; Kang, Kweon-Ho Nuclear Engineering and Technology, Vol. 43, Issue 4 https://doi.org/10.5516/NET.2011.43.4.317	journal	August 2011
Equilibrium distribution of actinides including Cm between molten LiCl-KCl eutectic and liquid cadmium Koyama, Tadafumi; Kinoshita, Kensuke; Inoue, Tadashi Radiochimica Acta, Vol. 96, Issue 4-5 https://doi.org/10.1524/ract.2008.1492	journal	January 2008
Reductive extraction kinetics of actinide and lanthanide elements in molten chloride and liquid cadmium system Moriyama, H.; Yamada, D.; Moritani, K. Journal of Alloys and Compounds, Vol. 408-412 https://doi.org/10.1016/j.jallcom.2004.12.120	journal	February 2006
A study on the electrodeposition of uranium using a liquid cadmium cathode at 440℃ and 500℃ [440℃와 500℃에서 액체카드뮴음극을 이용한 우라늄 전착에 관한 연구] Yoon, Jong-Ho; Kim, Si-Hyung; Kim, Gha-Young Journal of the Nuclear Fuel Cycle and Waste Technology, Vol. 11, Issue 3 https://doi.org/10.7733/jnfcwt-k.2013.11.3.199	journal	September 2013
Separation behaviors of actinides from rare-earths in molten salt electrorefining using saturated liquid cadmium cathode Kato, Tetsuya; Inoue, Tadashi; Iwai, Takashi Journal of Nuclear Materials, Vol. 357, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2006.06.003	journal	October 2006
Electrochemical Behavior of Li-B Alloy Anode - Liquid Cadmium Cathode (LCC) System for Electrodeposition of Nd in LiCl-KCl Kim, Gha-Young; Shin, Jiseon; Kim, Tack-Jin Journal of the Korean Electrochemical Society, Vol. 18, Issue 3 https://doi.org/10.5229/JKES.2015.18.3.102	journal	August 2015
Thermochemical Investigations in the System Cadmium-Praseodymium Relevant for Pyrometallurgical Fuel Reprocessing Reichmann, Thomas L.; Ipser, Herbert Metallurgical and Materials Transactions A, Vol. 45, Issue 3 https://doi.org/10.1007/s11661-013-2065-4	journal	October 2013
Uranium recovery from liquid cadmium separated from the molten salt used in electrorefining Jang, Junhyuk; Kim, Tackjin; Eun, Hee-Chul Journal of Radioanalytical and Nuclear Chemistry, Vol. 318, Issue 3 https://doi.org/10.1007/s10967-018-6183-8	journal	September 2018
Actinides recovery from molten salt/liquid metal system by electrochemical methods Iizuka, Masatoshi; Koyama, Tadafumi; Kondo, Naruhito Journal of Nuclear Materials, Vol. 247 https://doi.org/10.1016/S0022-3115(97)00096-2	journal	August 1997
Electrochemical and Thermodynamic Properties of CeCl ₃ on Liquid Cadmium Cathode (LCC) in LiCl-KCl Eutectic Salt Yoon, Dalsung; Phongikaroon, Supathorn; Zhang, Jinsuo Journal of The Electrochemical Society, Vol. 163, Issue 3 https://doi.org/10.1149/2.0101605jes	journal	January 2016
Equilibrium distribution of rare earth elements between molten KCl-LiCl eutectic salt and liquid cadmium Sakata, Masahiro; Kurata, Masaki; Hijikata, Takatoshi Journal of Nuclear Materials, Vol. 185, Issue 1 https://doi.org/10.1016/0022-3115(91)90365-E	journal	November 1991
Separation of Actinides from Rare Earth Elements by Electrorefining in LiC1-KC1 Eutectic Salt Sakamura, Yoshiharu; Hijikata, Takatoshi; Kinoshita, Kensuke Journal of Nuclear Science and Technology, Vol. 35, Issue 1 https://doi.org/10.1080/18811248.1998.9733819	journal	January 1998
Reinvestigation of the Cd–Gd phase diagram Reichmann, Thomas L.; Ipser, Herbert Journal of Alloys and Compounds, Vol. 617 https://doi.org/10.1016/j.jallcom.2014.07.211	journal	December 2014
Thermochemical properties of the intermetallic compounds in the lanthanum–cadmium system Shirai, Osamu; Uehara, Akihiro; Fujii, Toshiyuki Journal of Nuclear Materials, Vol. 344, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2005.04.032	journal	September 2005
Separation of actinides from rare earth elements by means of molten salt electrorefining with anodic dissolution of U–Pu–Zr alloy fuel Kinoshita, Kensuke; Koyama, Tadafumi; Inoue, Tadashi Journal of Physics and Chemistry of Solids, Vol. 66, Issue 2-4 https://doi.org/10.1016/j.jpcs.2004.06.069	journal	February 2005
Transient modeling of spent nuclear fuel electrorefining with liquid metal electrode Seo, Seungjin; Choi, Sungyeol; Park, Byung Gi Journal of Nuclear Materials, Vol. 491 https://doi.org/10.1016/j.jnucmat.2017.04.053	journal	August 2017
Evaluation of the thermochemical properties of Ho–Cd intermetallic compounds using electrochemical techniques Castrillejo, Y.; Oduber, F.; Barrado, E. RSC Advances, Vol. 6, Issue 75 https://doi.org/10.1039/C6RA15442E	journal	January 2016
An Assessment of the Multi-stage Counter Current Extraction of TRUs from Spent Molten Salt, into Liquid Metal Kobayashi, Tsuguyuki Journal of Nuclear Science and Technology, Vol. 43, Issue 7 https://doi.org/10.1080/18811248.2006.9711166	journal	July 2006
Distribution behavior of uranium, neptunium, rare-earth elements ( Y, La, Ce, Nd, Sm, Eu, Gd) and alkaline-earth metals (Sr,Ba) between molten LiClKCI eutectic salt and liquid cadmium or bismuth Kurata, M.; Sakamura, Y.; Hijikata, T. Journal of Nuclear Materials, Vol. 227, Issue 1-2 https://doi.org/10.1016/0022-3115(95)00146-8	journal	December 1995
Electrode reaction of plutonium at liquid cadmium in LiCl–KCl eutectic melts Shirai, O.; Iizuka, M.; Iwai, T. Journal of Electroanalytical Chemistry, Vol. 490, Issue 1-2 https://doi.org/10.1016/S0022-0728(00)00193-5	journal	August 2000
An Experimental Study of Molten Salt Electrorefining of Uranium Using Solid Iron Cathode and Liquid Cadmium Cathode for Development of Pyrometallurgical Reprocessing KOYAMA, Tadafumi; IIZUKA, Masatoshi; SHOJI, Yuichi Journal of Nuclear Science and Technology, Vol. 34, Issue 4, p. 384-393 https://doi.org/10.1080/18811248.1997.9733678	journal	April 1997
Thermodynamic Evaluation of Liquid Cd Cathode Containing U and Pu Kurata, Masaki; Uozumi, Koichi; Kato, Tetsuya Journal of Nuclear Science and Technology, Vol. 46, Issue 11 https://doi.org/10.1080/18811248.2009.9711617	journal	November 2009
Electrochemical Measurement of Diffusion Coefficient of Actinides and Rare Earths in Liquid Cd Murakami, T.; Sakamura, Y.; Akiyama, N. Procedia Chemistry, Vol. 7 https://doi.org/10.1016/j.proche.2012.10.121	journal	January 2012
Phase relations in the thorium-cadmium system Bates, J.; Ader, M.; Meisenhelder, J. Journal of the Less Common Metals, Vol. 77, Issue 2 https://doi.org/10.1016/0022-5088(81)90172-7	journal	February 1981
Contribution to the system samarium-cadmium Bruzzone, G.; Fornasini, M. L. Journal of the Less Common Metals, Vol. 37, Issue 2 https://doi.org/10.1016/0022-5088(74)90045-9	journal	August 1974
Uranium exchange kinetics in a molten LiCl-KCl/Cd system at 500 °C Yoo, Tae-Sic; Fredrickson, Guy L.; Teske, Gregory M. Journal of Nuclear Materials, Vol. 508 https://doi.org/10.1016/j.jnucmat.2018.05.059	journal	September 2018
Partition of lanthanum and neodymium metals and chloride salts between molten cadmium and molten LiCl-KCl eutectic Ackerman, John P.; Settle, Jack L. Journal of Alloys and Compounds, Vol. 177, Issue 1 https://doi.org/10.1016/0925-8388(91)90063-2	journal	December 1991
Pyrometallurgical Partitioning of Uranium and Transuranic Elements from Rare Earth Elements by Electrorefining and Reductive Extraction Uozumi, Koichi; Kinoshita, Kensuke; Inoue, Tadashi Journal of Nuclear Science and Technology, Vol. 38, Issue 1 https://doi.org/10.1080/18811248.2001.9715005	journal	January 2001
Electrodeposition of uranium in stirred liquid cadmium cathode Koyama, Tadafumi; Iizuka, Masatoshi; Kondo, Naruhito Journal of Nuclear Materials, Vol. 247 https://doi.org/10.1016/S0022-3115(97)00100-1	journal	August 1997
Experimental Observations on the Roles of the Cadmium Pool in the Mark-IV Electrorefiner Li, Shelly X. Nuclear Technology, Vol. 162, Issue 2 https://doi.org/10.13182/NT08-A3941	journal	May 2008
Distribution of actinides in molten chloride salt/cadmium metal systems Koyama, T.; Johnson, T. R.; Fischer, D. F. Journal of Alloys and Compounds, Vol. 189, Issue 1 https://doi.org/10.1016/0925-8388(92)90043-9	journal	November 1992
The electrochemical behaviour of the Pr(III)/Pr redox system at Bi and Cd liquid electrodes in molten eutectic LiCl–KCl Castrillejo, Y.; Bermejo, M. R.; Arocas, P. Díaz Journal of Electroanalytical Chemistry, Vol. 579, Issue 2 https://doi.org/10.1016/j.jelechem.2005.03.001	journal	June 2005
A study on the evaporation of cadmium for the recovery of actinides from a liquid cathode Kwon, S. W.; Kim, J. Y.; Ahn, D. H. Journal of Radioanalytical and Nuclear Chemistry, Vol. 284, Issue 1 https://doi.org/10.1007/s10967-010-0446-3	journal	January 2010
Electrochemical behaviors of uranium and plutonium at simultaneous recoveries into liquid cadmium cathodes Uozumi, Koichi; Iizuka, Masatoshi; Kato, Tetsuya Journal of Nuclear Materials, Vol. 325, Issue 1 https://doi.org/10.1016/j.jnucmat.2003.10.010	journal	February 2004
Distribution of plutonium, americium, and several rare earth fission product elements between liquid cadmium and LiClKCl eutectic Ackerman, John P.; Settle, Jack L. Journal of Alloys and Compounds, Vol. 199, Issue 1-2 https://doi.org/10.1016/0925-8388(93)90430-U	journal	September 1993
Actinide Recovery Experiments with Bench-Scale Liquid Cadmium Cathode in Real Fission Product-Laden Molten Salt Li, Shelly X.; Herrmann, S. D.; Goff, K. M. Nuclear Technology, Vol. 165, Issue 2 https://doi.org/10.13182/NT09-A4085	journal	February 2009
Thermodynamic study of the cerium–cadmium system Skołyszewska-Kühberger, Barbara; Reichmann, Thomas L.; Ganesan, Rajesh Calphad, Vol. 44 https://doi.org/10.1016/j.calphad.2013.07.005	journal	March 2014
Electrorefiner Liquid Cadmium Cathode Crucible Thermal Shock Solbrig, C. W.; Vaden, DeeEarl Separation Science and Technology, Vol. 41, Issue 10 https://doi.org/10.1080/01496390600745750	journal	June 2006
Development of the anode-liquid cathode module (ALCM) for a high-throughput electrowinner Kim, Gha-Young; Kim, Tack-Jin; Kim, Si-Hyung Journal of Radioanalytical and Nuclear Chemistry, Vol. 300, Issue 3 https://doi.org/10.1007/s10967-014-3096-z	journal	March 2014
Recovery of uranium using electrorefining with an anode-liquid cathode module (ALCM) in molten LiCl–KCl–UCl3–NdCl3 and cadmium distillation Kim, Gha-Young; Shin, Jiseon; Kim, Si-Hyung Journal of Radioanalytical and Nuclear Chemistry, Vol. 307, Issue 2 https://doi.org/10.1007/s10967-015-4292-1	journal	July 2015
Integrated Experiments of Electrometallurgical Pyroprocessing Using Plutonium Oxide Koyama, Tadafumi; Hijikata, Takatoshi; Usami, Tsuyoshi Journal of Nuclear Science and Technology, Vol. 44, Issue 3 https://doi.org/10.1080/18811248.2007.9711298	journal	March 2007
In-situ observation of a dendrite growth in an aqueous condition and a uranium deposition into a liquid cadmium cathode in an electrowinning system Kim, Si-Hyung; Yoon, Dal-Seong; You, Young-Jae Journal of Nuclear Materials, Vol. 385, Issue 1 https://doi.org/10.1016/j.jnucmat.2008.10.019	journal	March 2009
Application of Electrochemical Method to Measure Diffusion Coefficient in Liquid Metal Murakami, Tsuyoshi; Koyama, Tadafumi Journal of The Electrochemical Society, Vol. 158, Issue 8 https://doi.org/10.1149/1.3593048	journal	January 2011
Countercurrent Extraction Test with Continuous Flow of Molten LiCl-KCl Salt and Liquid Cd for Pyro-Reprocessing of Metal FBR Fuel Kinoshita, Kensuke; Tsukada, Takeshi Journal of Nuclear Science and Technology, Vol. 47, Issue 2 https://doi.org/10.1080/18811248.2010.9711947	journal	February 2010
Evaluation of Gibbs free energies of formation of Ce–Cd intermetallic compounds using electrochemical techniques Shibata, Hiroki; Hayashi, Hirokazu; Akabori, Mitsuo Journal of Physics and Chemistry of Solids, Vol. 75, Issue 8 https://doi.org/10.1016/j.jpcs.2014.04.004	journal	August 2014
The Cd-Eu (cadmium-europium) system Gschneidner, K. A.; Calderwood, F. W. Bulletin of Alloy Phase Diagrams, Vol. 9, Issue 1 https://doi.org/10.1007/BF02877452	journal	February 1988
A RECORDING EFFUSION BALANCE FOR PHASE DIAGRAM INVESTIGATIONS: U-Cd, U-Zn AND Ce-Zn SYSTEMS ¹ Veleckis, Ewald; Rosen, Charles L.; Feder, Harold M. The Journal of Physical Chemistry, Vol. 65, Issue 12 https://doi.org/10.1021/j100829a004	journal	December 1961
Sequential Electrolysis of U-Pu Alloy Containing a Small Amount of Am to Recover U- and U-Pu-Am Products Kuratal, Masaki; Yahagi, Noboru; Kitawaki, Shinichi Journal of Nuclear Science and Technology, Vol. 46, Issue 2 https://doi.org/10.1080/18811248.2007.9711519	journal	February 2009
Phase equilibria in the neodymium–cadmium binary system Skołyszewska-Kühberger, Barbara; Reichmann, Thomas L.; Ipser, Herbert Journal of Alloys and Compounds, Vol. 606 https://doi.org/10.1016/j.jallcom.2014.04.009	journal	September 2014
Electrotransport of Uranium from a Liquid Cadmium Anode to a Solid Cathode Ahluwalia, Rajesh K.; Hua, Thanh Q. Nuclear Technology, Vol. 140, Issue 1 https://doi.org/10.13182/NT02-A3322	journal	October 2002
Evaluation of Cadmium Pool Potential in a Electrorefiner with Ceramic Part it ion for Spent Metallic Fuel Kobayashi, Tsuguyuki; Fujita, Reiko; Nakamura, Hitoshi Journal of Nuclear Science and Technology, Vol. 34, Issue 1 https://doi.org/10.1080/18811248.1997.9732055	journal	January 1997
Electrorefining Experiments to Recover Uranium with a Cadmium-Lithium Anode and Their Theoretical Evaluation Kobayashi, Tsuguyuki; Fujita, Reiko; Nakamura, Hitoshi Journal of Nuclear Science and Technology, Vol. 36, Issue 3 https://doi.org/10.1080/18811248.1999.9726210	journal	March 1999
Electrolysis of AmN in LiCl-KCl Eutectic Melts and Renitridation of Am Recovered in Liquid Cd Cathode Hayashi, Hirokazu; Shibata, Hiroki; Akabori, Mitsuo Electrochemistry, Vol. 77, Issue 8 https://doi.org/10.5796/electrochemistry.77.673	journal	January 2009
Standard enthalpy of formation of compounds of the Cd–Zr system Phapale, S.; Mishra, R.; Das, D. Journal of Nuclear Materials, Vol. 375, Issue 2 https://doi.org/10.1016/j.jnucmat.2008.01.004	journal	April 2008
Electrochemical Analysis of Actinides and Rare Earth Constituents in Liquid Cadmium Cathode Product from Spent Fuel Electrorefining Li, Shelly X.; Herrmann, Steven D.; Simpson, Michael F. Nuclear Technology, Vol. 171, Issue 3 https://doi.org/10.13182/NT10-A10864	journal	September 2010
Application of electrochemical techniques in pyrochemical processes – Electrochemical behaviour of rare earths at W, Cd, Bi and Al electrodes Castrillejo, Y.; Bermejo, R.; Martínez, A. M. Journal of Nuclear Materials, Vol. 360, Issue 1 https://doi.org/10.1016/j.jnucmat.2006.08.011	journal	January 2007
Equilibrium Distributions of Actinides and Fission Products in Pyrochemical Separation Systems, (II) LiCl-KCl/Cd System Moriyama, Hirotake; Kinoshita, Kensuke; Asaoka, Yoshiyuki Journal of Nuclear Science and Technology, Vol. 27, Issue 10 https://doi.org/10.1080/18811248.1990.9731273	journal	October 1990
The phase diagram of the system lithium-cadmium van der Marel, C.; Vinke, G. J. B.; Hennephof, J. Journal of Physics and Chemistry of Solids, Vol. 43, Issue 10 https://doi.org/10.1016/0022-3697(82)90118-4	journal	January 1982
Novel Approach to Extracting Transuranic Elements in Molten Salt Electrorefining Sakamura, Yoshiharu; Iizuka, Masatoshi; Koyama, Tadafumi Nuclear Technology, Vol. 190, Issue 2 https://doi.org/10.13182/NT14-64	journal	May 2015
A model study on multistep recovery of actinides based on the difference in diffusion coefficients within liquid metal Chun, Young-Min; Shin, Heon-Cheol Nuclear Engineering and Technology, Vol. 47, Issue 5 https://doi.org/10.1016/j.net.2015.04.005	journal	August 2015
The lanthanum-cadmium system Bruzzone, G.; Merlo, F. Journal of the Less Common Metals, Vol. 30, Issue 2 https://doi.org/10.1016/0022-5088(73)90115-X	journal	February 1973
An Assessment of Multistage Counter Current Extraction of TRU from Spent Molten Salt into Liquid Metal II. Effect of Stage Efficiency, Scrub Stage, and TRU Concentration Kobayashi, Tsuguyuki Journal of Nuclear Science and Technology, Vol. 45, Issue 1 https://doi.org/10.1080/18811248.2008.9711417	journal	January 2008
A study on the electrochemical deposition behavior of uranium ion in a LiCl–KCl molten salt on solid and liquid electrode Kim, Gha-Young; Yoon, Dalseong; Paek, Seungwoo Journal of Electroanalytical Chemistry, Vol. 682 https://doi.org/10.1016/j.jelechem.2012.07.025	journal	August 2012
Distribution behavior of plutonium and americium in LiCl–KCl eutectic/liquid cadmium systems Sakamura, Y.; Shirai, O.; Iwai, T. Journal of Alloys and Compounds, Vol. 321, Issue 1 https://doi.org/10.1016/S0925-8388(01)00973-2	journal	May 2001
Electrode reactions of Ce3+/Ce couple in LiCl–KCl solutions containing CeCl3 at solid W and liquid Cd electrodes Kim, Si-Hyung; Paek, Seungwoo; Kim, Tack-Jin Electrochimica Acta, Vol. 85 https://doi.org/10.1016/j.electacta.2012.08.084	journal	December 2012
Thermodynamic quantities of actinides and rare earth elements in liquid bismuth and cadmium Kurata, Masaki; Sakamura, Yoshiharu; Matsui, Tsuneo Journal of Alloys and Compounds, Vol. 234, Issue 1 https://doi.org/10.1016/0925-8388(95)01960-X	journal	February 1996
Recovery of U-Pu Alloy from MOX Using a Pyroprocess Series Kitawaki, Shinichi; Shinozaki, Tadahiro; Fukushima, Mineo Nuclear Technology, Vol. 162, Issue 2 https://doi.org/10.13182/NT08-A3937	journal	May 2008
Engineering-Scale Liquid Cadmium Cathode Experiments Vaden, D.; Li, S. X.; Westphal, B. R. Nuclear Technology, Vol. 162, Issue 2 https://doi.org/10.13182/NT08-A3938	journal	May 2008
Cyclic Voltammetry Behavior of Americium at a Liquid Cadmium Electrode in LiCl-KCl Eutectic Melts Hayashi, Hirokazu; Akabori, Mitsuo; Minato, Kazuo Nuclear Technology, Vol. 162, Issue 2 https://doi.org/10.13182/NT08-A3939	journal	May 2008
Measurement of chemical activities of rare earths (RE: Ce, Pr, Sm and Eu) in cadmium alloy Ghosh, Sajal; Ganesan, Rajesh; Sridharan, R. Journal of Nuclear Materials, Vol. 467 https://doi.org/10.1016/j.jnucmat.2015.09.050	journal	December 2015
Thermodynamic assessment of systems of actinide or rare earth with Cd Kurata, Masaki; Sakamura, Yoshiharu Journal of Phase Equilibria, Vol. 22, Issue 3 https://doi.org/10.1361/105497101770338707	journal	May 2001
Distillation behavior of cadmium for U recovery from liquid cadmium cathode in pyroprocessing Lee, Sungjai; Jang, Junhyuk Journal of Radioanalytical and Nuclear Chemistry, Vol. 314, Issue 1 https://doi.org/10.1007/s10967-017-5394-8	journal	August 2017

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