Here, the thermal properties of plasma-generated aluminum oxyfluoride passivation layers at the surface of aluminum thin films are measured. The oxyfluoride layers are generated using plasmas produced in mixtures of NH3 and SF6 to simultaneously remove oxygen and add fluorine to the aluminum surface, an alternative approach to the more conventional two-step methods that utilize HF treatments to remove the native oxide followed by metal-fluoride (e.g., MgF2, LiF, and AlF3) thin film deposition that serves to protect the aluminum surface from further oxidation. Here, the change in thermal properties of the layers as a function of plasma processing time is determined. A significant reduction in thermal boundary conductance is measured with the increasing treatment time, which can be related to the increasing fluorine content in the layers. Acoustic reflection measurements suggest this reduced thermal boundary conductance is related to lower bonding strength to aluminum with increasing fluorine.
Tomko, John A., Boris, David R., Rosenberg, Samantha G., Walton, Scott G., & Hopkins, Patrick E. (2019). Thermal conductance of aluminum oxy-fluoride passivation layers. Applied Physics Letters, 115(19). https://doi.org/10.1063/1.5120028
Tomko, John A., Boris, David R., Rosenberg, Samantha G., et al., "Thermal conductance of aluminum oxy-fluoride passivation layers," Applied Physics Letters 115, no. 19 (2019), https://doi.org/10.1063/1.5120028
@article{osti_1574485,
author = {Tomko, John A. and Boris, David R. and Rosenberg, Samantha G. and Walton, Scott G. and Hopkins, Patrick E.},
title = {Thermal conductance of aluminum oxy-fluoride passivation layers},
annote = {Here, the thermal properties of plasma-generated aluminum oxyfluoride passivation layers at the surface of aluminum thin films are measured. The oxyfluoride layers are generated using plasmas produced in mixtures of NH3 and SF6 to simultaneously remove oxygen and add fluorine to the aluminum surface, an alternative approach to the more conventional two-step methods that utilize HF treatments to remove the native oxide followed by metal-fluoride (e.g., MgF2, LiF, and AlF3) thin film deposition that serves to protect the aluminum surface from further oxidation. Here, the change in thermal properties of the layers as a function of plasma processing time is determined. A significant reduction in thermal boundary conductance is measured with the increasing treatment time, which can be related to the increasing fluorine content in the layers. Acoustic reflection measurements suggest this reduced thermal boundary conductance is related to lower bonding strength to aluminum with increasing fluorine.},
doi = {10.1063/1.5120028},
url = {https://www.osti.gov/biblio/1574485},
journal = {Applied Physics Letters},
issn = {ISSN 0003-6951},
number = {19},
volume = {115},
place = {United States},
publisher = {American Institute of Physics (AIP)},
year = {2019},
month = {11}}