Triple hydrogen atom abstraction from Mn–NH 3 complexes results in cyclophosphazenium cations

Cook, Brian J.; Johnson, Samantha I.; Chambers, Geoffrey M.; Kaminsky, Werner; Bullock, R. Morris

doi:10.1039/C9CC06915A

Triple hydrogen atom abstraction from Mn–NH ₃ complexes results in cyclophosphazenium cations

Journal Article · Mon Nov 18 23:00:00 EST 2019 · ChemComm

DOI:https://doi.org/10.1039/C9CC06915A· OSTI ID:1573275

Cook, Brian J. ^[1]; ^[1]; Chambers, Geoffrey M. ^[1]; ^[2]; ^[1]

Center for Molecular Electrocatalysis, Pacific Northwest National Laboratory P.O. Box 999, Richland, USA
Department of Chemistry, University of Washington, Seattle, USA

All three H atoms of the NH ₃ ligand of [Mn(depe) ₂ (CO)(NH ₃ )] ⁺ are abstracted by an organic radical, giving a rare cyclophosphazenium cation; computations suggest that insertion of NH _x into a Mn–P bond provides a strong thermodynamic driving force.

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI ID:: 1573275

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 93 Vol. 55; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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