Progress in development of electrolytes for magnesium batteries

Deivanayagam, Ramasubramonian; Ingram, Brian J.; Shahbazian-Yassar, Reza

doi:10.1016/j.ensm.2019.05.028

Title: Progress in development of electrolytes for magnesium batteries

Journal Article · Wed May 22 00:00:00 EDT 2019 · Energy Storage Materials

DOI:https://doi.org/10.1016/j.ensm.2019.05.028· OSTI ID:1572939

Deivanayagam, Ramasubramonian ^[1]; Ingram, Brian J. ^[2]; Shahbazian-Yassar, Reza ^[1]

Univ. of Illinois at Chicago, Chicago, IL (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)

Over the last few years, there has been an increased interest in developing safe, next-generation battery systems that offer energy densities higher than those of lithium-based batteries. In this context, batteries based on multivalent-ions (Mg²⁺, Zn²⁺, Ca²⁺, and Al³⁺) have developed their own niche with their capability to achieve at least twice the energy density of monovalent-ion systems such as Li-ion and Na-ion batteries. Among the multivalent-ion battery candidates, magnesium (Mg) batteries appear to be the most viable choice to eventually replace the Li-ion technology because of the high electrode potential, superior safety, and high abundance of Mg-metal. However, the limited development in electrolytes and cathodes has prevented their commercialization to date. There is a lack of suitable electrolytes that can be used at high voltages required for Mg²⁺ insertion into cathode hosts. The limited compatibility of organic electrolytes with Mg-metal anode is also a challenge, which requires extensive studies of the metal/electrolyte interactions. Such studies over the last two decades were critical in developing state-of-the-art Mg electrolytes that possess voltage windows of >4.0 V and simultaneously be compatible with Mg-metal anodes. Here, we present a review on the development of Mg battery electrolytes, challenges that impede their performance, and promising strategies that have been adopted to address them. As a result, we believe that this comprehensive review covering all three categories of Mg electrolytes (liquids, polymers, and solids) would enable researchers to get a quick grasp of the prevailing challenges, and consequently motivate them to develop novel electrolyte candidates.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Joint Center for Energy Storage Research (JCESR)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1572939

Journal Information:: Energy Storage Materials, Vol. 21, Issue C; ISSN 2405-8297

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 123 works

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Mg ₃ (BH ₄ ) ₄ (NH ₂ ) ₂ as Inorganic Solid Electrolyte with High Mg ²⁺ Ionic Conductivity Le Ruyet, Ronan; Fleutot, Benoît; Berthelot, Romain ACS Applied Energy Materials, Vol. 3, Issue 7 https://doi.org/10.1021/acsaem.0c00980	journal	June 2020
A high-voltage concept with sodium-ion conducting β-alumina for magnesium-sodium dual-ion batteries Kravchyk, Kostiantyn V.; Walter, Marc; Kovalenko, Maksym V. ETH Zurich https://doi.org/10.3929/ethz-b-000361670	text	January 2019
Recent Development of Mg Ion Solid Electrolyte Zhan, Yi; Zhang, Wei; Lei, Bing Frontiers in Chemistry, Vol. 8 https://doi.org/10.3389/fchem.2020.00125	journal	February 2020
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