Interphases in Sodium-Ion Batteries

Song, Junhua; Xiao, Biwei; Lin, Yuehe; Xu, Kang; Li, Xiaolin

doi:10.1002/aenm.201703082

Title: Interphases in Sodium-Ion Batteries

Journal Article · Fri Jun 15 00:00:00 EDT 2018 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201703082· OSTI ID:1572521

Song, Junhua ^[1]; Xiao, Biwei ^[1];

^[2]; Xu, Kang ^[3]; Li, Xiaolin ^[1]

BATTELLE (PACIFIC NW LAB)
WASHINGTON STATE UNIV
U. S. Army Research Laboratory

Sodium-ion batteries (SIBs) as economical high energy alternatives to lithium-ion batteries (LIBs) have received significant attention for large-scale energy storage in the last few years. While the efforts of developing SIBs have benefited from the knowledge learned in LIBs, thanks to the apparent proximity between Na-ion and Li-ion, the unique physical and chemical properties of Na-ion also distinctly differ itself from Li-ion. It is expected SIBs have drastically different electrode material structure, solvation-de-solvation behavior, electrode-electrolyte interphase stability, ion transfer property, and hence electrochemical performance of batteries. In this review, we comprehensively summarize the current understanding of the anode solid-electrolyte-interphase (SEI) and cathode cathode-electrolyte-interphase (CEI) in SIBs, with an emphasis on how the tuning of the stability and ion transfer properties of interphases fundamentally determines the reversibility and efficiency of electrochemical reactions. Through these carefully screened references, we intend to reveal the intrinsic correlation between the properties/functionalities of the interphases and the electrochemical performances of batteries.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1572521

Report Number(s):: PNNL-SA-130469

Journal Information:: Advanced Energy Materials, Vol. 8, Issue 17

Country of Publication:: United States

Language:: English

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Ultrathin Surface Coating Enables the Stable Sodium Metal Anode Luo, Wei; Lin, Chuan-Fu; Zhao, Oliver Advanced Energy Materials, Vol. 7, Issue 2 https://doi.org/10.1002/aenm.201601526	journal	September 2016
Highly Stable Sodium Batteries Enabled by Functional Ionic Polymer Membranes Wei, Shuya; Choudhury, Snehashis; Xu, Jun Advanced Materials, Vol. 29, Issue 12 https://doi.org/10.1002/adma.201605512	journal	January 2017
Atomic-Layer-Deposition Oxide Nanoglue for Sodium Ion Batteries Han, Xiaogang; Liu, Yang; Jia, Zheng Nano Letters, Vol. 14, Issue 1 https://doi.org/10.1021/nl4035626	journal	December 2013
SnO2 coated carbon cloth with surface modification as Na-ion battery anode Liu, Yihang; Fang, Xin; Ge, Mingyuan Nano Energy, Vol. 16 https://doi.org/10.1016/j.nanoen.2015.07.010	journal	September 2015
Enhancement of Sodium Ion Battery Performance Enabled by Oxygen Vacancies Xu, Yang; Zhou, Min; Wang, Xin Angewandte Chemie International Edition, Vol. 54, Issue 30 https://doi.org/10.1002/anie.201503477	journal	June 2015
Core-Shell Ge@Graphene@TiO ₂ Nanofibers as a High-Capacity and Cycle-Stable Anode for Lithium and Sodium Ion Battery Wang, Xiaoyan; Fan, Ling; Gong, Decai Advanced Functional Materials, Vol. 26, Issue 7 https://doi.org/10.1002/adfm.201504589	journal	December 2015
Vine-like MoS ₂ anode materials self-assembled from 1-D nanofibers for high capacity sodium rechargeable batteries Ryu, Won-Hee; Jung, Ji-Won; Park, Kyusung Nanoscale, Vol. 6, Issue 19 https://doi.org/10.1039/C4NR02044H	journal	January 2014
Mechanistic Insight into the Stability of HfO ₂ -Coated MoS ₂ Nanosheet Anodes for Sodium Ion Batteries Ahmed, Bilal; Anjum, Dalaver H.; Hedhili, Mohamed N. Small, Vol. 11, Issue 34 https://doi.org/10.1002/smll.201500919	journal	June 2015
X-ray Crystal Structure Analysis of Sodium-Ion Conductivity in 94 Na ₃ PS ₄ ⋅6 Na ₄ SiS ₄ Glass-Ceramic Electrolytes Tanibata, Naoto; Noi, Kousuke; Hayashi, Akitoshi ChemElectroChem, Vol. 1, Issue 7 https://doi.org/10.1002/celc.201402016	journal	June 2014
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Room-Temperature All-solid-state Rechargeable Sodium-ion Batteries with a Cl-doped Na3PS4 Superionic Conductor Chu, Iek-Heng; Kompella, Christopher S.; Nguyen, Han Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep33733	journal	September 2016
Origin of Outstanding Stability in the Lithium Solid Electrolyte Materials: Insights from Thermodynamic Analyses Based on First-Principles Calculations Zhu, Yizhou; He, Xingfeng; Mo, Yifei ACS Applied Materials & Interfaces, Vol. 7, Issue 42 https://doi.org/10.1021/acsami.5b07517	journal	October 2015
Investigations of the Exothermic Reactions of Natural Graphite Anode for Li-Ion Batteries during Thermal Runaway Yang, Hui; Bang, Hyunjoo; Amine, Khalil Journal of The Electrochemical Society, Vol. 152, Issue 1 https://doi.org/10.1149/1.1836126	journal	January 2005
LiFSI vs. LiPF6 electrolytes in contact with lithiated graphite: Comparing thermal stabilities and identification of specific SEI-reinforcing additives Eshetu, Gebrekidan Gebresilassie; Grugeon, Sylvie; Gachot, Grégory Electrochimica Acta, Vol. 102 https://doi.org/10.1016/j.electacta.2013.03.171	journal	July 2013
Corrigendum: Safer Electrolytes for Lithium-Ion Batteries: State of the Art and Perspectives Kalhoff, Julian; Eshetu, Gebrekidan Gebresilassie; Bresser, Dominic ChemSusChem, Vol. 8, Issue 17 https://doi.org/10.1002/cssc.201501066	journal	August 2015
Solubility of the Solid Electrolyte Interphase (SEI) in Sodium Ion Batteries Mogensen, Ronnie; Brandell, Daniel; Younesi, Reza ACS Energy Letters, Vol. 1, Issue 6 https://doi.org/10.1021/acsenergylett.6b00491	journal	November 2016
Chemical Composition and Morphology of the Elevated Temperature SEI on Graphite Andersson, A. M.; Edström, K. Journal of The Electrochemical Society, Vol. 148, Issue 10 https://doi.org/10.1149/1.1397771	journal	January 2001
TPD–GC/MS analysis of the solid electrolyte interface (SEI) on a graphite anode in the propylene carbonate/ethylene sulfite electrolyte system for lithium batteries Ota, Hitoshi; Sato, Tomohiro; Suzuki, Hitoshi Journal of Power Sources, Vol. 97-98 https://doi.org/10.1016/S0378-7753(01)00738-8	journal	July 2001
Composition and Evolution of the Solid-Electrolyte Interphase in Na ₂ Ti ₃ O ₇ Electrodes for Na-Ion Batteries: XPS and Auger Parameter Analysis Muñoz-Márquez, Miguel A.; Zarrabeitia, Maider; Castillo-Martínez, Elizabeth ACS Applied Materials & Interfaces, Vol. 7, Issue 14 https://doi.org/10.1021/acsami.5b01375	journal	April 2015
Finding Conductivity Optima of Battery Electrolytes by Conductivity Measurements Guided by a Simplex Algorithm Schweiger, H. -G.; Multerer, M.; Schweizer-Berberich, M. Journal of The Electrochemical Society, Vol. 152, Issue 3 https://doi.org/10.1149/1.1859711	journal	January 2005
4.0 V Aqueous Li-Ion Batteries Yang, Chongyin; Chen, Ji; Qing, Tingting Joule, Vol. 1, Issue 1 https://doi.org/10.1016/j.joule.2017.08.009	journal	September 2017
Improving the cyclability of sodium-ion cathodes by selection of electrolyte solvent Vidal-Abarca, C.; Lavela, P.; Tirado, J. L. Journal of Power Sources, Vol. 197 https://doi.org/10.1016/j.jpowsour.2011.09.008	journal	January 2012
Study on the Reversible Electrode Reaction of Na _{1– x} Ni _0.5 Mn _0.5 O ₂ for a Rechargeable Sodium-Ion Battery Komaba, Shinichi; Yabuuchi, Naoaki; Nakayama, Tetsuri Inorganic Chemistry, Vol. 51, Issue 11 https://doi.org/10.1021/ic300357d	journal	May 2012
Highly stable linear carbonate-containing electrolytes with fluoroethylene carbonate for high-performance cathodes in sodium-ion batteries Lee, Yongwon; Lee, Jaegi; Kim, Hyungsub Journal of Power Sources, Vol. 320 https://doi.org/10.1016/j.jpowsour.2016.04.070	journal	July 2016
Unravelling the Role of Electrochemically Active FePO ₄ Coating by Atomic Layer Deposition for Increased High-Voltage Stability of LiNi _0.5 Mn _1.5 O ₄ Cathode Material Xiao, Biwei; Liu, Jian; Sun, Qian Advanced Science, Vol. 2, Issue 5 https://doi.org/10.1002/advs.201500022	journal	March 2015
Surface modification of cathode materials from nano- to microscale for rechargeable lithium-ion batteries Myung, Seung-Taek; Amine, Khalil; Sun, Yang-Kook Journal of Materials Chemistry, Vol. 20, Issue 34 https://doi.org/10.1039/c0jm00508h	journal	January 2010
Highly Stable Na _2/3 (Mn _0.54 Ni _0.13 Co _0.13 )O ₂ Cathode Modified by Atomic Layer Deposition for Sodium-Ion Batteries Kaliyappan, Karthikeyan; Liu, Jian; Lushington, Andrew ChemSusChem, Vol. 8, Issue 15 https://doi.org/10.1002/cssc.201500155	journal	June 2015
Enhanced Performance of P2-Na _0.66 (Mn _0.54 Co _0.13 Ni _0.13 )O ₂ Cathode for Sodium-Ion Batteries by Ultrathin Metal Oxide Coatings via Atomic Layer Deposition Kaliyappan, Karthikeyan; Liu, Jian; Xiao, Biwei Advanced Functional Materials, Vol. 27, Issue 37 https://doi.org/10.1002/adfm.201701870	journal	August 2017
Layered P2-Na2/3[Ni1/3Mn2/3]O2 as high-voltage cathode for sodium-ion batteries: The capacity decay mechanism and Al2O3 surface modification Liu, Yihang; Fang, Xin; Zhang, Anyi Nano Energy, Vol. 27 https://doi.org/10.1016/j.nanoen.2016.06.026	journal	September 2016
Nanoscale stabilization of Li–sulfur batteries by atomic layer deposited Al2O3 Li, Xia; Liu, Jian; Wang, Biqiong RSC Advances, Vol. 4, Issue 52 https://doi.org/10.1039/c4ra04015e	journal	January 2014
Sodium Ion Diffusion in Al ₂ O ₃ : A Distinct Perspective Compared with Lithium Ion Diffusion Jung, Sung Chul; Kim, Hyung-Jin; Choi, Jang Wook Nano Letters, Vol. 14, Issue 11 https://doi.org/10.1021/nl503169v	journal	October 2014
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan Energy & Environmental Science, Vol. 6, Issue 8 https://doi.org/10.1039/c3ee40847g	journal	January 2013
Na-ion batteries, recent advances and present challenges to become low cost energy storage systems Palomares, Verónica; Serras, Paula; Villaluenga, Irune Energy & Environmental Science, Vol. 5, Issue 3 https://doi.org/10.1039/c2ee02781j	journal	January 2012
Research Development on Sodium-Ion Batteries Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500192f	journal	October 2014
Trends in Na-Ion Solvation with Alkyl-Carbonate Electrolytes for Sodium-Ion Batteries: Insights from First-Principles Calculations Shakourian-Fard, Mehdi; Kamath, Ganesh; Smith, Kassiopeia The Journal of Physical Chemistry C, Vol. 119, Issue 40 https://doi.org/10.1021/acs.jpcc.5b04706	journal	September 2015
Understanding Li ⁺ –Solvent Interaction in Nonaqueous Carbonate Electrolytes with ¹⁷ O NMR Bogle, Xavier; Vazquez, Rafael; Greenbaum, Steven The Journal of Physical Chemistry Letters, Vol. 4, Issue 10 https://doi.org/10.1021/jz400661k	journal	May 2013
Differentiating Contributions to “Ion Transfer” Barrier from Interphasial Resistance and Li ⁺ Desolvation at Electrolyte/Graphite Interface Xu, Kang; von Cresce, Arthur; Lee, Unchul Langmuir, Vol. 26, Issue 13 https://doi.org/10.1021/la1009994	journal	July 2010
In situ Raman spectroscopy of carbon-coated ZnFe ₂ O ₄ anode material in Li-ion batteries – investigation of SEI growth Cabo-Fernandez, Laura; Mueller, Franziska; Passerini, Stefano Chemical Communications, Vol. 52, Issue 20 https://doi.org/10.1039/C5CC09350C	journal	January 2016
Materials’ Methods: NMR in Battery Research Pecher, Oliver; Carretero-González, Javier; Griffith, Kent J. Chemistry of Materials, Vol. 29, Issue 1 https://doi.org/10.1021/acs.chemmater.6b03183	journal	November 2016
Atomic Force Microscopy Studies on Molybdenum Disulfide Flakes as Sodium-Ion Anodes Lacey, Steven D.; Wan, Jiayu; Cresce, Arthur von Wald Nano Letters, Vol. 15, Issue 2 https://doi.org/10.1021/nl503871s	journal	January 2015

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