Modulation versus Templating: Fine‐Tuning of Hierarchally Porous PCN‐250 Using Fatty Acids To Engineer Guest Adsorption

Kirchon, Angelo; Li, Jialuo; Xia, Fangqing; Day, Gregory S.; Becker, Benjamin; Chen, Wenmiao; Sue, Hung‐Jue; Fang, Yu; Zhou, Hong‐Cai

doi:10.1002/anie.201905006

Title: Modulation versus Templating: Fine‐Tuning of Hierarchally Porous PCN‐250 Using Fatty Acids To Engineer Guest Adsorption

Journal Article · Mon Sep 02 00:00:00 EDT 2019 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201905006· OSTI ID:1572120

Kirchon, Angelo ^[1]; Li, Jialuo ^[1]; Xia, Fangqing ^[2]; Day, Gregory S. ^[1]; Becker, Benjamin ^[1]; Chen, Wenmiao ^[1]; Sue, Hung‐Jue ^[2]; Fang, Yu ^[1];

^[1]

Department of Chemistry Texas A&,M University College Station TX 77843-3255 USA
Department of Materials Science and Engineering Texas A&,M University College Station TX 77843-3255 USA

Abstract Modulation and templating are two synthetic techniques that have garnered significant attention over the last several years for the preparation of hierarchically porous metal–organic frameworks (HP‐MOFs). In this study, by using fatty acids with different lengths and concentrations as dual‐functional modulators/templates, we were able to obtain HP‐MOFs with tunable mesopores that exhibit different pore diameters and locations. We found that the length and concentration of the fatty acids can determine if micelle formation occurs, which in turn dictates the porosity of the resulting HP‐MOFs. The HP‐MOFs with different mesopores differed in their performance in gas uptake and dye adsorption, and the structure–performance relationships were ascribed to the pore diameters and locations. This approach could provide a potentially universal method to efficiently introduce hierarchal mesopores into existing microporous MOF adsorbents with tunable properties.

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Sponsoring Organization:: USDOE

OSTI ID:: 1572120

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Vol. 58 Journal Issue: 36; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 48 works

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References (35)

Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report) Thommes, Matthias; Kaneko, Katsumi; Neimark, Alexander V. Pure and Applied Chemistry, Vol. 87, Issue 9-10 https://doi.org/10.1515/pac-2014-1117	journal	October 2015
A Kinetic Study of the Growth of Fatty Acid Vesicles Chen, Irene A.; Szostak, Jack W. Biophysical Journal, Vol. 87, Issue 2 https://doi.org/10.1529/biophysj.104.039875	journal	August 2004
Nanoscale metal–organic frameworks for drug delivery: a conventional platform with new promise Wang, Lei; Zheng, Min; Xie, Zhigang Journal of Materials Chemistry B, Vol. 6, Issue 5 https://doi.org/10.1039/C7TB02970E	journal	January 2018
Ultrafast room-temperature synthesis of hierarchically porous metal–organic frameworks by a versatile cooperative template strategy Duan, Chongxiong; Huo, Jinhao; Li, Feier Journal of Materials Science, Vol. 53, Issue 24 https://doi.org/10.1007/s10853-018-2793-3	journal	August 2018
Gas storage in porous metal–organic frameworks for clean energy applications Ma, Shengqian; Zhou, Hong-Cai Chem. Commun., Vol. 46, Issue 1 https://doi.org/10.1039/B916295J	journal	January 2010
Creating Hierarchical Pores by Controlled Linker Thermolysis in Multivariate Metal–Organic Frameworks Feng, Liang; Yuan, Shuai; Zhang, Liang-Liang Journal of the American Chemical Society, Vol. 140, Issue 6 https://doi.org/10.1021/jacs.7b12916	journal	January 2018
Hierarchically structured metal–organic frameworks assembled by hydroxy double salt–template synergy with high space–time yields Duan, Chongxiong; Li, Feier; Li, Libo CrystEngComm, Vol. 20, Issue 8 https://doi.org/10.1039/C7CE01843F	journal	January 2018
Aqueous-Phase Synthesis of Mesoporous Zr-Based MOFs Templated by Amphoteric Surfactants Li, Ke; Lin, Shaoliang; Li, Yongsheng Angewandte Chemie International Edition, Vol. 57, Issue 13 https://doi.org/10.1002/anie.201800619	journal	February 2018
A Modulator-Induced Defect-Formation Strategy to Hierarchically Porous Metal-Organic Frameworks with High Stability Cai, Guorui; Jiang, Hai-Long Angewandte Chemie, Vol. 129, Issue 2 https://doi.org/10.1002/ange.201610914	journal	December 2016
Micelle Formation and the Hydrophobic Effect ^† Maibaum, Lutz; Dinner, Aaron R.; Chandler, David The Journal of Physical Chemistry B, Vol. 108, Issue 21 https://doi.org/10.1021/jp037487t	journal	May 2004
Metal–organic frameworks for energy storage: Batteries and supercapacitors Wang, Lu; Han, Yuzhen; Feng, Xiao Coordination Chemistry Reviews, Vol. 307 https://doi.org/10.1016/j.ccr.2015.09.002	journal	January 2016
Implicit-Solvent Models for Micellization: Nonionic Surfactants and Temperature-Dependent Properties Jusufi, Arben; Sanders, Samantha; Klein, Michael L. The Journal of Physical Chemistry B, Vol. 115, Issue 5 https://doi.org/10.1021/jp108107f	journal	February 2011
Solvophobic Interactions and Micelle Formation in Structure Forming Nonaqueous Solvents Ray, Ashoka Nature, Vol. 231, Issue 5301 https://doi.org/10.1038/231313a0	journal	June 1971
Aqueous-Phase Synthesis of Mesoporous Zr-Based MOFs Templated by Amphoteric Surfactants Li, Ke; Lin, Shaoliang; Li, Yongsheng Angewandte Chemie, Vol. 130, Issue 13 https://doi.org/10.1002/ange.201800619	journal	February 2018
Kinetically tuned dimensional augmentation as a versatile synthetic route towards robust metal–organic frameworks Feng, Dawei; Wang, Kecheng; Wei, Zhangwen Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6723	journal	December 2014
Characterization of micro- and mesoporous solids by physisorption methods and pore-size analysis Storck, Sebastian; Bretinger, Helmut; Maier, Wilhelm F. Applied Catalysis A: General, Vol. 174, Issue 1-2, p. 137-146 https://doi.org/10.1016/S0926-860X(98)00164-1	journal	November 1998
PCN-250 under Pressure: Sequential Phase Transformation and the Implications for MOF Densification Yuan, Shuai; Sun, Xing; Pang, Jiandong Joule, Vol. 1, Issue 4 https://doi.org/10.1016/j.joule.2017.09.001	journal	December 2017
Effect of temperature on micelle formation in aqueous solutions of alkyltrimethylammonium bromides Zieliński, Ryszard; Ikeda, Shoichi; Nomura, Hiroyasu Journal of Colloid and Interface Science, Vol. 129, Issue 1 https://doi.org/10.1016/0021-9797(89)90428-1	journal	April 1989
A comparison of micelle formation of ionic surfactants in formamide, in N-methylformamide and in N,N-dimethylformamide Akhter, M. Salim; Alawi, Sadeq M. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 219, Issue 1-3 https://doi.org/10.1016/S0927-7757(03)00055-4	journal	June 2003
Pore size determination in modified micro- and mesoporous materials. Pitfalls and limitations in gas adsorption data analysis Groen, Johan C.; Peffer, Louk A. A.; Pérez-Ramı́rez, Javier Microporous and Mesoporous Materials, Vol. 60, Issue 1-3 https://doi.org/10.1016/S1387-1811(03)00339-1	journal	June 2003
A Modulator-Induced Defect-Formation Strategy to Hierarchically Porous Metal-Organic Frameworks with High Stability Cai, Guorui; Jiang, Hai-Long Angewandte Chemie International Edition, Vol. 56, Issue 2 https://doi.org/10.1002/anie.201610914	journal	December 2016
Template-directed synthesis of metal–organic materials Zhang, Zhenjie; Zaworotko, Michael J. Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00075G	journal	January 2014
Hierarchically mesostructured MIL-101 metal–organic frameworks: supramolecular template-directed synthesis and accelerated adsorption kinetics for dye removal Huang, Xiao-Xian; Qiu, Ling-Guang; Zhang, Wang CrystEngComm, Vol. 14, Issue 5 https://doi.org/10.1039/C1CE06138K	journal	January 2012
Introduction to Metal–Organic Frameworks Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M. Chemical Reviews, Vol. 112, Issue 2, p. 673-674 https://doi.org/10.1021/cr300014x	journal	September 2011
Template synthesis of hierarchical porous metal–organic frameworks with tunable porosity Duan, Chongxiong; Li, Feier; Zhang, Hang RSC Advances, Vol. 7, Issue 82 https://doi.org/10.1039/C7RA08798E	journal	January 2017
Effect of Benzoic Acid as a Modulator in the Structure of UiO-66: An Experimental and Computational Study Atzori, Cesare; Shearer, Greig C.; Maschio, Lorenzo The Journal of Physical Chemistry C, Vol. 121, Issue 17 https://doi.org/10.1021/acs.jpcc.7b00483	journal	April 2017
Construction of hierarchically porous metal–organic frameworks through linker labilization Yuan, Shuai; Zou, Lanfang; Qin, Jun-Sheng Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15356	journal	May 2017
Applications of hierarchically structured porous materials from energy storage and conversion, catalysis, photocatalysis, adsorption, separation, and sensing to biomedicine Sun, Ming-Hui; Huang, Shao-Zhuan; Chen, Li-Hua Chemical Society Reviews, Vol. 45, Issue 12 https://doi.org/10.1039/C6CS00135A	journal	January 2016
Determination of pore size and pore size distribution Kaneko, Katsumi Journal of Membrane Science, Vol. 96, Issue 1-2 https://doi.org/10.1016/0376-7388(94)00126-X	journal	November 1994
Modulator Effects on the Water-Based Synthesis of Zr/Hf Metal–Organic Frameworks: Quantitative Relationship Studies between Modulator, Synthetic Condition, and Performance Hu, Zhigang; Castano, Ioannina; Wang, Songnan Crystal Growth & Design, Vol. 16, Issue 4 https://doi.org/10.1021/acs.cgd.6b00076	journal	March 2016
Incorporating Heavy Alkanes in Metal–Organic Frameworks for Optimizing Adsorbed Natural Gas Capacity Fang, Yu; Banerjee, Sayan; Joseph, Elizabeth A. Chemistry – A European Journal, Vol. 24, Issue 64 https://doi.org/10.1002/chem.201804012	journal	July 2018
Micelles in Non‐Aqueous Media Mattoon, R. W.; Mathews, M. B. The Journal of Chemical Physics, Vol. 17, Issue 5 https://doi.org/10.1063/1.1747295	journal	May 1949
Supramolecular templating of hierarchically porous metal–organic frameworks Bradshaw, Darren; El-Hankari, Samir; Lupica-Spagnolo, Lucia Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00127C	journal	January 2014
Temperature Effect on Micelle Formation: Molecular Thermodynamic Model Revisited Khoshnood, Atefeh; Lukanov, Boris; Firoozabadi, Abbas Langmuir, Vol. 32, Issue 9 https://doi.org/10.1021/acs.langmuir.6b00039	journal	February 2016
Suspension Processing of Microporous Metal-Organic Frameworks: A Scalable Route to High-Quality Adsorbents Kirchon, Angelo; Day, Gregory S.; Fang, Yu iScience, Vol. 5 https://doi.org/10.1016/j.isci.2018.06.009	journal	July 2018

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