Modulation versus Templating: Fine‐Tuning of Hierarchally Porous PCN‐250 Using Fatty Acids To Engineer Guest Adsorption

Kirchon, Angelo; Li, Jialuo; Xia, Fangqing; Day, Gregory S.; Becker, Benjamin; Chen, Wenmiao; Sue, Hung‐Jue; Fang, Yu; Zhou, Hong‐Cai

doi:10.1002/ange.201905006

Modulation versus Templating: Fine‐Tuning of Hierarchally Porous PCN‐250 Using Fatty Acids To Engineer Guest Adsorption

Journal Article · Mon Sep 02 00:00:00 EDT 2019 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201905006· OSTI ID:1561360

Kirchon, Angelo ^[1]; Li, Jialuo ^[1]; Xia, Fangqing ^[2]; Day, Gregory S. ^[1]; Becker, Benjamin ^[1]; Chen, Wenmiao ^[1]; Sue, Hung‐Jue ^[2]; Fang, Yu ^[1]; ^[1]

Department of Chemistry Texas A&,M University College Station TX 77843-3255 USA
Department of Materials Science and Engineering Texas A&,M University College Station TX 77843-3255 USA

Abstract

Modulation and templating are two synthetic techniques that have garnered significant attention over the last several years for the preparation of hierarchically porous metal–organic frameworks (HP‐MOFs). In this study, by using fatty acids with different lengths and concentrations as dual‐functional modulators/templates, we were able to obtain HP‐MOFs with tunable mesopores that exhibit different pore diameters and locations. We found that the length and concentration of the fatty acids can determine if micelle formation occurs, which in turn dictates the porosity of the resulting HP‐MOFs. The HP‐MOFs with different mesopores differed in their performance in gas uptake and dye adsorption, and the structure–performance relationships were ascribed to the pore diameters and locations. This approach could provide a potentially universal method to efficiently introduce hierarchal mesopores into existing microporous MOF adsorbents with tunable properties.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0001015

OSTI ID:: 1561360

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 36 Vol. 131; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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