MXene-Conducting Polymer Asymmetric Pseudocapacitors

Boota, Muhammad; Gogotsi, Yury

doi:10.1002/aenm.201802917

MXene-Conducting Polymer Asymmetric Pseudocapacitors

Journal Article · Thu Dec 20 04:00:00 EST 2018 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201802917· OSTI ID:1566397

Boota, Muhammad ^[1]; ^[1]

A. J. Drexel Nanomaterials Institute, Department of Materials Science and Engineering, Drexel University, Philadelphia PA 19104 USA

Conducting polymers (CPs) are attractive pseudocapacitive materials which show the highest capacitance under positive potentials in aqueous protic electrolytes. One way to expand their voltage window (thus energy density) in aqueous electrolytes is to manufacture asymmetric supercapacitors using distinctly different anodes. However, CPs lack matching pseudocapacitive anode materials that can perform well in protic electrolytes (e.g., sulfuric acid). 2D titanium carbide (Ti₃C₂T_x), MXene, as a universal pseudocapacitive anode material for a range of CPs, such as polyaniline, polypyrrole, and poly(3,4-ethylenedioxythiophene) deposited on reduced graphene oxide (rGO) sheets, is reported here. All-pseudocapacitive organic–inorganic asymmetric devices with MXene cathodes and rGO–polymer anodes can operate in voltage windows up to 1.45 V in 3 m H₂SO₄. Most importantly, these devices show outstanding cycling performance, outperforming many reported asymmetric pseudocapacitors.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST); UT-Battelle LLC/ORNL, Oak Ridge, TN (Unted States)

Sponsoring Organization:: USDOE SC Office of Basic Energy Sciences (SC-22)

DOE Contract Number:: AC05-00OR22725

OSTI ID:: 1566397

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 7 Vol. 9; ISSN 1614-6832

Publisher:: Wiley

Country of Publication:: United States

Language:: English

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