Asymmetric Flexible MXene-Reduced Graphene Oxide Micro-Supercapacitor

Couly, Cedric; Alhabeb, Mohamed; Van Aken, Katherine L.; Kurra, Narendra; Gomes, Luisa; Navarro-Suárez, Adriana M.; Anasori, Babak; Alshareef, Husam N.; Gogotsi, Yury

doi:10.1002/aelm.201700339

Asymmetric Flexible MXene-Reduced Graphene Oxide Micro-Supercapacitor

Journal Article · Mon Nov 27 04:00:00 EST 2017 · Advanced Electronic Materials

DOI:https://doi.org/10.1002/aelm.201700339· OSTI ID:1483176

Couly, Cedric ^[1]; Alhabeb, Mohamed ^[1]; ^[1]; Kurra, Narendra ^[2]; Gomes, Luisa ^[1]; Navarro-Suárez, Adriana M. ^[3]; Anasori, Babak ^[1]; Alshareef, Husam N. ^[4]; ^[1]

Drexel Univ., Philadelphia, PA (United States)
Drexel Univ., Philadelphia, PA (United States); King Abdullah Univ. of Science and Technology (KAUST), Thuwal (Kingdom of Saudi Arabia)
Drexel Univ., Philadelphia, PA (United States); CIC energiGUNE, Alava (Spain)
King Abdullah Univ. of Science and Technology (KAUST), Thuwal (Kingdom of Saudi Arabia)

Current microfabrication of micro–supercapacitors often involves multistep processing and delicate lithography protocols. In this study, simple fabrication of an asymmetric MXene–based micro–supercapacitor that is flexible, binder–free, and current–collector–free is reported. Here, the interdigitated device architecture is fabricated using a custom–made mask and a scalable spray coating technique onto a flexible, transparent substrate. The electrode materials are comprised of titanium carbide MXene (Ti₃C₂T_x) and reduced graphene oxide (rGO), which are both 2D layered materials that contribute to the fast ion diffusion in the interdigitated electrode architecture. This MXene–based asymmetric micro–supercapacitor operates at a 1 V voltage window, while retaining 97% of the initial capacitance after ten thousand cycles, and exhibits an energy density of 8.6 mW h cm^–3 at a power density of 0.2 W cm^–3. Further, these micro–supercapacitors show a high level of flexibility during mechanical bending. Utilizing the ability of Ti₃C₂T_x–MXene electrodes to operate at negative potentials in aqueous electrolytes, it is shown that using Ti₃C₂T_x as a negative electrode and rGO as a positive one in asymmetric architectures is a promising strategy for increasing both energy and power densities of micro–supercapacitors.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1483176

Alternate ID(s):: OSTI ID: 1410379

Journal Information:: Advanced Electronic Materials, Journal Name: Advanced Electronic Materials Journal Issue: 1 Vol. 4; ISSN 2199-160X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (46)

Superior Micro-Supercapacitors Based on Graphene Quantum Dots Liu, Wen-Wen; Feng, Ya-Qiang; Yan, Xing-Bin Advanced Functional Materials, Vol. 23, Issue 33 https://doi.org/10.1002/adfm.201203771	journal	March 2013
Marker Pen Lithography for Flexible and Curvilinear On-Chip Energy Storage Jiang, Qiu; Kurra, Narendra; Alshareef, Husam N. Advanced Functional Materials, Vol. 25, Issue 31 https://doi.org/10.1002/adfm.201501698	journal	July 2015
Highly Conductive Optical Quality Solution-Processed Films of 2D Titanium Carbide Dillon, Andrew D.; Ghidiu, Michael J.; Krick, Alex L. Advanced Functional Materials, Vol. 26, Issue 23 https://doi.org/10.1002/adfm.201600357	journal	April 2016
Two-Dimensional Nanocrystals Produced by Exfoliation of Ti₃AlC₂ Naguib, Michael; Kurtoglu, Murat; Presser, Volker Advanced Materials, Vol. 23, Issue 37, p. 4248-4253 https://doi.org/10.1002/adma.201102306	journal	August 2011
All-Solid-State Flexible Ultrathin Micro-Supercapacitors Based on Graphene Niu, Zhiqiang; Zhang, Li; Liu, Lili Advanced Materials, Vol. 25, Issue 29 https://doi.org/10.1002/adma.201301332	journal	May 2013
Synthesis of Two-Dimensional Materials for Capacitive Energy Storage Mendoza-Sánchez, Beatriz; Gogotsi, Yury Advanced Materials, Vol. 28, Issue 29 https://doi.org/10.1002/adma.201506133	journal	June 2016
Effect of Synthesis on Quality, Electronic Properties and Environmental Stability of Individual Monolayer Ti ₃ C ₂ MXene Flakes Lipatov, Alexey; Alhabeb, Mohamed; Lukatskaya, Maria R. Advanced Electronic Materials, Vol. 2, Issue 12 https://doi.org/10.1002/aelm.201600255	journal	November 2016
Ultrasmall Integrated 3D Micro-Supercapacitors Solve Energy Storage for Miniature Devices Meng, Chuizhou; Maeng, Jimin; John, Simon W. M. Advanced Energy Materials, Vol. 4, Issue 7 https://doi.org/10.1002/aenm.201301269	journal	December 2013
Microfabricated Pseudocapacitors Using Ni(OH) ₂ Electrodes Exhibit Remarkable Volumetric Capacitance and Energy Density Kurra, Narendra; Alhebshi, Nuha A.; Alshareef, H. N. Advanced Energy Materials, Vol. 5, Issue 2 https://doi.org/10.1002/aenm.201401303	journal	September 2014
MXene-on-Paper Coplanar Microsupercapacitors Kurra, Narendra; Ahmed, Bilal; Gogotsi, Yury Advanced Energy Materials, Vol. 6, Issue 24 https://doi.org/10.1002/aenm.201601372	journal	September 2016
Formulation of Ionic-Liquid Electrolyte To Expand the Voltage Window of Supercapacitors Van Aken, Katherine L.; Beidaghi, Majid; Gogotsi, Yury Angewandte Chemie, Vol. 127, Issue 16 https://doi.org/10.1002/ange.201412257	journal	March 2015
Formulation of Ionic-Liquid Electrolyte To Expand the Voltage Window of Supercapacitors Van Aken, Katherine L.; Beidaghi, Majid; Gogotsi, Yury Angewandte Chemie International Edition, Vol. 54, Issue 16 https://doi.org/10.1002/anie.201412257	journal	March 2015
A Review of Graphene-Based Electrochemical Microsupercapacitors Xiong, Guoping; Meng, Chuizhou; Reifenberger, Ronald G. Electroanalysis, Vol. 26, Issue 1 https://doi.org/10.1002/elan.201300238	journal	November 2013
Elaboration of a microstructured inkjet-printed carbon electrochemical capacitor Pech, David; Brunet, Magali; Taberna, Pierre-Louis Journal of Power Sources, Vol. 195, Issue 4, p. 1266-1269 https://doi.org/10.1016/j.jpowsour.2009.08.085	journal	February 2010
Capacitance of two-dimensional titanium carbide (MXene) and MXene/carbon nanotube composites in organic electrolytes Dall’Agnese, Yohan; Rozier, Patrick; Taberna, Pierre-Louis Journal of Power Sources, Vol. 306 https://doi.org/10.1016/j.jpowsour.2015.12.036	journal	February 2016
Freestanding functionalized carbon nanotube-based electrode for solid-state asymmetric supercapacitors Xiao, Xu; Li, Tianqi; Peng, Zehua Nano Energy, Vol. 6 https://doi.org/10.1016/j.nanoen.2014.02.014	journal	May 2014
A general strategy for the fabrication of high performance microsupercapacitors Kurra, Narendra; Jiang, Qiu; Alshareef, H. N. Nano Energy, Vol. 16 https://doi.org/10.1016/j.nanoen.2015.05.031	journal	September 2015
Toward self-powered sensor networks Wang, Zhong Lin Nano Today, Vol. 5, Issue 6 https://doi.org/10.1016/j.nantod.2010.09.001	journal	December 2010
New Insights into the Structure of Nanoporous Carbons from NMR, Raman, and Pair Distribution Function Analysis Forse, Alexander C.; Merlet, Céline; Allan, Phoebe K. Chemistry of Materials, Vol. 27, Issue 19 https://doi.org/10.1021/acs.chemmater.5b03216	journal	September 2015
Resolving the Structure of Ti ₃ C ₂ T _x MXenes through Multilevel Structural Modeling of the Atomic Pair Distribution Function Wang, Hsiu-Wen; Naguib, Michael; Page, Katharine Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b04250	journal	December 2015
Micro-Pseudocapacitors with Electroactive Polymer Electrodes: Toward AC-Line Filtering Applications Kurra, Narendra; Jiang, Qiu; Syed, Ahad ACS Applied Materials & Interfaces, Vol. 8, Issue 20 https://doi.org/10.1021/acsami.5b12784	journal	May 2016
Atomic Defects in Monolayer Titanium Carbide (Ti ₃ C ₂ T _x ) MXene Sang, Xiahan; Xie, Yu; Lin, Ming-Wei ACS Nano, Vol. 10, Issue 10 https://doi.org/10.1021/acsnano.6b05240	journal	September 2016
Preparation of Graphitic Oxide Hummers, William S.; Offeman, Richard E. Journal of the American Chemical Society, Vol. 80, Issue 6, p. 1339-1339 https://doi.org/10.1021/ja01539a017	journal	March 1958
Ultrathin Planar Graphene Supercapacitors Yoo, Jung Joon; Balakrishnan, Kaushik; Huang, Jingsong Nano Letters, Vol. 11, Issue 4 https://doi.org/10.1021/nl200225j	journal	April 2011
2D metal carbides and nitrides (MXenes) for energy storage Anasori, Babak; Lukatskaya, Maria R.; Gogotsi, Yury Nature Reviews Materials, Vol. 2, Issue 2 https://doi.org/10.1038/natrevmats.2016.98	journal	January 2017
Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance Ghidiu, Michael; Lukatskaya, Maria R.; Zhao, Meng-Qiang Nature, Vol. 516, Issue 7529 https://doi.org/10.1038/nature13970	journal	November 2014
Scalable fabrication of high-power graphene micro-supercapacitors for flexible and on-chip energy storage El-Kady, Maher F.; Kaner, Richard B. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2446	journal	February 2013
Graphene-based in-plane micro-supercapacitors with high power and energy densities Wu, Zhong–Shuai; Parvez, Khaled; Feng, Xinliang Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3487	journal	September 2013
Processable aqueous dispersions of graphene nanosheets Li, Dan; Müller, Marc B.; Gilje, Scott Nature Nanotechnology, Vol. 3, Issue 2 https://doi.org/10.1038/nnano.2007.451	journal	January 2008
Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon Pech, David; Brunet, Magali; Durou, Hugo Nature Nanotechnology, Vol. 5, Issue 9, p. 651-654 https://doi.org/10.1038/nnano.2010.162	journal	August 2010
Direct laser writing of micro-supercapacitors on hydrated graphite oxide films Gao, Wei; Singh, Neelam; Song, Li Nature Nanotechnology, Vol. 6, Issue 8 https://doi.org/10.1038/nnano.2011.110	journal	July 2011
Microsupercapacitors as miniaturized energy-storage components for on-chip electronics Kyeremateng, Nana Amponsah; Brousse, Thierry; Pech, David Nature Nanotechnology, Vol. 12, Issue 1 https://doi.org/10.1038/nnano.2016.196	journal	November 2016
Studying disorder in graphite-based systems by Raman spectroscopy Pimenta, M. A.; Dresselhaus, G.; Dresselhaus, M. S. Phys. Chem. Chem. Phys., Vol. 9, Issue 11 https://doi.org/10.1039/B613962K	journal	January 2007
Multifunctional 3D nanoarchitectures for energy storage and conversion Rolison, Debra R.; Long, Jeffrey W.; Lytle, Justin C. Chemical Society Reviews, Vol. 38, Issue 1, p. 226-252 https://doi.org/10.1039/B801151F	journal	January 2009
All-MXene (2D titanium carbide) solid-state microsupercapacitors for on-chip energy storage Peng, You-Yu; Akuzum, Bilen; Kurra, Narendra Energy & Environmental Science, Vol. 9, Issue 9 https://doi.org/10.1039/C6EE01717G	journal	January 2016
A high-performance current collector-free flexible in-plane micro-supercapacitor based on a highly conductive reduced graphene oxide film Wu, Mingmao; Li, Yingru; Yao, Bowen Journal of Materials Chemistry A, Vol. 4, Issue 41 https://doi.org/10.1039/C6TA06846D	journal	January 2016
Capacitive energy storage in micro-scale devices: recent advances in design and fabrication of micro-supercapacitors Beidaghi, Majid; Gogotsi, Yury Energy & Environmental Science, Vol. 7, Issue 3 https://doi.org/10.1039/c3ee43526a	journal	January 2014
Novel and high-performance asymmetric micro-supercapacitors based on graphene quantum dots and polyaniline nanofibers Liu, Wenwen; Yan, Xingbin; Chen, Jiangtao Nanoscale, Vol. 5, Issue 13 https://doi.org/10.1039/c3nr01139a	journal	January 2013
Photolithographic fabrication of high-performance all-solid-state graphene-based planar micro-supercapacitors with different interdigital fingers Wu, Zhong-Shuai; Parvez, Khaled; Feng, Xinliang Journal of Materials Chemistry A, Vol. 2, Issue 22 https://doi.org/10.1039/c4ta00958d	journal	January 2014
Flexible and conductive MXene films and nanocomposites with high capacitance Ling, Zheng; Ren, Chang E.; Zhao, Meng-Qiang Proceedings of the National Academy of Sciences, Vol. 111, Issue 47 https://doi.org/10.1073/pnas.1414215111	journal	November 2014
Interpretation of Raman spectra of disordered and amorphous carbon Ferrari, A. C.; Robertson, J. Physical Review B, Vol. 61, Issue 20, p. 14095-14107 https://doi.org/10.1103/PhysRevB.61.14095	journal	May 2000
Monolithic Carbide-Derived Carbon Films for Micro-Supercapacitors Chmiola, J.; Largeot, C.; Taberna, P. L. Science, Vol. 328, Issue 5977 https://doi.org/10.1126/science.1184126	journal	April 2010
Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide Lukatskaya, M. R.; Mashtalir, O.; Ren, C. E. Science, Vol. 341, Issue 6153 https://doi.org/10.1126/science.1241488	journal	September 2013
On-chip and freestanding elastic carbon films for micro-supercapacitors Huang, P.; Lethien, C.; Pinaud, S. Science, Vol. 351, Issue 6274 https://doi.org/10.1126/science.aad3345	journal	February 2016
Electromagnetic interference shielding with 2D transition metal carbides (MXenes) Shahzad, F.; Alhabeb, M.; Hatter, C. B. Science, Vol. 353, Issue 6304 https://doi.org/10.1126/science.aag2421	journal	September 2016
New insights into the structure of nanoporous carbons from NMR, Raman, and pair distribution function analysis Forse, Alexander C.; Merlet, Céline; Allan, Phoebe K. Washington D.C. : American Chemical Society https://doi.org/10.34657/1589	null	January 2015

Cited By (40)

Electrochromic Effect in Titanium Carbide MXene Thin Films Produced by Dip‐Coating Salles, Pol; Pinto, David; Hantanasirisakul, Kanit Advanced Functional Materials, Vol. 29, Issue 17 https://doi.org/10.1002/adfm.201809223	journal	February 2019
Recent Development of Printed Micro‐Supercapacitors: Printable Materials, Printing Technologies, and Perspectives Li, Hongpeng; Liang, Jiajie Advanced Materials, Vol. 32, Issue 3 https://doi.org/10.1002/adma.201805864	journal	April 2019
Doping Effects and Charge-Transfer Dynamics at Hybrid Perovskite/Graphene Interfaces Brus, Viktor V.; Lang, Felix; Fengler, Steffen Advanced Materials Interfaces, Vol. 5, Issue 20 https://doi.org/10.1002/admi.201800826	journal	August 2018
MXene‐Based Composites: Synthesis and Applications in Rechargeable Batteries and Supercapacitors Yang, Jian; Bao, Weizhai; Jaumaux, Pauline Advanced Materials Interfaces, Vol. 6, Issue 8 https://doi.org/10.1002/admi.201802004	journal	February 2019
Direct Laser Etching Free‐Standing MXene‐MoS ₂ Film for Highly Flexible Micro‐Supercapacitor Chen, Xing; Wang, Siliang; Shi, Junjie Advanced Materials Interfaces, Vol. 6, Issue 22 https://doi.org/10.1002/admi.201901160	journal	September 2019
Graphene-Based Planar Microsupercapacitors: Recent Advances and Future Challenges Liang, Jiaxing; Mondal, Anjon Kumar; Wang, Da-Wei Advanced Materials Technologies, Vol. 4, Issue 1 https://doi.org/10.1002/admt.201800200	journal	October 2018
Hydrous RuO ₂ ‐Decorated MXene Coordinating with Silver Nanowire Inks Enabling Fully Printed Micro‐Supercapacitors with Extraordinary Volumetric Performance Li, Hongpeng; Li, Xiran; Liang, Jiajie Advanced Energy Materials, Vol. 9, Issue 15 https://doi.org/10.1002/aenm.201803987	journal	February 2019
On‐Chip MXene Microsupercapacitors for AC‐Line Filtering Applications Jiang, Qiu; Kurra, Narendra; Maleski, Kathleen Advanced Energy Materials https://doi.org/10.1002/aenm.201901061	journal	May 2019
Ti ₃ C ₂ T _x (MXene)‐Silicon Heterojunction for Efficient Photovoltaic Cells Yu, LePing; Bati, Abdulaziz S. R.; Grace, Tom S. L. Advanced Energy Materials, Vol. 9, Issue 31 https://doi.org/10.1002/aenm.201901063	journal	July 2019
Antimonene Engineered Highly Deformable Freestanding Electrode with Extraordinarily Improved Energy Storage Performance Yu, Jiali; Zhou, Jie; Yao, Pingping Advanced Energy Materials, Vol. 9, Issue 44 https://doi.org/10.1002/aenm.201902462	journal	October 2019
Advanced Electrode Materials Comprising of Structure‐Engineered Quantum Dots for High‐Performance Asymmetric Micro‐Supercapacitors Liu, Wenwen; Zhang, Maiwen; Li, Matthew Advanced Energy Materials, Vol. 10, Issue 8 https://doi.org/10.1002/aenm.201903724	journal	January 2020
Selective Etching of Silicon from Ti 3 SiC 2 (MAX) To Obtain 2D Titanium Carbide (MXene) Alhabeb, Mohamed; Maleski, Kathleen; Mathis, Tyler S. Angewandte Chemie, Vol. 130, Issue 19 https://doi.org/10.1002/ange.201802232	journal	March 2018
Selective Etching of Silicon from Ti ₃ SiC ₂ (MAX) To Obtain 2D Titanium Carbide (MXene) Alhabeb, Mohamed; Maleski, Kathleen; Mathis, Tyler S. Angewandte Chemie International Edition, Vol. 57, Issue 19 https://doi.org/10.1002/anie.201802232	journal	March 2018
Fabrication of Cobaltosic Oxide Nanoparticle‐Doped 3 D MXene/Graphene Hybrid Porous Aerogels for All‐Solid‐State Supercapacitors Liu, Rui; Zhang, Aitang; Tang, Jianguo Chemistry – A European Journal, Vol. 25, Issue 21 https://doi.org/10.1002/chem.201806342	journal	March 2019
Laser‐Cutting Fabrication of Mxene‐Based Flexible Micro‐Supercapacitors with High Areal Capacitance Wang, Na; Liu, Jinzhang; Zhao, Yi ChemNanoMat, Vol. 5, Issue 5 https://doi.org/10.1002/cnma.201800674	journal	March 2019
Miniaturized Energy Storage Devices Based on Two‐Dimensional Materials Jiang, Kang; Weng, Qunhong ChemSusChem, Vol. 13, Issue 6 https://doi.org/10.1002/cssc.201902520	journal	March 2020
Recent Progress of MXene-Based Nanomaterials in Flexible Energy Storage and Electronic Devices Yang, Qi; Wang, Yukun; Li, Xinliang Energy & Environmental Materials, Vol. 1, Issue 4 https://doi.org/10.1002/eem2.12023	journal	December 2018
Laser-Assisted Large-Scale Fabrication of All-Solid-State Asymmetrical Micro-Supercapacitor Array Gao, Jian; Shao, Changxiang; Shao, Shengxian Small, Vol. 14, Issue 37 https://doi.org/10.1002/smll.201801809	journal	August 2018
Automated Scalpel Patterning of Solution Processed Thin Films for Fabrication of Transparent MXene Microsupercapacitors Salles, Pol; Quain, Evan; Kurra, Narendra Small, Vol. 14, Issue 44 https://doi.org/10.1002/smll.201802864	journal	October 2018
A Conductive and Highly Deformable All-Pseudocapacitive Composite Paper as Supercapacitor Electrode with Improved Areal and Volumetric Capacitance Zhou, Jie; Yu, Jiali; Shi, Ludi Small, Vol. 14, Issue 51 https://doi.org/10.1002/smll.201803786	journal	November 2018
An Ultrafast Conducting Polymer@MXene Positive Electrode with High Volumetric Capacitance for Advanced Asymmetric Supercapacitors Li, Ke; Wang, Xuehang; Li, Shuo Small, Vol. 16, Issue 4 https://doi.org/10.1002/smll.201906851	journal	December 2019
Recent Advances in Design of Flexible Electrodes for Miniaturized Supercapacitors Yu, Chenyang; An, Jianing; Chen, Qiang Small Methods, Vol. 4, Issue 6 https://doi.org/10.1002/smtd.201900824	journal	February 2020
Electrodeposition of polypyrrole on He plasma etched carbon nanotube films for electrodes of flexible all-solid-state supercapacitor Han, Yichuan; Chen, Peishan; Xia, Yanfei Journal of Solid State Electrochemistry, Vol. 23, Issue 5 https://doi.org/10.1007/s10008-019-04242-4	journal	March 2019
Flexible asymmetric microsupercapacitor with high energy density based on all-graphene electrode system Siddique, Ahmad Hassan; Bokhari, Syeda Wishal; Butt, Rehman Journal of Materials Science, Vol. 55, Issue 1 https://doi.org/10.1007/s10853-019-03987-7	journal	September 2019
Carbon nanotubes enhance flexible MXene films for high-rate supercapacitors Chen, He; Yu, Lanyong; Lin, Zifeng Journal of Materials Science, Vol. 55, Issue 3 https://doi.org/10.1007/s10853-019-04003-8	journal	September 2019
Review of MXenes as new nanomaterials for energy storage/delivery and selected environmental applications Jun, Byung-Moon; Kim, Sewoon; Heo, Jiyong Nano Research, Vol. 12, Issue 3 https://doi.org/10.1007/s12274-018-2225-3	journal	October 2018
Supercapacitors based on free-standing reduced graphene oxides/carbon nanotubes hybrid films Yang, Zhi-Guang; Liu, Ning-Ning; Dong, Shuo SN Applied Sciences, Vol. 1, Issue 1 https://doi.org/10.1007/s42452-018-0059-y	journal	November 2018
Applications of 2D MXenes in energy conversion and storage systems Pang, Jinbo; Mendes, Rafael G.; Bachmatiuk, Alicja Chemical Society Reviews, Vol. 48, Issue 1 https://doi.org/10.1039/c8cs00324f	journal	January 2019
Flexible Ti ₃ C ₂ T _x /PEDOT:PSS films with outstanding volumetric capacitance for asymmetric supercapacitors Li, Lu; Zhang, Na; Zhang, Mingyi Dalton Transactions, Vol. 48, Issue 5 https://doi.org/10.1039/c8dt04374d	journal	January 2019
Processing and manufacturing of graphene-based microsupercapacitors Zhang, Guofeng; Han, Yuyang; Shao, Changxiang Materials Chemistry Frontiers, Vol. 2, Issue 10 https://doi.org/10.1039/c8qm00270c	journal	January 2018
Micro-supercapacitors based on oriented coordination polymer thin films for AC line-filtering Hua, Weiwei; Xiu, Jingwei; Xiu, Fei RSC Advances, Vol. 8, Issue 53 https://doi.org/10.1039/c8ra06474a	journal	January 2018
2D layered organic–inorganic heterostructures for clean energy applications Azadmanjiri, Jalal; Wang, James; Berndt, Christopher C. Journal of Materials Chemistry A, Vol. 6, Issue 9 https://doi.org/10.1039/c8ta00132d	journal	January 2018
Reactive laser synthesis of nitrogen-doped hybrid graphene-based electrodes for energy storage Pérez del Pino, Ángel; Martínez Villarroya, Andreu; Chuquitarqui, Alex Journal of Materials Chemistry A, Vol. 6, Issue 33 https://doi.org/10.1039/c8ta03830a	journal	January 2018
Spontaneous MXene monolayer assembly at the liquid–air interface Petukhov, D. I.; Chumakov, A. P.; Kan, A. S. Nanoscale, Vol. 11, Issue 20 https://doi.org/10.1039/c9nr00525k	journal	January 2019
Fully inkjet printed ultrathin microsupercapacitors based on graphene electrodes and a nano-graphene oxide electrolyte Sollami Delekta, Szymon; Adolfsson, Karin H.; Benyahia Erdal, Nejla Nanoscale, Vol. 11, Issue 21 https://doi.org/10.1039/c9nr01427f	journal	January 2019
Insights into the thermal and chemical stability of multilayered V ₂ CT _x MXene Thakur, Raj; VahidMohammadi, Armin; Moncada, Jorge Nanoscale, Vol. 11, Issue 22 https://doi.org/10.1039/c9nr03020d	journal	January 2019
A high-performance trace level acetone sensor using an indispensable V ₄ C ₃ T _x MXene Zhao, Wei-Na; Yun, Na; Dai, Zhen-Hua RSC Advances, Vol. 10, Issue 3 https://doi.org/10.1039/c9ra09069j	journal	January 2020
Ionic liquid pre-intercalated MXene films for ionogel-based flexible micro-supercapacitors with high volumetric energy density Zheng, Shuanghao; Zhang, Chuanfang (John); Zhou, Feng Journal of Materials Chemistry A, Vol. 7, Issue 16 https://doi.org/10.1039/c9ta02190f	journal	January 2019
3D printing-based cellular microelectrodes for high-performance asymmetric quasi-solid-state micro-pseudocapacitors Wang, Teng; Tian, Xiaocong; Li, Liang Journal of Materials Chemistry A, Vol. 8, Issue 4 https://doi.org/10.1039/c9ta11386j	journal	January 2020
Investigation on the Performance Improvement of Polyacrylonitrile-Derived Flexible Electrospun Carbon Nanofiber Mats He, Xin; Lan, Qiuming; Zhao, Sirou Applied Sciences, Vol. 9, Issue 18 https://doi.org/10.3390/app9183683	journal	September 2019

Similar Records

Flexible MXene/Graphene Films for Ultrafast Supercapacitors with Outstanding Volumetric Capacitance

Journal Article · Fri Jun 30 00:00:00 EDT 2017 · Advanced Functional Materials · OSTI ID:1399231

Related Subjects

36 MATERIALS SCIENCE
MXene
asymmetric architectures
flexible electronics
graphene
micro-supercapacitors

Asymmetric Flexible MXene-Reduced Graphene Oxide Micro-Supercapacitor

Citation Formats

References (46)

Cited By (40)

Similar Records

Related Subjects