A path for synthesis of boron-nitride nanostructures in volume of arc plasma

Han, Longtao; Krstić, Predrag

doi:10.1088/1361-6528/aa5653

A path for synthesis of boron-nitride nanostructures in volume of arc plasma

Journal Article · Thu Jan 12 04:00:00 EST 2017 · Nanotechnology

DOI:https://doi.org/10.1088/1361-6528/aa5653· OSTI ID:1565600

Han, Longtao ^[1]; Krstić, Predrag ^[1]

Stony Brook Univ., NY (United States). Inst. for Advanced Computational Science and Dept. of Materials Science and Engineering

We find a possible channel for direct nanosynthesis of boron-nitride (BN) nanostructures, including growth of BN nanotubes from a mixture of BN diatomic molecules by quantum–classical molecular dynamics simulations. No catalyst or boron nanoparticle is needed for this synthesis, however the conditions for the synthesis of each of the nanostructures, such as temperature and flux of the BN feedstock are identified and are compatible with the conditions in an electric arc at high pressure. We also find that BN nanostructures can be synthetized by feeding a boron nanoparticle by BN diatomic molecules, however if hydrogen rich molecules like NH3 or HBNH are used as a feedstock, two-dimensional nanoflake stable structures are formed.

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Oak Ridge Leadership Computing Facility (OLCF)

Sponsoring Organization:: USDOE Office of Science

OSTI ID:: 1565600

Journal Information:: Nanotechnology, Journal Name: Nanotechnology Journal Issue: 7 Vol. 28; ISSN 0957-4484

Publisher:: IOP Publishing

Country of Publication:: United States

Language:: English

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