Shape-controlled synthesis and in situ characterisation of anisotropic Au nanomaterials using liquid cell transmission electron microscopy

Wang, Shih-Ting; Lin, Yiyang; Nielsen, Michael H.; Song, Cheng Yu; Thomas, Michael R.; Spicer, Christopher D.; Kröger, Roland; Ercius, Peter; Aloni, Shaul; Stevens, Molly M.

doi:10.1039/c9nr01474h

Title: Shape-controlled synthesis and in situ characterisation of anisotropic Au nanomaterials using liquid cell transmission electron microscopy

Journal Article · Fri Aug 30 00:00:00 EDT 2019 · Nanoscale

DOI:https://doi.org/10.1039/c9nr01474h· OSTI ID:1561948

^[1];

^[2]; Song, Cheng Yu ^[3];

^[1];

^[4];

^[3]; Aloni, Shaul ^[3];

^[1]

Imperial College, London (United Kingdom)
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry
Univ. of York, Heslington (United Kingdom)

Understanding the mechanisms behind crystal nucleation and growth is a fundamental requirement for the design and production of bespoke nanomaterials with controlled sizes and morphologies. In this work, we select gold (Au) nanoparticles as the model system for our study due to their representative applications in biology, electronics and optoelectronics. We investigate the radiation-induced in situ growth of gold (Au) particles using liquid cell transmission electron microscopy (LCTEM) and study the growth kinetics of non-spherical Au structures. Under controlled electron fluence, liquid flow rate and Au³⁺ ion supply, we show the favoured diffusion-limited growth of multi-twinned nascent Au seed particles into branched structures when using thin liquid cells (100 nm and 250 nm) in LCTEM, whereas faceted structures (e.g., spheres, rods, and prisms) formed when using a 1 μm thick liquid cell. In addition, we observed that anisotropic Au growth could be modulated by Au-binding amyloid fibrils, which we ascribe to their capability to regulate Au³⁺ ion diffusion and mass transfer in solution. We anticipate that this study will provide new perspectives on the shape-controlled synthesis of anisotropic metallic nanomaterials using LCTEM.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Molecular Foundry; Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); Taiwan Strategic Alliance Scholarship; Engineering and Physical Sciences Research Council (EPSRC); Lawrence Fellowship; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: AC02-05CH11231; AC52-07NA27344; EP/K020641/1

OSTI ID:: 1561948

Alternate ID(s):: OSTI ID: 1562738; OSTI ID: 1692266

Report Number(s):: LLNL-JRNL-805912; NANOHL; ark:/13030/qt5qz910p9

Journal Information:: Nanoscale, Vol. 11, Issue 36; ISSN 2040-3364

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 7 works

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References (81)

Optical Properties of Star-Shaped Gold Nanoparticles Nehl, Colleen L.; Liao, Hongwei; Hafner, Jason H. Nano Letters, Vol. 6, Issue 4 https://doi.org/10.1021/nl052409y	journal	April 2006
Electron microscopy of specimens in liquid de Jonge, Niels; Ross, Frances M. Nature Nanotechnology, Vol. 6, Issue 11, p. 695-704 https://doi.org/10.1038/nnano.2011.161	journal	October 2011
Templated Techniques for the Synthesis and Assembly of Plasmonic Nanostructures Jones, Matthew R.; Osberg, Kyle D.; Macfarlane, Robert J. Chemical Reviews, Vol. 111, Issue 6 https://doi.org/10.1021/cr1004452	journal	June 2011
Temperature dependence of solvated electron diffusion in water and water-d2 Schmidt, K. H.; Han, P.; Bartels, D. M. The Journal of Physical Chemistry, Vol. 96, Issue 1 https://doi.org/10.1021/j100180a039	journal	January 1992
Shape control in gold nanoparticle synthesis Grzelczak, Marek; Pérez-Juste, Jorge; Mulvaney, Paul Chemical Society Reviews, Vol. 37, Issue 9 https://doi.org/10.1039/b711490g	journal	January 2008
Controlled Nucleation for the Regulation of the Particle Size in Monodisperse Gold Suspensions Frens, G. Nature Physical Science, Vol. 241, Issue 105, p. 20-22 https://doi.org/10.1038/physci241020a0	journal	January 1973
Synthesis of gold structures by gold-binding peptide governed by concentration of gold ion and peptide Kim, Jungok; Kim, Dong-Hun; Lee, Sylvia J. Bioscience, Biotechnology, and Biochemistry, Vol. 80, Issue 8 https://doi.org/10.1080/09168451.2016.1176516	journal	April 2016
Gold Nanostars For Surface-Enhanced Raman Scattering: Synthesis, Characterization and Optimization Khoury, Christopher G.; Vo-Dinh, Tuan The Journal of Physical Chemistry C, Vol. 112, Issue 48 https://doi.org/10.1021/jp8054747	journal	November 2008
Bubble and Pattern Formation in Liquid Induced by an Electron Beam Grogan, Joseph M.; Schneider, Nicholas M.; Ross, Frances M. Nano Letters, Vol. 14, Issue 1 https://doi.org/10.1021/nl404169a	journal	December 2013
Mechanism and kinetics of hydrated electron diffusion Tay, Kafui A.; Coudert, François-Xavier; Boutin, Anne The Journal of Chemical Physics, Vol. 129, Issue 5 https://doi.org/10.1063/1.2964101	journal	August 2008
Mechanisms of Nucleation and Growth of Nanoparticles in Solution Thanh, Nguyen T. K.; Maclean, N.; Mahiddine, S. Chemical Reviews, Vol. 114, Issue 15 https://doi.org/10.1021/cr400544s	journal	July 2014
Crystallization by particle attachment in synthetic, biogenic, and geologic environments De Yoreo, J. J.; Gilbert, P. U. P. A.; Sommerdijk, N. A. J. M. Science, Vol. 349, Issue 6247 https://doi.org/10.1126/science.aaa6760	journal	July 2015
Observation of Single Colloidal Platinum Nanocrystal Growth Trajectories Zheng, H.; Smith, R. K.; Jun, Y. -w. Science, Vol. 324, Issue 5932 https://doi.org/10.1126/science.1172104	journal	June 2009
In situ TEM imaging of CaCO3 nucleation reveals coexistence of direct and indirect pathways Nielsen, M. H.; Aloni, S.; De Yoreo, J. J. Science, Vol. 345, Issue 6201 https://doi.org/10.1126/science.1254051	journal	September 2014
Defining the radiation chemistry during liquid cell electron microscopy to enable visualization of nanomaterial growth and degradation dynamics: DEFINING THE RADIATION CHEMISTRY DURING LCEM Woehl, T. J.; Abellan, P. Journal of Microscopy, Vol. 265, Issue 2 https://doi.org/10.1111/jmi.12508	journal	December 2016
In Situ Liquid Cell Electron Microscopy of the Solution Growth of Au–Pd Core–Shell Nanostructures Jungjohann, K. L.; Bliznakov, S.; Sutter, P. W. Nano Letters, Vol. 13, Issue 6 https://doi.org/10.1021/nl4014277	journal	May 2013
Nucleus interaction and fine structures of colloidal gold particles Uyeda, Natsu; Nishino, Misao; Suito, Eiji Journal of Colloid and Interface Science, Vol. 43, Issue 2 https://doi.org/10.1016/0021-9797(73)90374-3	journal	May 1973
Calcium carbonate nucleation driven by ion binding in a biomimetic matrix revealed by in situ electron microscopy Smeets, Paul J. M.; Cho, Kang Rae; Kempen, Ralph G. E. Nature Materials, Vol. 14, Issue 4 https://doi.org/10.1038/nmat4193	journal	January 2015
Avoiding drying-artifacts in transmission electron microscopy: Characterizing the size and colloidal state of nanoparticles Michen, Benjamin; Geers, Christoph; Vanhecke, Dimitri Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep09793	journal	May 2015
Spatially dependent dose rate in liquid cell transmission electron microscopy Gupta, Tanya; Schneider, Nicholas M.; Park, Jeung Hun Nanoscale, Vol. 10, Issue 16 https://doi.org/10.1039/C8NR01935E	journal	January 2018
Factors influencing quantitative liquid (scanning) transmission electron microscopy Abellan, P.; Woehl, T. J.; Parent, L. R. Chem. Commun., Vol. 50, Issue 38 https://doi.org/10.1039/C3CC48479C	journal	January 2014
Influence of Cetyltrimethylammonium Bromide on Gold Nanocrystal Formation Studied by In Situ Liquid Cell Scanning Transmission Electron Microscopy Canepa, Silvia A.; Sneed, Brian T.; Sun, Hongyu The Journal of Physical Chemistry C, Vol. 122, Issue 4 https://doi.org/10.1021/acs.jpcc.7b06383	journal	January 2018
Electron–Water Interactions and Implications for Liquid Cell Electron Microscopy Schneider, Nicholas M.; Norton, Michael M.; Mendel, Brian J. The Journal of Physical Chemistry C, Vol. 118, Issue 38 https://doi.org/10.1021/jp507400n	journal	September 2014
Opportunities and challenges in liquid cell electron microscopy Ross, F. M. Science, Vol. 350, Issue 6267 https://doi.org/10.1126/science.aaa9886	journal	December 2015
Microfluidic System for Transmission Electron Microscopy Ring, Elisabeth A.; de Jonge, Niels Microscopy and Microanalysis, Vol. 16, Issue 5 https://doi.org/10.1017/S1431927610093669	journal	August 2010
Droplet-Based Microfluidic Synthesis of Anisotropic Metal Nanocrystals Duraiswamy, Suhanya; Khan, Saif A. Small, Vol. 5, Issue 24 https://doi.org/10.1002/smll.200901453	journal	December 2009
Electric Field Induced Au Nanocrystal Formation in Aqueous Solutions Hun Park, Jeung; Reuter, Mark C.; Kodambaka, Suneel Microscopy and Microanalysis, Vol. 20, Issue S3 https://doi.org/10.1017/S1431927614009726	journal	August 2014
In-situ liquid-cell TEM study of radial flow-guided motion of octahedral Au nanoparticles and nanoparticle clusters Li, Chang; Chen, Xin; Liu, Haiyang Nano Research, Vol. 11, Issue 9 https://doi.org/10.1007/s12274-018-2052-6	journal	April 2018
Microfluidic continuous flow synthesis of rod-shaped gold and silver nanocrystals Boleininger, Johann; Kurz, Andreas; Reuss, Valerie Phys. Chem. Chem. Phys., Vol. 8, Issue 33 https://doi.org/10.1039/B604666E	journal	January 2006
Dynamic microscopy of nanoscale cluster growth at the solid–liquid interface Williamson, M. J.; Tromp, R. M.; Vereecken, P. M. Nature Materials, Vol. 2, Issue 8 https://doi.org/10.1038/nmat944	journal	July 2003
The kinetics of precipitation from supersaturated solid solutions Lifshitz, I. M.; Slyozov, V. V. Journal of Physics and Chemistry of Solids, Vol. 19, Issue 1-2 https://doi.org/10.1016/0022-3697(61)90054-3	journal	April 1961
Anisotropic Metal Nanoparticles: Synthesis, Assembly, and Optical Applications Murphy, Catherine J.; Sau, Tapan K.; Gole, Anand M. The Journal of Physical Chemistry B, Vol. 109, Issue 29 https://doi.org/10.1021/jp0516846	journal	July 2005
Multistep nucleation of nanocrystals in aqueous solution Loh, N. Duane; Sen, Soumyo; Bosman, Michel Nature Chemistry, Vol. 9, Issue 1 https://doi.org/10.1038/nchem.2618	journal	October 2016
Synthesis and Optical Properties of “Branched” Gold Nanocrystals Hao, Encai; Bailey, Ryan C.; Schatz, George C. Nano Letters, Vol. 4, Issue 2, p. 327-330 https://doi.org/10.1021/nl0351542	journal	February 2004
Excess electron migration in liquid water Schnitker, Jurgen; Rossky, Peter J. The Journal of Physical Chemistry, Vol. 93, Issue 19 https://doi.org/10.1021/j100356a017	journal	September 1989
Symmetry breaking during nanocrystal growth Gilroy, Kyle D.; Peng, Hsin-Chieh; Yang, Xuan Chemical Communications, Vol. 53, Issue 33 https://doi.org/10.1039/C7CC01121K	journal	January 2017
Electric-Field-Directed Growth of Gold Nanorods in Aqueous Surfactant Solutions Pérez-Juste, J.; Liz-Marzán, L. M.; Carnie, S. Advanced Functional Materials, Vol. 14, Issue 6 https://doi.org/10.1002/adfm.200305068	journal	June 2004
Microfluidic Synthesis of Nanomaterials Song, Yujun; Hormes, Josef; Kumar, Challa S. S. R. Small, Vol. 4, Issue 6 https://doi.org/10.1002/smll.200701029	journal	June 2008
Growth of Au on Pt Icosahedral Nanoparticles Revealed by Low-Dose In Situ TEM Wu, Jianbo; Gao, Wenpei; Wen, Jianguo Nano Letters, Vol. 15, Issue 4 https://doi.org/10.1021/acs.nanolett.5b00414	journal	March 2015
Tuning Size and Sensing Properties in Colloidal Gold Nanostars Barbosa, Silvia; Agrawal, Amit; Rodríguez-Lorenzo, Laura Langmuir, Vol. 26, Issue 18 https://doi.org/10.1021/la102559e	journal	September 2010
Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics? Xia, Younan; Xiong, Yujie; Lim, Byungkwon Angewandte Chemie International Edition, Vol. 48, Issue 1, p. 60-103 https://doi.org/10.1002/anie.200802248	journal	December 2008
Liquid Cell Transmission Electron Microscopy Study of Platinum Iron Nanocrystal Growth and Shape Evolution Liao, Hong-Gang; Zheng, Haimei Journal of the American Chemical Society, Vol. 135, Issue 13 https://doi.org/10.1021/ja310612p	journal	March 2013
Exploring the Formation of Symmetric Gold Nanostars by Liquid-Cell Transmission Electron Microscopy Ahmad, Nabeel; Wang, Guillaume; Nelayah, Jaysen Nano Letters, Vol. 17, Issue 7 https://doi.org/10.1021/acs.nanolett.7b01013	journal	June 2017
Transmission electron microscopy with a liquid flow cell Klein, K. L.; Anderson, I. M.; De Jonge, N. Journal of Microscopy, Vol. 242, Issue 2, p. 117-123 https://doi.org/10.1111/j.1365-2818.2010.03484.x	journal	January 2011
Liquid-Phase Transmission Electron Microscopy for Studying Colloidal Inorganic Nanoparticles Kim, Byung Hyo; Yang, Jiwoong; Lee, Donghoon Advanced Materials, Vol. 30, Issue 4 https://doi.org/10.1002/adma.201703316	journal	November 2017
Direct Observation of Interactions between Nanoparticles and Nanoparticle Self-Assembly in Solution Tan, Shu Fen; Chee, See Wee; Lin, Guanhua Accounts of Chemical Research, Vol. 50, Issue 6 https://doi.org/10.1021/acs.accounts.7b00063	journal	May 2017
Controlled Growth of Nanoparticles from Solution with In Situ Liquid Transmission Electron Microscopy Evans, James E.; Jungjohann, Katherine L.; Browning, Nigel D. Nano Letters, Vol. 11, Issue 7 https://doi.org/10.1021/nl201166k	journal	July 2011
Formation of Au Nanoparticles in Liquid Cell Transmission Electron Microscopy: From a Systematic Study to Engineered Nanostructures Zhang, Yucheng; Keller, Debora; Rossell, Marta D. Chemistry of Materials, Vol. 29, Issue 24 https://doi.org/10.1021/acs.chemmater.7b04421	journal	November 2017
Liquid Cell Transmission Electron Microscopy Liao, Hong-Gang; Zheng, Haimei Annual Review of Physical Chemistry, Vol. 67, Issue 1 https://doi.org/10.1146/annurev-physchem-040215-112501	journal	May 2016
Dendritic Gold Nanowire Growth Observed in Liquid with Transmission Electron Microscopy Kraus, Tobias; de Jonge, Niels Langmuir, Vol. 29, Issue 26 https://doi.org/10.1021/la401584z	journal	June 2013
Unravelling Kinetic and Thermodynamic Effects on the Growth of Gold Nanoplates by Liquid Transmission Electron Microscopy Alloyeau, Damien; Dachraoui, Walid; Javed, Yasir Nano Letters, Vol. 15, Issue 4 https://doi.org/10.1021/acs.nanolett.5b00140	journal	March 2015
Pushing the Envelope of In Situ Transmission Electron Microscopy Ramachandramoorthy, Rajaprakash; Bernal, Rodrigo; Espinosa, Horacio D. ACS Nano, Vol. 9, Issue 5 https://doi.org/10.1021/acsnano.5b01391	journal	May 2015
Size-Controlled Flow Synthesis of Gold Nanoparticles Using a Segmented Flow Microfluidic Platform Sebastian Cabeza, Victor; Kuhn, Simon; Kulkarni, Amol A. Langmuir, Vol. 28, Issue 17 https://doi.org/10.1021/la205131e	journal	April 2012
Control of Electron Beam-Induced Au Nanocrystal Growth Kinetics through Solution Chemistry Park, Jeung Hun; Schneider, Nicholas M.; Grogan, Joseph M. Nano Letters, Vol. 15, Issue 8 https://doi.org/10.1021/acs.nanolett.5b01677	journal	July 2015
In Situ Electron Energy-Loss Spectroscopy in Liquids Holtz, Megan E.; Yu, Yingchao; Gao, Jie Microscopy and Microanalysis, Vol. 19, Issue 4 https://doi.org/10.1017/S1431927613001505	journal	May 2013
Colloidal nanocrystal synthesis and the organic–inorganic interface Yin, Yadong; Alivisatos, A. Paul Nature, Vol. 437, Issue 7059, p. 664-670 https://doi.org/10.1038/nature04165	journal	September 2005
Electron microscopy of whole cells in liquid with nanometer resolution Jonge, N. d.; Peckys, D. B.; Kremers, G. J. Proceedings of the National Academy of Sciences, Vol. 106, Issue 7 https://doi.org/10.1073/pnas.0809567106	journal	January 2009
The role of electron irradiation history in liquid cell transmission electron microscopy Moser, Trevor H.; Mehta, Hardeep; Park, Chiwoo Science Advances, Vol. 4, Issue 4 https://doi.org/10.1126/sciadv.aaq1202	journal	April 2018
Liquid Cell Transmission Electron Microscopy and the Impact of Confinement on the Precipitation from Supersaturated Solutions Kröger, Roland; Verch, Andreas Minerals, Vol. 8, Issue 1, p. 21 https://doi.org/10.3390/min8010021	journal	January 2018
The Use of Graphene and Its Derivatives for Liquid-Phase Transmission Electron Microscopy of Radiation-Sensitive Specimens Cho, Hoduk; Jones, Matthew R.; Nguyen, Son C. Nano Letters, Vol. 17, Issue 1 https://doi.org/10.1021/acs.nanolett.6b04383	journal	December 2016
Shape-Controlled Synthesis of Gold and Silver Nanoparticles Sun, Yugang; Xia, Younan Science, Vol. 298, Issue 5601, p. 2176-2179 https://doi.org/10.1126/science.1077229	journal	December 2002
Radiation-induced and chemical formation of gold clusters Gachard, Elisabeth; Remita, Hynd; Khatouri, Jamal New Journal of Chemistry, Vol. 22, Issue 11 https://doi.org/10.1039/a804445g	journal	January 1998
Facet development during platinum nanocube growth Liao, H. -G.; Zherebetskyy, D.; Xin, H. Science, Vol. 345, Issue 6199 https://doi.org/10.1126/science.1253149	journal	August 2014
High-Resolution EM of Colloidal Nanocrystal Growth Using Graphene Liquid Cells Yuk, Jong Min; Park, Jungwon; Ercius, Peter Science, Vol. 336, Issue 6077 https://doi.org/10.1126/science.1217654	journal	April 2012
Nanocrystal Diffusion in a Liquid Thin Film Observed by in Situ Transmission Electron Microscopy Zheng, Haimei; Claridge, Shelley A.; Minor, Andrew M. Nano Letters, Vol. 9, Issue 6 https://doi.org/10.1021/nl9012369	journal	June 2009
High-Resolution Imaging and Spectroscopy at High Pressure: A Novel Liquid Cell for the Transmission Electron Microscope Tanase, Mihaela; Winterstein, Jonathan; Sharma, Renu Microscopy and Microanalysis, Vol. 21, Issue 6 https://doi.org/10.1017/S1431927615015482	journal	December 2015
Mechanisms Controlling Crystal Habits of Gold and Silver Colloids Lofton, C.; Sigmund, W. Advanced Functional Materials, Vol. 15, Issue 7 https://doi.org/10.1002/adfm.200400091	journal	July 2005
Electrochemical electron beam lithography: Write, read, and erase metallic nanocrystals on demand Park, Jeung Hun; Steingart, Daniel A.; Kodambaka, Suneel Science Advances, Vol. 3, Issue 7 https://doi.org/10.1126/sciadv.1700234	journal	July 2017
Facet-Dependent Interactions of Islet Amyloid Polypeptide with Gold Nanoparticles: Implications for Fibril Formation and Peptide-Induced Lipid Membrane Disruption Wang, Shih-Ting; Lin, Yiyang; Todorova, Nevena Chemistry of Materials, Vol. 29, Issue 4 https://doi.org/10.1021/acs.chemmater.6b04144	journal	February 2017
Growth and form of gold nanorods prepared by seed-mediated, surfactant-directed synthesis Johnson, Christopher J.; Dujardin, Erik; Davis, Sean A. Journal of Materials Chemistry, Vol. 12, Issue 6 https://doi.org/10.1039/b200953f	journal	April 2002
Metal Nanocrystals with Highly Branched Morphologies Lim, Byungkwon; Xia, Younan Angewandte Chemie International Edition, Vol. 50, Issue 1 https://doi.org/10.1002/anie.201002024	journal	November 2010
Beyond Archimedean solids: Star polyhedral gold nanocrystals Burt, Justin L.; Elechiguerra, Jose L.; Reyes-Gasga, Jose Journal of Crystal Growth, Vol. 285, Issue 4 https://doi.org/10.1016/j.jcrysgro.2005.09.060	journal	December 2005
Investigating Processes of Nanocrystal Formation and Transformation via Liquid Cell TEM Nielsen, Michael H.; Li, Dongsheng; Zhang, Hengzhong Microscopy and Microanalysis, Vol. 20, Issue 2 https://doi.org/10.1017/S1431927614000294	journal	March 2014
Anisotropic Metal Nanoparticles: Synthesis, Assembly, and Optical Applications Murphy, Catherine J.; Sau, Tapan K.; Gole, Anand M. ChemInform, Vol. 36, Issue 41 https://doi.org/10.1002/chin.200541223	journal	October 2005
Seeing crystal formation one particle at a time Han, Yilong Nature Materials, Vol. 19, Issue 4 https://doi.org/10.1038/s41563-020-0649-0	journal	March 2020
Shape Control in Gold Nanoparticle Synthesis* Grzelczak, Marek; Pérez-Juste, Jorge; Mulvaney, Paul Colloidal Synthesis of Plasmonic Nanometals https://doi.org/10.1201/9780429295188-6	book	April 2020
Synthesis of gold structures by gold-binding peptide governed by concentration of gold ion and peptide Kim, Jungok; Kim, Dong-Hun; Lee, Sylvia J. Taylor & Francis https://doi.org/10.6084/m9.figshare.3198721.v1	text	January 2016
Shape-Controlled Synthesis of Gold and Silver Nanoparticles. Sun, Yugang; Xia, Younan ChemInform, Vol. 34, Issue 10 https://doi.org/10.1002/chin.200310226	journal	March 2003
Synthesis of gold structures by gold-binding peptide governed by concentration of gold ion and peptide Kim, Jungok; Kim, Dong-Hun; Lee, Sylvia J. Taylor & Francis https://doi.org/10.6084/m9.figshare.3198721	text	January 2016
Mechanism and kinetics of hydrated electron diffusion Tay, Kafui A.; Coudert, François-Xavier; Boutin, Anne arXiv https://doi.org/10.48550/arxiv.1211.0669	text	January 2012
In Situ Electron Energy-Loss Spectroscopy in Liquids Holtz, Megan E.; Yu, Yingchao; Gao, Jie arXiv https://doi.org/10.48550/arxiv.1212.1501	text	January 2012

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Title: Shape-controlled synthesis and in situ characterisation of anisotropic Au nanomaterials using liquid cell transmission electron microscopy

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