Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Microstructure and surface morphology of InAsSbBi grown by molecular beam epitaxy

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.5096795· OSTI ID:1560706

The physical and chemical properties of 210 nm thick InAsSbBi layers grown by molecular beam epitaxy at temperatures between 400 and 430 °C on (100) GaSb substrates are investigated using Rutherford backscattering, X-ray diffraction, transmission electron microscopy, Nomarski optical microscopy, and atomic force microscopy. The results indicate that the layers are nearly lattice matched, coherently strained, and contain dilute Bi mole fractions. Large surface droplets with diameters on the order of 1 μm and densities on the order of 106 cm−2 are observed when the InAsSbBi growth is performed with lean As overpressures around 1%. Surface droplets are not observed when the As overpressure is increased to 4%. Small crystalline droplets with diameters on the order of 70 nm and densities on the order of 1010 cm−2 are observed between the large droplets for InAsSbBi grown at 430 °C. Analysis of one of the small droplets indicates a misoriented zinc blende crystal structure composed primarily of In, Sb, and Bi, with a lattice constant of 6.543 ± 0.038 Å. Lateral modulation in the Bi mole fraction is observed in InAsSbBi layers grown at 400 °C.

Sponsoring Organization:
USDOE
OSTI ID:
1560706
Journal Information:
Journal of Applied Physics, Journal Name: Journal of Applied Physics Journal Issue: 9 Vol. 126; ISSN 0021-8979
Publisher:
American Institute of PhysicsCopyright Statement
Country of Publication:
United States
Language:
English

References (27)

Die Konstitution der Mischkristalle und die Raumf�llung der Atome journal January 1921
Surface morphology and Bi incorporation in GaSbBi(As)/GaSb films journal March 2014
Investigation of MBE-grown InAs1−Bi alloys and Bi-mediated type-II superlattices by transmission electron microscopy journal September 2015
Examination of the Structural Quality of InAsSbBi Epilayers using Cross Section Transmission Electron Microscopy journal August 2018
Band parameters for III–V compound semiconductors and their alloys journal June 2001
Structural properties of bismuth‐bearing semiconductor alloys journal January 1988
Composition of AlGaAs journal February 1997
Spontaneous formation of nanostructures by surface spinodal decomposition in GaAs 1−x Bi x epilayers journal May 2015
Measurement of InAsSb bandgap energy and InAs/InAsSb band edge positions using spectroscopic ellipsometry and photoluminescence spectroscopy journal December 2015
Optical properties of InAsBi and optimal designs of lattice-matched and strain-balanced III-V semiconductor superlattices journal June 2016
Measurement of InAsBi mole fraction and InBi lattice constant using Rutherford backscattering spectrometry and X-ray diffraction journal October 2016
Bandgap and composition of bulk InAsSbBi grown by molecular beam epitaxy journal August 2017
Microstructure and interface analysis of emerging Ga(Sb,Bi) epilayers and Ga(Sb,Bi)/GaSb quantum wells for optoelectronic applications journal April 2018
Molecular beam epitaxy growth and optical properties of InAsSbBi journal August 2019
Composition determination in the GaAs/(Al, Ga)As system using contrast in dark-field transmission electron microscope images journal July 1989
Formation and phase transformation of Bi-containing QD-like clusters in annealed GaAsBi journal April 2014
Detecting lateral composition modulation in dilute Ga(As,Bi) epilayers journal September 2015
Spontaneous formation of three-dimensionally ordered Bi-rich nanostructures within GaAs 1− x Bi x /GaAs quantum wells journal July 2016
Aberration-corrected scanning transmission electron microscopy: from atomic imaging and analysis to solving energy problems
  • Pennycook, S. J.; Chisholm, M. F.; Lupini, A. R.
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 367, Issue 1903 https://doi.org/10.1098/rsta.2009.0112
journal September 2009
Characterizing composition modulations in InAs/AlAs short-period superlattices journal November 1999
Relativistic Hartree–Fock X-ray and electron scattering factors journal May 1968
Correlation between interface structure and light emission at 1.3–1.55 μm of (Ga,In)(N,As) diluted nitride heterostructures on GaAs substrates
  • Trampert, Achim; Chauveau, Jean-Michel; Ploog, Klaus H.
  • Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 22, Issue 4 https://doi.org/10.1116/1.1775197
journal January 2004
The Role of Epitaxial Strain on the Spontaneous Formation of Bi-Rich Nanostructures in Ga(As,Bi) Epilayers and Quantum Wells journal July 2017
Novel Dilute Bismide, Epitaxy, Physical Properties and Device Application journal February 2017
Progress in Infrared Photodetectors Since 2000 journal April 2013
What to use to express the variability of data: Standard deviation or standard error of mean? journal January 2012
Formation of Tetragonal InBi Clusters in InAsBi/InAs(100) Heterostructures Grown by Molecular Beam Epitaxy journal November 2013

Similar Records

Minority carrier lifetime and photoluminescence of mid-wave infrared InAsSbBi
Journal Article · Mon Aug 10 20:00:00 EDT 2020 · Applied Physics Letters · OSTI ID:1647118

Molecular beam epitaxy growth and optical properties of InAsSbBi
Journal Article · Wed Aug 21 20:00:00 EDT 2019 · Journal of Applied Physics · OSTI ID:1560702

Molecular beam epitaxy growth and optoelectronic properties of droplet-free lattice-matched GaInAsSbBi on GaSb with wavelength extension exceeding 5 μm
Journal Article · Mon Feb 10 19:00:00 EST 2025 · Journal of Applied Physics · OSTI ID:2584384

Related Subjects