Searching for promising new perovskite-based photovoltaic absorbers: the importance of electronic dimensionality

Xiao, Zewen; Meng, Weiwei; Wang, Jianbo; Mitzi, David B.; Yan, Yanfa

doi:10.1039/c6mh00519e

Searching for promising new perovskite-based photovoltaic absorbers: the importance of electronic dimensionality

Journal Article · Fri Dec 23 23:00:00 EST 2016 · Materials Horizons

DOI:https://doi.org/10.1039/c6mh00519e· OSTI ID:1559762

^[1]; Meng, Weiwei ^[2]; Wang, Jianbo ^[3]; Mitzi, David B. ^[4]; ^[2]

Univ. of Toledo, OH (United States). Wright Center for Photovoltaics Innovation and Commercialization (PVIC); Duke University
Univ. of Toledo, OH (United States). Wright Center for Photovoltaics Innovation and Commercialization (PVIC)
Wuhan Univ. (China). Center for Electron Microscopy
Duke Univ., Durham, NC (United States). Dept. of Mechanical Engineering and Materials Science, and Dept. of Chemistry

Searching for promising nontoxic and air-stable perovskite absorbers for solar cell applications has drawn extensive attention. Here, we show that a promising perovskite absorber should exhibit a high electronic dimensionality. Semiconductors that exhibit a high structural dimensionality, but a low electronic dimensionality have less promise as an absorber, because of barriers to isotropic current flow, enhanced electron/hole effective masses and fundamentally deeper defect states (more effective at causing recombination). Our concept accounts for the device performance of the perovskite-based solar cells reported in literature so far.

View Accepted Manuscript (DOE)

Research Organization:: Duke Univ., Durham, NC (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0006712

OSTI ID:: 1559762

Journal Information:: Materials Horizons, Journal Name: Materials Horizons Journal Issue: 2 Vol. 4; ISSN 2051-6347; ISSN MHAOAL

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (111)

Unique Properties of Halide Perovskites as Possible Origins of the Superior Solar Cell Performance Yin, Wan-Jian; Shi, Tingting; Yan, Yanfa Advanced Materials, Vol. 26, Issue 27 https://doi.org/10.1002/adma.201306281	journal	May 2014
Lead-Free Halide Perovskite Solar Cells with High Photocurrents Realized Through Vacancy Modulation Kumar, Mulmudi Hemant; Dharani, Sabba; Leong, Wei Lin Advanced Materials, Vol. 26, Issue 41 https://doi.org/10.1002/adma.201401991	journal	September 2014
Bismuth Based Hybrid Perovskites A ₃ Bi ₂ I ₉ (A: Methylammonium or Cesium) for Solar Cell Application Park, Byung-Wook; Philippe, Bertrand; Zhang, Xiaoliang Advanced Materials, Vol. 27, Issue 43 https://doi.org/10.1002/adma.201501978	journal	September 2015
Lead-Free Inverted Planar Formamidinium Tin Triiodide Perovskite Solar Cells Achieving Power Conversion Efficiencies up to 6.22% Liao, Weiqiang; Zhao, Dewei; Yu, Yue Advanced Materials, Vol. 28, Issue 42 https://doi.org/10.1002/adma.201602992	journal	August 2016
A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability Smith, Ian C.; Hoke, Eric T.; Solis-Ibarra, Diego Angewandte Chemie, Vol. 126, Issue 42 https://doi.org/10.1002/ange.201406466	journal	September 2014
Pure Cubic-Phase Hybrid Iodobismuthates AgBi ₂ I ₇ for Thin-Film Photovoltaics Kim, Younghoon; Yang, Zhenyu; Jain, Ankit Angewandte Chemie, Vol. 128, Issue 33 https://doi.org/10.1002/ange.201603608	journal	June 2016
A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability Smith, Ian C.; Hoke, Eric T.; Solis-Ibarra, Diego Angewandte Chemie International Edition, Vol. 53, Issue 42 https://doi.org/10.1002/anie.201406466	journal	September 2014
Pure Cubic-Phase Hybrid Iodobismuthates AgBi ₂ I ₇ for Thin-Film Photovoltaics Kim, Younghoon; Yang, Zhenyu; Jain, Ankit Angewandte Chemie International Edition, Vol. 55, Issue 33 https://doi.org/10.1002/anie.201603608	journal	June 2016
Exploring a Lead-free Semiconducting Hybrid Ferroelectric with a Zero-Dimensional Perovskite-like Structure Sun, Zhihua; Zeb, Aurang; Liu, Sijie Angewandte Chemie International Edition, Vol. 55, Issue 39 https://doi.org/10.1002/anie.201606079	journal	August 2016
Methylammonium Bismuth Iodide as a Lead-Free, Stable Hybrid Organic-Inorganic Solar Absorber Hoye, Robert L. Z.; Brandt, Riley E.; Osherov, Anna Chemistry - A European Journal, Vol. 22, Issue 8 https://doi.org/10.1002/chem.201505055	journal	January 2016
Thermodynamic Stability and Defect Chemistry of Bismuth-Based Lead-Free Double Perovskites Xiao, Zewen; Meng, Weiwei; Wang, Jianbo ChemSusChem, Vol. 9, Issue 18 https://doi.org/10.1002/cssc.201600771	journal	August 2016
Lead-free mesoscopic Cs ₂ SnI ₆ perovskite solar cells using different nanostructured ZnO nanorods as electron transport layers Qiu, Xiaofeng; Jiang, Yanan; Zhang, Hailiang physica status solidi (RRL) - Rapid Research Letters, Vol. 10, Issue 8 https://doi.org/10.1002/pssr.201600166	journal	June 2016
Organic–inorganic bismuth (III)-based material: A lead-free, air-stable and solution-processable light-absorber beyond organolead perovskites Lyu, Miaoqiang; Yun, Jung-Ho; Cai, Molang Nano Research, Vol. 9, Issue 3 https://doi.org/10.1007/s12274-015-0948-y	journal	January 2016
Active-layer evolution and efficiency improvement of (CH3NH3 3Bi2I9-based solar cell on TiO2-deposited ITO substrate Zhang, Xinqian; Wu, Gang; Gu, Zhuowei Nano Research, Vol. 9, Issue 10 https://doi.org/10.1007/s12274-016-1177-8	journal	July 2016
Optical properties of PbI-based perovskite structures Ishihara, Teruya Journal of Luminescence, Vol. 60-61 https://doi.org/10.1016/0022-2313(94)90145-7	journal	April 1994
Structural and electronic properties of the natural quantum-well system (C6H5CH2CH2NH3)2SnI4 Papavassiliou, G. C.; Koutselas, I. B.; Terzis, A. Solid State Communications, Vol. 91, Issue 9 https://doi.org/10.1016/0038-1098(94)00435-8	journal	September 1994
Optical and related properties of natural one-dimensional semiconductors based on PbI and SnI units Koutselas, I. B.; Mitzi, D. B.; Papavassiliou, G. C. Synthetic Metals, Vol. 86, Issue 1-3 https://doi.org/10.1016/S0379-6779(97)81081-8	journal	February 1997
High-temperature structural evolution of caesium and rubidium triiodoplumbates Trots, D. M.; Myagkota, S. V. Journal of Physics and Chemistry of Solids, Vol. 69, Issue 10, p. 2520-2526 https://doi.org/10.1016/j.jpcs.2008.05.007	journal	October 2008
Zero-dimensional (CH3NH3)3Bi2I9 perovskite for optoelectronic applications Öz, Senol; Hebig, Jan-Christoph; Jung, Eunhwan Solar Energy Materials and Solar Cells, Vol. 158 https://doi.org/10.1016/j.solmat.2016.01.035	journal	December 2016
From unstable CsSnI3 to air-stable Cs2SnI6: A lead-free perovskite solar cell light absorber with bandgap of 1.48 eV and high absorption coefficient Qiu, Xiaofeng; Cao, Bingqiang; Yuan, Shuai Solar Energy Materials and Solar Cells, Vol. 159 https://doi.org/10.1016/j.solmat.2016.09.022	journal	January 2017
Bandgap and exciton binding energies in lead-iodide-based natural quantum-well crystals Tanaka, Kenichiro; Kondo, Takashi Science and Technology of Advanced Materials, Vol. 4, Issue 6, p. 599-604 https://doi.org/10.1016/j.stam.2003.09.019	journal	March 2004
Molecular design and photovoltaic performance of a novel thiocyanate-based layered organometal perovskite material Liu, Jiaying; Shi, Jiangjian; Li, Dongmei Synthetic Metals, Vol. 215 https://doi.org/10.1016/j.synthmet.2015.11.028	journal	May 2016
Thin-Film Preparation and Characterization of Cs ₃ Sb ₂ I ₉ : A Lead-Free Layered Perovskite Semiconductor Saparov, Bayrammurad; Hong, Feng; Sun, Jon-Paul Chemistry of Materials, Vol. 27, Issue 16 https://doi.org/10.1021/acs.chemmater.5b01989	journal	August 2015
Crystal and Electronic Structures of Complex Bismuth Iodides A ₃ Bi ₂ I ₉ ( A = K, Rb, Cs) Related to Perovskite: Aiding the Rational Design of Photovoltaics Lehner, Anna J.; Fabini, Douglas H.; Evans, Hayden A. Chemistry of Materials, Vol. 27, Issue 20 https://doi.org/10.1021/acs.chemmater.5b03147	journal	October 2015
Stabilizing Perovskite Structures by Tuning Tolerance Factor: Formation of Formamidinium and Cesium Lead Iodide Solid-State Alloys Li, Zhen; Yang, Mengjin; Park, Ji-Sang Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b04107	journal	December 2015
Alloying and Defect Control within Chalcogenide Perovskites for Optimized Photovoltaic Application Meng, Weiwei; Saparov, Bayrammurad; Hong, Feng Chemistry of Materials, Vol. 28, Issue 3 https://doi.org/10.1021/acs.chemmater.5b04213	journal	January 2016
Cs ₂ AgBiX ₆ (X = Br, Cl): New Visible Light Absorbing, Lead-Free Halide Perovskite Semiconductors McClure, Eric T.; Ball, Molly R.; Windl, Wolfgang Chemistry of Materials, Vol. 28, Issue 5 https://doi.org/10.1021/acs.chemmater.5b04231	journal	February 2016
Thin-Film Deposition and Characterization of a Sn-Deficient Perovskite Derivative Cs ₂ SnI ₆ Saparov, Bayrammurad; Sun, Jon-Paul; Meng, Weiwei Chemistry of Materials, Vol. 28, Issue 7 https://doi.org/10.1021/acs.chemmater.6b00433	journal	March 2016
Confinement Effects in Low-Dimensional Lead Iodide Perovskite Hybrids Kamminga, Machteld E.; Fang, Hong-Hua; Filip, Marina R. Chemistry of Materials, Vol. 28, Issue 13 https://doi.org/10.1021/acs.chemmater.6b00809	journal	June 2016
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J. Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867 https://doi.org/10.1021/acs.chemmater.6b00847	journal	April 2016
Red-to-Black Piezochromism in a Compressible Pb–I–SCN Layered Perovskite Umeyama, Daiki; Lin, Yu; Karunadasa, Hemamala I. Chemistry of Materials, Vol. 28, Issue 10 https://doi.org/10.1021/acs.chemmater.6b01147	journal	May 2016
Facile Synthesis and Characterization of Sulfur Doped Low Bandgap Bismuth Based Perovskites by Soluble Precursor Route Vigneshwaran, Murugan; Ohta, Takeshi; Iikubo, Satoshi Chemistry of Materials, Vol. 28, Issue 18 https://doi.org/10.1021/acs.chemmater.6b02315	journal	September 2016
Role of Organic Counterion in Lead- and Tin-Based Two-Dimensional Semiconducting Iodide Perovskites and Application in Planar Solar Cells Mao, Lingling; Tsai, Hsinhan; Nie, Wanyi Chemistry of Materials, Vol. 28, Issue 21 https://doi.org/10.1021/acs.chemmater.6b03054	journal	October 2016
Rb as an Alternative Cation for Templating Inorganic Lead-Free Perovskites for Solution Processed Photovoltaics Harikesh, P. C.; Mulmudi, Hemant Kumar; Ghosh, Biplab Chemistry of Materials, Vol. 28, Issue 20 https://doi.org/10.1021/acs.chemmater.6b03310	journal	October 2016
Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design Saparov, Bayrammurad; Mitzi, David B. Chemical Reviews, Vol. 116, Issue 7 https://doi.org/10.1021/acs.chemrev.5b00715	journal	March 2016
Computational Screening of Homovalent Lead Substitution in Organic–Inorganic Halide Perovskites Filip, Marina R.; Giustino, Feliciano The Journal of Physical Chemistry C, Vol. 120, Issue 1 https://doi.org/10.1021/acs.jpcc.5b11845	journal	December 2015
Viability of Lead-Free Perovskites with Mixed Chalcogen and Halogen Anions for Photovoltaic Applications Hong, Feng; Saparov, Bayrammurad; Meng, Weiwei The Journal of Physical Chemistry C, Vol. 120, Issue 12 https://doi.org/10.1021/acs.jpcc.6b00920	journal	March 2016
Optical-Vibrational Properties of the Cs ₂ SnX ₆ (X = Cl, Br, I) Defect Perovskites and Hole-Transport Efficiency in Dye-Sensitized Solar Cells Kaltzoglou, Andreas; Antoniadou, Maria; Kontos, Athanassios G. The Journal of Physical Chemistry C, Vol. 120, Issue 22 https://doi.org/10.1021/acs.jpcc.6b02175	journal	May 2016
Density Functional Calculations of Native Defects in CH ₃ NH ₃ PbI ₃ : Effects of Spin–Orbit Coupling and Self-Interaction Error Du, Mao-Hua The Journal of Physical Chemistry Letters, Vol. 6, Issue 8 https://doi.org/10.1021/acs.jpclett.5b00199	journal	April 2015
Cesium Lead Halide Perovskites with Improved Stability for Tandem Solar Cells Beal, Rachel E.; Slotcavage, Daniel J.; Leijtens, Tomas The Journal of Physical Chemistry Letters, Vol. 7, Issue 5 https://doi.org/10.1021/acs.jpclett.6b00002	journal	February 2016
Photovoltaic Properties of Two-Dimensional (CH ₃ NH ₃ ) ₂ Pb(SCN) ₂ I ₂ Perovskite: A Combined Experimental and Density Functional Theory Study Xiao, Zewen; Meng, Weiwei; Saparov, Bayrammurad The Journal of Physical Chemistry Letters, Vol. 7, Issue 7 https://doi.org/10.1021/acs.jpclett.6b00248	journal	March 2016
Lead-Free Halide Double Perovskites via Heterovalent Substitution of Noble Metals Volonakis, George; Filip, Marina R.; Haghighirad, Amir Abbas The Journal of Physical Chemistry Letters, Vol. 7, Issue 7 https://doi.org/10.1021/acs.jpclett.6b00376	journal	March 2016
Band Gaps of the Lead-Free Halide Double Perovskites Cs ₂ BiAgCl ₆ and Cs ₂ BiAgBr ₆ from Theory and Experiment Filip, Marina R.; Hillman, Samuel; Haghighirad, Amir Abbas The Journal of Physical Chemistry Letters, Vol. 7, Issue 13 https://doi.org/10.1021/acs.jpclett.6b01041	journal	June 2016
Crystal Structure of AgBi ₂ I ₇ Thin Films Xiao, Zewen; Meng, Weiwei; Mitzi, David B. The Journal of Physical Chemistry Letters, Vol. 7, Issue 19 https://doi.org/10.1021/acs.jpclett.6b01834	journal	September 2016
Effect of Electron Transporting Layer on Bismuth-Based Lead-Free Perovskite (CH ₃ NH ₃ ) ₃ Bi ₂ I ₉ for Photovoltaic Applications Singh, Trilok; Kulkarni, Ashish; Ikegami, Masashi ACS Applied Materials & Interfaces, Vol. 8, Issue 23 https://doi.org/10.1021/acsami.6b02843	journal	June 2016
Optoelectronic Properties of (CH ₃ NH ₃ ) ₃ Sb ₂ I ₉ Thin Films for Photovoltaic Applications Hebig, Jan-Christoph; Kühn, Irina; Flohre, Jan ACS Energy Letters, Vol. 1, Issue 1 https://doi.org/10.1021/acsenergylett.6b00170	journal	June 2016
Pure Cs ₄ PbBr ₆ : Highly Luminescent Zero-Dimensional Perovskite Solids Saidaminov, Makhsud I.; Almutlaq, Jawaher; Sarmah, Smritakshi ACS Energy Letters, Vol. 1, Issue 4 https://doi.org/10.1021/acsenergylett.6b00396	journal	September 2016
Can Pb-Free Halide Double Perovskites Support High-Efficiency Solar Cells? Savory, Christopher N.; Walsh, Aron; Scanlon, David O. ACS Energy Letters, Vol. 1, Issue 5 https://doi.org/10.1021/acsenergylett.6b00471	journal	October 2016
Toward Lead-Free Perovskite Solar Cells Giustino, Feliciano; Snaith, Henry J. ACS Energy Letters, Vol. 1, Issue 6 https://doi.org/10.1021/acsenergylett.6b00499	journal	November 2016
Structurally Tailored Organic−Inorganic Perovskites: Optical Properties and Solution-Processed Channel Materials for Thin-Film Transistors Mitzi, David B.; Dimitrakopoulos, Christos D.; Kosbar, Laura L. Chemistry of Materials, Vol. 13, Issue 10 https://doi.org/10.1021/cm010105g	journal	October 2001
Semiconducting Perovskites (2-XC ₆ H ₄ C ₂ H ₄ NH ₃ ) ₂ SnI ₄ (X = F, Cl, Br): Steric Interaction between the Organic and Inorganic Layers Xu, Zhengtao; Mitzi, David B.; Dimitrakopoulos, Christos D. Inorganic Chemistry, Vol. 42, Issue 6 https://doi.org/10.1021/ic0261474	journal	March 2003
Tuning the Band Gap in Hybrid Tin Iodide Perovskite Semiconductors Using Structural Templating Knutson, Jeremy L.; Martin, James D.; Mitzi, David B. Inorganic Chemistry, Vol. 44, Issue 13 https://doi.org/10.1021/ic050244q	journal	June 2005
Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties Stoumpos, Constantinos C.; Malliakas, Christos D.; Kanatzidis, Mercouri G. Inorganic Chemistry, Vol. 52, Issue 15, p. 9019-9038 https://doi.org/10.1021/ic401215x	journal	July 2013
Strong Covalency-Induced Recombination Centers in Perovskite Solar Cell Material CH ₃ NH ₃ PbI ₃ Agiorgousis, Michael L.; Sun, Yi-Yang; Zeng, Hao Journal of the American Chemical Society, Vol. 136, Issue 41 https://doi.org/10.1021/ja5079305	journal	October 2014
Air-Stable Molecular Semiconducting Iodosalts for Solar Cell Applications: Cs₂SnI₆ as a Hole Conductor Lee, Byunghong; Stoumpos, Constantinos C.; Zhou, Nanjia Journal of the American Chemical Society, Vol. 136, Issue 43, p. 15379-15385 https://doi.org/10.1021/ja508464w	journal	October 2014
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051 https://doi.org/10.1021/ja809598r	journal	May 2009
Hybrid Germanium Iodide Perovskite Semiconductors: Active Lone Pairs, Structural Distortions, Direct and Indirect Energy Gaps, and Strong Nonlinear Optical Properties Stoumpos, Constantinos C.; Frazer, Laszlo; Clark, Daniel J. Journal of the American Chemical Society, Vol. 137, Issue 21 https://doi.org/10.1021/jacs.5b01025	journal	May 2015
2D Homologous Perovskites as Light-Absorbing Materials for Solar Cell Applications Cao, Duyen H.; Stoumpos, Constantinos C.; Farha, Omar K. Journal of the American Chemical Society, Vol. 137, Issue 24 https://doi.org/10.1021/jacs.5b03796	journal	June 2015
Ligand-Stabilized Reduced-Dimensionality Perovskites Quan, Li Na; Yuan, Mingjian; Comin, Riccardo Journal of the American Chemical Society, Vol. 138, Issue 8 https://doi.org/10.1021/jacs.5b11740	journal	February 2016
A Bismuth-Halide Double Perovskite with Long Carrier Recombination Lifetime for Photovoltaic Applications Slavney, Adam H.; Hu, Te; Lindenberg, Aaron M. Journal of the American Chemical Society, Vol. 138, Issue 7 https://doi.org/10.1021/jacs.5b13294	journal	February 2016
Fabrication of Efficient Formamidinium Tin Iodide Perovskite Solar Cells through SnF ₂ –Pyrazine Complex Lee, Seon Joo; Shin, Seong Sik; Kim, Young Chan Journal of the American Chemical Society, Vol. 138, Issue 12 https://doi.org/10.1021/jacs.6b00142	journal	March 2016
Defect Tolerance to Intolerance in the Vacancy-Ordered Double Perovskite Semiconductors Cs ₂ SnI ₆ and Cs ₂ TeI ₆ Maughan, Annalise E.; Ganose, Alex M.; Bordelon, Mitchell M. Journal of the American Chemical Society, Vol. 138, Issue 27 https://doi.org/10.1021/jacs.6b03207	journal	June 2016
First-Principles Study of Lead Iodide Perovskite Tetragonal and Orthorhombic Phases for Photovoltaics Geng, Wei; Zhang, Le; Zhang, Yan-Ning The Journal of Physical Chemistry C, Vol. 118, Issue 34 https://doi.org/10.1021/jp504951h	journal	August 2014
Superior Photovoltaic Properties of Lead Halide Perovskites: Insights from First-Principles Theory Yin, Wan-Jian; Shi, Tingting; Yan, Yanfa The Journal of Physical Chemistry C, Vol. 119, Issue 10 https://doi.org/10.1021/jp512077m	journal	February 2015
Conducting tin halides with a layered organic-based perovskite structure Mitzi, D. B.; Feild, C. A.; Harrison, W. T. A. Nature, Vol. 369, Issue 6480, p. 467-469 https://doi.org/10.1038/369467a0	journal	June 1994
Compositional engineering of perovskite materials for high-performance solar cells Jeon, Nam Joong; Noh, Jun Hong; Yang, Woon Seok Nature, Vol. 517, Issue 7535 https://doi.org/10.1038/nature14133	journal	January 2015
High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells Tsai, Hsinhan; Nie, Wanyi; Blancon, Jean-Christophe Nature, Vol. 536, Issue 7616 https://doi.org/10.1038/nature18306	journal	July 2016
Lead-free solid-state organic–inorganic halide perovskite solar cells Hao, Feng; Stoumpos, Constantinos C.; Cao, Duyen Hanh Nature Photonics, Vol. 8, Issue 6 https://doi.org/10.1038/nphoton.2014.82	journal	May 2014
Relativistic GW calculations on CH3NH3PbI3 and CH3NH3SnI3 Perovskites for Solar Cell Applications Umari, Paolo; Mosconi, Edoardo; De Angelis, Filippo Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep04467	journal	March 2014
Energy barrier at the N719-dye/CsSnI3 interface for photogenerated holes in dye-sensitized solar cells Zhang, Jin; Yu, Chunhui; Wang, Lili Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep06954	journal	November 2014
Solution phase n-doping of C ₆₀ and PCBM using tetrabutylammonium fluoride Weber, C. D.; Bradley, C.; Lonergan, M. C. J. Mater. Chem. A, Vol. 2, Issue 2 https://doi.org/10.1039/C3TA14132B	journal	January 2014
Lead-free organic–inorganic tin halide perovskites for photovoltaic applications Noel, Nakita K.; Stranks, Samuel D.; Abate, Antonio Energy Environ. Sci., Vol. 7, Issue 9 https://doi.org/10.1039/C4EE01076K	journal	January 2014
Halide perovskite materials for solar cells: a theoretical review Yin, Wan-Jian; Yang, Ji-Hui; Kang, Joongoo Journal of Materials Chemistry A, Vol. 3, Issue 17 https://doi.org/10.1039/C4TA05033A	journal	January 2015
Crystallographic insights into (CH ₃ NH ₃ ) ₃ (Bi ₂ I ₉ ): a new lead-free hybrid organic–inorganic material as a potential absorber for photovoltaics Eckhardt, Kai; Bon, Volodymyr; Getzschmann, Jürgen Chemical Communications, Vol. 52, Issue 14 https://doi.org/10.1039/C5CC10455F	journal	January 2016
Intrinsic defects in a photovoltaic perovskite variant Cs ₂ SnI ₆ Xiao, Zewen; Zhou, Yuanyuan; Hosono, Hideo Physical Chemistry Chemical Physics, Vol. 17, Issue 29 https://doi.org/10.1039/C5CP03102H	journal	January 2015
Structural and optical properties of methylammonium lead iodide across the tetragonal to cubic phase transition: implications for perovskite solar cells Quarti, Claudio; Mosconi, Edoardo; Ball, James M. Energy & Environmental Science, Vol. 9, Issue 1 https://doi.org/10.1039/C5EE02925B	journal	January 2016
On the application of the tolerance factor to inorganic and hybrid halide perovskites: a revised system Travis, W.; Glover, E. N. K.; Bronstein, H. Chemical Science, Vol. 7, Issue 7 https://doi.org/10.1039/C5SC04845A	journal	January 2016
Lead-free germanium iodide perovskite materials for photovoltaic applications Krishnamoorthy, Thirumal; Ding, Hong; Yan, Chen Journal of Materials Chemistry A, Vol. 3, Issue 47 https://doi.org/10.1039/C5TA05741H	journal	January 2015
Inorganic caesium lead iodide perovskite solar cells Eperon, Giles E.; Paternò, Giuseppe M.; Sutton, Rebecca J. Journal of Materials Chemistry A, Vol. 3, Issue 39 https://doi.org/10.1039/C5TA06398A	journal	January 2015
Beyond methylammonium lead iodide: prospects for the emergent field of ns ² containing solar absorbers Ganose, Alex M.; Savory, Christopher N.; Scanlon, David O. Chemical Communications, Vol. 53, Issue 1 https://doi.org/10.1039/C6CC06475B	journal	January 2017
Defect properties of the two-dimensional (CH ₃ NH ₃ ) ₂ Pb(SCN) ₂ I ₂ perovskite: a density-functional theory study Xiao, Zewen; Meng, Weiwei; Wang, Jianbo Physical Chemistry Chemical Physics, Vol. 18, Issue 37 https://doi.org/10.1039/C6CP05302E	journal	January 2016
The synthesis, structure and electronic properties of a lead-free hybrid inorganic–organic double perovskite (MA) ₂ KBiCl ₆ (MA = methylammonium) Wei, Fengxia; Deng, Zeyu; Sun, Shijing Materials Horizons, Vol. 3, Issue 4 https://doi.org/10.1039/C6MH00053C	journal	January 2016
First-principles insight into the photoelectronic properties of Ge-based perovskites Lu, Xiaoqing; Zhao, Zigang; Li, Ke RSC Advances, Vol. 6, Issue 90 https://doi.org/10.1039/C6RA18534G	journal	January 2016
Optoelectronic and photovoltaic properties of the air-stable organohalide semiconductor (CH ₃ NH ₃ ) ₃ Bi ₂ I ₉ Abulikemu, Mutalifu; Ould-Chikh, Samy; Miao, Xiaohe Journal of Materials Chemistry A, Vol. 4, Issue 32 https://doi.org/10.1039/C6TA04657F	journal	January 2016
Layered 2D alkyldiammonium lead iodide perovskites: synthesis, characterization, and use in solar cells Safdari, Majid; Svensson, Per H.; Hoang, Minh Tam Journal of Materials Chemistry A, Vol. 4, Issue 40 https://doi.org/10.1039/C6TA05055G	journal	January 2016
Exploring the properties of lead-free hybrid double perovskites using a combined computational-experimental approach Deng, Zeyu; Wei, Fengxia; Sun, Shijing Journal of Materials Chemistry A, Vol. 4, Issue 31 https://doi.org/10.1039/C6TA05817E	journal	January 2016
Preparation, structure and optical properties of [CH3SC(NH2)NH2]3PbI5, [CH3SC(NH2)NH2]4Pb2Br8and [CH3SC(NH2)NH2]3PbCl5·CH3SC(NH2)NH2Cl Mousdis, G. A.; Gionis, V.; Papavassiliou, G. C. Journal of Materials Chemistry, Vol. 8, Issue 10 https://doi.org/10.1039/a802926a	journal	January 1998
Templating and structural engineering in organic–inorganic perovskites Mitzi, David B. Journal of the Chemical Society, Dalton Transactions, Issue 1 https://doi.org/10.1039/b007070j	journal	January 2001
Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3)PbI3 for solid-state sensitised solar cell applications Baikie, Tom; Fang, Yanan; Kadro, Jeannette M. Journal of Materials Chemistry A, Vol. 1, Issue 18 https://doi.org/10.1039/c3ta10518k	journal	January 2013
Effect of temperature variation on shift and broadening of the exciton band in Cs3Bi2I9 layered crystals Machulin, V. F.; Motsnyi, F. V.; Smolanka, O. M. Low Temperature Physics, Vol. 30, Issue 12 https://doi.org/10.1063/1.1820036	journal	December 2004
Unusual defect physics in CH ₃ NH ₃ PbI ₃ perovskite solar cell absorber Yin, Wan-Jian; Shi, Tingting; Yan, Yanfa Applied Physics Letters, Vol. 104, Issue 6 https://doi.org/10.1063/1.4864778	journal	February 2014
Route to n -type doping in SnS Xiao, Zewen; Ran, Fan-Yong; Hosono, Hideo Applied Physics Letters, Vol. 106, Issue 15 https://doi.org/10.1063/1.4918294	journal	April 2015
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Synthetic Three-and Lower-Dimensional Semiconductors Based on Inorganic Units Papavassiliou, G. C. Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol. 286, Issue 1 https://doi.org/10.1080/10587259608042291	journal	July 1996
Optical properties due to electronic transitions in two-dimensional semiconductors ( C n H 2 n + 1 NH 3 ) 2 PbI 4 Ishihara, Teruya; Takahashi, Jun; Goto, Takenari Physical Review B, Vol. 42, Issue 17 https://doi.org/10.1103/PhysRevB.42.11099	journal	December 1990
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Electronic structures of lead iodide based low-dimensional crystals Umebayashi, T.; Asai, K.; Kondo, T. Physical Review B, Vol. 67, Issue 15 https://doi.org/10.1103/PhysRevB.67.155405	journal	April 2003
Assessment of correction methods for the band-gap problem and for finite-size effects in supercell defect calculations: Case studies for ZnO and GaAs Lany, Stephan; Zunger, Alex Physical Review B, Vol. 78, Issue 23, Article No. 235104 https://doi.org/10.1103/PhysRevB.78.235104	journal	December 2008
Effect of metal cation replacement on the electronic structure of metalorganic halide perovskites: Replacement of lead with alkaline-earth metals Pazoki, Meysam; Jacobsson, T. Jesper; Hagfeldt, Anders Physical Review B, Vol. 93, Issue 14 https://doi.org/10.1103/PhysRevB.93.144105	journal	April 2016
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Electron-density distribution in a crystal of potassium tetrafluoronickelate, K ₂ NiF ₄ Yeh, S. K.; Wu, S. Y.; Lee, C. S. Acta Crystallographica Section B Structural Science, Vol. 49, Issue 5 https://doi.org/10.1107/S0108768193003246	journal	October 1993
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Interface engineering of highly efficient perovskite solar cells Zhou, H.; Chen, Q.; Li, G. Science, Vol. 345, Issue 6196 https://doi.org/10.1126/science.1254050	journal	July 2014
Conducting Layered Organic-inorganic Halides Containing <110>-Oriented Perovskite Sheets Mitzi, D. B.; Wang, S.; Feild, C. A. Science, Vol. 267, Issue 5203, p. 1473-1476 https://doi.org/10.1126/science.267.5203.1473	journal	March 1995
High-performance photovoltaic perovskite layers fabricated through intramolecular exchange Yang, W. S.; Noh, J. H.; Jeon, N. J. Science, Vol. 348, Issue 6240 https://doi.org/10.1126/science.aaa9272	journal	May 2015
Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance Saliba, M.; Matsui, T.; Domanski, K. Science, Vol. 354, Issue 6309 https://doi.org/10.1126/science.aah5557	journal	September 2016
Exciton absorption spectrum of thin CsPbI3 and Cs4PbI6 films Yunakova, O. N.; Miloslavskii, V. K.; Kovalenko, E. N. Optics and Spectroscopy, Vol. 112, Issue 1 https://doi.org/10.1134/S0030400X12010249	journal	January 2012
Ligand-Hole in [SnI ₆ ] Unit and Origin of Band Gap in Photovoltaic Perovskite Variant Cs ₂ SnI ₆ Xiao, Zewen; Lei, Hechang; Zhang, Xiao Bulletin of the Chemical Society of Japan, Vol. 88, Issue 9 https://doi.org/10.1246/bcsj.20150110	journal	September 2015
Preparation, Structure and Optical Properties of [CH3SC(NH2)2]3SnI5, [CH3SC(NH2)2][HSC(NH2)2]SnBr4, (CH3C5H4NCH3)PbBr3, and [C6H5CH2SC(NH2)2]4Pb3I10 Raptopoulou, C. P.; Terzis, A.; Mousdis, G. A. Zeitschrift für Naturforschung B, Vol. 57, Issue 6 https://doi.org/10.1515/znb-2002-0609	journal	June 2002
Rb as an Alternative Cation for Templating Inorganic Lead-Free Perovskites for Solution Processed Photovoltaics Harikesh, P. C.; Mulmudi, Hemant; Ghosh, Biplab Open Science Framework https://doi.org/10.17605/osf.io/894g2	text	January 2019
On the application of the tolerance factor to inorganic and hybrid halide perovskites: a revised system. Travis, W.; Glover, Enk; Bronstein, H. Royal Society of Chemistry (RSC) https://doi.org/10.17863/cam.43716	journalarticle	January 2016

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Lead-Free Halide Double Perovskites: A Review of the Structural, Optical, and Stability Properties as Well as Their Viability to Replace Lead Halide Perovskites Meyer, Edson; Mutukwa, Dorcas; Zingwe, Nyengerai Metals, Vol. 8, Issue 9 https://doi.org/10.3390/met8090667	journal	August 2018

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