Coherent single-photon emission from colloidal lead halide perovskite quantum dots

Utzat, Hendrik; Sun, Weiwei; Kaplan, Alexander E. K.; Krieg, Franziska; Ginterseder, Matthias; Spokoyny, Boris; Klein, Nathan D.; Shulenberger, Katherine E.; Perkinson, Collin F.; Kovalenko, Maksym V.; Bawendi, Moungi G.

doi:10.1126/science.aau7392

Coherent single-photon emission from colloidal lead halide perovskite quantum dots

Journal Article · Thu Feb 21 00:00:00 EST 2019 · Science

DOI:https://doi.org/10.1126/science.aau7392· OSTI ID:1547714

; ; ; Krieg, Franziska; ; ; Klein, Nathan D.; Shulenberger, Katherine E.; ; ;

Chemically made colloidal semiconductor quantum dots have long been proposed as scalable and color-tunable single emitters in quantum optics, but they have typically suffered from prohibitively incoherent emission. We now demonstrate that individual colloidal lead halide perovskite quantum dots (PQDs) display highly efficient single-photon emission with optical coherence times as long as 80 picoseconds, an appreciable fraction of their 210-picosecond radiative lifetimes. These measurements suggest that PQDs should be explored as building blocks in sources of indistinguishable single photons and entangled photon pairs. Our results present a starting point for the rational design of lead halide perovskite–based quantum emitters that have fast emission, wide spectral tunability, and scalable production and that benefit from the hybrid integration with nanophotonic components that has been demonstrated for colloidal materials.

View Journal Article

Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02-07ER46454; SC0001088

OSTI ID:: 1547714

Alternate ID(s):: OSTI ID: 1566720

Journal Information:: Science, Journal Name: Science Journal Issue: 6431 Vol. 363; ISSN 0036-8075

Publisher:: American Association for the Advancement of Science (AAAS)Copyright Statement

Country of Publication:: United States

Language:: English

References (26)

Ultrafast Room-Temperature Single Photon Emission from Quantum Dots Coupled to Plasmonic Nanocavities Hoang, Thang B.; Akselrod, Gleb M.; Mikkelsen, Maiken H. Nano Letters, Vol. 16, Issue 1 https://doi.org/10.1021/acs.nanolett.5b03724	journal	December 2015
Probing Linewidths and Biexciton Quantum Yields of Single Cesium Lead Halide Nanocrystals in Solution Utzat, Hendrik; Shulenberger, Katherine E.; Achorn, Odin B. Nano Letters, Vol. 17, Issue 11 https://doi.org/10.1021/acs.nanolett.7b03120	journal	October 2017
Colloidal CsPbX ₃ (X = Cl, Br, I) Nanocrystals 2.0: Zwitterionic Capping Ligands for Improved Durability and Stability Krieg, Franziska; Ochsenbein, Stefan T.; Yakunin, Sergii ACS Energy Letters, Vol. 3, Issue 3 https://doi.org/10.1021/acsenergylett.8b00035	journal	February 2018
Single Cesium Lead Halide Perovskite Nanocrystals at Low Temperature: Fast Single-Photon Emission, Reduced Blinking, and Exciton Fine Structure Rainò, Gabriele; Nedelcu, Georgian; Protesescu, Loredana ACS Nano, Vol. 10, Issue 2 https://doi.org/10.1021/acsnano.5b07328	journal	January 2016
Influence of Spectral Diffusion on the Line Shapes of Single CdSe Nanocrystallite Quantum Dots Empedocles, S. A.; Bawendi, M. G. The Journal of Physical Chemistry B, Vol. 103, Issue 11 https://doi.org/10.1021/jp983305x	journal	March 1999
Colloidal Quantum Dots in All-Dielectric High- Q Pillar Microcavities Kahl, Matthias; Thomay, Tim; Kohnle, Verena Nano Letters, Vol. 7, Issue 9 https://doi.org/10.1021/nl071812x	journal	September 2007
High Purcell Factor Due To Coupling of a Single Emitter to a Dielectric Slot Waveguide Kolchin, Pavel; Pholchai, Nitipat; Mikkelsen, Maiken H. Nano Letters, Vol. 15, Issue 1 https://doi.org/10.1021/nl5037808	journal	December 2014
Nanocrystals of Cesium Lead Halide Perovskites (CsPbX ₃ , X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I. Nano Letters, Vol. 15, Issue 6 https://doi.org/10.1021/nl5048779	journal	February 2015
Engineering the Spin–Flip Limited Exciton Dephasing in Colloidal CdSe/CdS Quantum Dots Accanto, Nicolò; Masia, Francesco; Moreels, Iwan ACS Nano, Vol. 6, Issue 6 https://doi.org/10.1021/nn300992a	journal	May 2012
Indistinguishable photons from a single-photon device Santori, Charles; Fattal, David; Vučković, Jelena Nature, Vol. 419, Issue 6907 https://doi.org/10.1038/nature01086	journal	October 2002
Bright triplet excitons in caesium lead halide perovskites Becker, Michael A.; Vaxenburg, Roman; Nedelcu, Georgian Nature, Vol. 553, Issue 7687 https://doi.org/10.1038/nature25147	journal	January 2018
Non-blinking quantum dot with a plasmonic nanoshell resonator Ji, Botao; Giovanelli, Emerson; Habert, Benjamin Nature Nanotechnology, Vol. 10, Issue 2 https://doi.org/10.1038/nnano.2014.298	journal	January 2015
High-performance semiconductor quantum-dot single-photon sources Senellart, Pascale; Solomon, Glenn; White, Andrew Nature Nanotechnology, Vol. 12, Issue 11 https://doi.org/10.1038/nnano.2017.218	journal	November 2017
Solid-state single-photon emitters Aharonovich, Igor; Englund, Dirk; Toth, Milos Nature Photonics, Vol. 10, Issue 10 https://doi.org/10.1038/nphoton.2016.186	journal	September 2016
Charge noise and spin noise in a semiconductor quantum device Kuhlmann, Andreas V.; Houel, Julien; Ludwig, Arne Nature Physics, Vol. 9, Issue 9 https://doi.org/10.1038/nphys2688	journal	July 2013
Efficient coupling of photons to a single molecule and the observation of its resonance fluorescence Wrigge, G.; Gerhardt, I.; Hwang, J. Nature Physics, Vol. 4, Issue 1 https://doi.org/10.1038/nphys812	journal	December 2007
Single photon emission from silicon-vacancy colour centres in chemical vapour deposition nano-diamonds on iridium Neu, Elke; Steinmetz, David; Riedrich-Möller, Janine New Journal of Physics, Vol. 13, Issue 2 https://doi.org/10.1088/1367-2630/13/2/025012	journal	February 2011
Modeling coherence measurements on a spectrally diffusing single-photon emitter Coolen, L.; Brokmann, X.; Hermier, J. -P. Physical Review A, Vol. 76, Issue 3 https://doi.org/10.1103/PhysRevA.76.033824	journal	September 2007
Quantum Emission from Defects in Single-Crystalline Hexagonal Boron Nitride Tran, Toan Trong; Zachreson, Cameron; Berhane, Amanuel Michael Physical Review Applied, Vol. 5, Issue 3 https://doi.org/10.1103/PhysRevApplied.5.034005	journal	March 2016
Quantum Interference of Single Photons from Remote Nitrogen-Vacancy Centers in Diamond Sipahigil, A.; Goldman, M. L.; Togan, E. Physical Review Letters, Vol. 108, Issue 14 https://doi.org/10.1103/PhysRevLett.108.143601	journal	April 2012
Indistinguishable Photons from Separated Silicon-Vacancy Centers in Diamond Sipahigil, A.; Jahnke, K. D.; Rogers, L. J. Physical Review Letters, Vol. 113, Issue 11 https://doi.org/10.1103/PhysRevLett.113.113602	journal	September 2014
Observation of the "Dark Exciton" in CdSe Quantum Dots Nirmal, M.; Norris, D. J.; Kuno, M. Physical Review Letters, Vol. 75, Issue 20 https://doi.org/10.1103/PhysRevLett.75.3728	journal	November 1995
Correlation between Fluorescence Intermittency and Spectral Diffusion in Single Semiconductor Quantum Dots Neuhauser, R. G.; Shimizu, K. T.; Woo, W. K. Physical Review Letters, Vol. 85, Issue 15 https://doi.org/10.1103/PhysRevLett.85.3301	journal	October 2000
Ultralong Dephasing Time in InGaAs Quantum Dots Borri, P.; Langbein, W.; Schneider, S. Physical Review Letters, Vol. 87, Issue 15 https://doi.org/10.1103/PhysRevLett.87.157401	journal	September 2001
Voltage-Controlled Optics of a Quantum Dot Högele, Alexander; Seidl, Stefan; Kroner, Martin Physical Review Letters, Vol. 93, Issue 21 https://doi.org/10.1103/PhysRevLett.93.217401	journal	November 2004
Photon-correlation Fourier spectroscopy Brokmann, Xavier; Bawendi, Moungi; Coolen, Laurent Optics Express, Vol. 14, Issue 13 https://doi.org/10.1364/OE.14.006333	journal	January 2006

Similar Records

Coherent single-photon emission from colloidal lead halide perovskite quantum dots

Journal Article · Wed Feb 20 23:00:00 EST 2019 · Science · OSTI ID:1566720

Colloidal Semiconductor Nanocrystal Lasers and Laser Diodes

Journal Article · Tue Jun 27 20:00:00 EDT 2023 · Chemical Reviews · OSTI ID:1987574

Coherent single-photon emission from colloidal lead halide perovskite quantum dots

Citation Formats

References (26)

Similar Records

Related Subjects