Ni and Se co-doping increases the power factor and thermoelectric performance of CoSbS

You, Yonghui; Su, Xianli; Hao, Shiqiang; Liu, Wei; Yan, Yonggao; Zhang, Tingting; Zhang, Min; Wolverton, Chris; Kanatzidis, Mercouri G.; Tang, Xinfeng

doi:10.1039/c8ta05572f

Ni and Se co-doping increases the power factor and thermoelectric performance of CoSbS

Journal Article · Sun Dec 31 23:00:00 EST 2017 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/c8ta05572f· OSTI ID:1540098

^[1]; ^[2]; Hao, Shiqiang ^[3]; Liu, Wei ^[4]; Yan, Yonggao ^[4]; Zhang, Tingting ^[4]; Zhang, Min ^[4]; Wolverton, Chris ^[3]; ^[5]; ^[4]

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing; Wuhan University of Technology; Wuhan 430070; China; DOE/OSTI
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing; Wuhan University of Technology; Wuhan 430070; China; Department of Chemistry
Department of Materials Science and Engineering; Northwestern University; Evanston; USA
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing; Wuhan University of Technology; Wuhan 430070; China
Department of Chemistry; Northwestern University; Evanston; USA; Department of Materials Science and Engineering

Ni and Se co-doping increases the DOS effective mass and softens the chemical bonding, resulting in the highestZT~ 0.58, 222% improvement over that of CoSbS.

Research Organization:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0014520

OSTI ID:: 1540098

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 31 Vol. 6; ISSN JMCAET; ISSN 2050-7488

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (74)

Origin of the High Performance in GeTe-Based Thermoelectric Materials upon Bi ₂ Te ₃ Doping Wu, Di; Zhao, Li-Dong; Hao, Shiqiang Journal of the American Chemical Society, Vol. 136, Issue 32 https://doi.org/10.1021/ja504896a	journal	August 2014
Thermal Conductivity Tritt, Terry M. https://doi.org/10.1007/b136496	book	January 2004
Doping of thermoelectric PbSe with chemically inert secondary phase nanoparticles Wu, Chao-Feng; Wang, Heng; Yan, Qimin J. Mater. Chem. C, Vol. 5, Issue 41 https://doi.org/10.1039/C7TC03614K	journal	January 2017
The impact of neutral impurity concentration on charge drift mobility in germanium Mei, H.; Mei, D. -M.; Wang, G. -J. arXiv https://doi.org/10.48550/arxiv.1607.03032	text	January 2016
Specific Heats at Low Temperatures Gopal, E. S. R. https://doi.org/10.1007/978-1-4684-9081-7	book	January 1966
High Performance Thermoelectricity in Earth-Abundant Compounds Based on Natural Mineral Tetrahedrites Lu, Xu; Morelli, Donald T.; Xia, Yi Advanced Energy Materials, Vol. 3, Issue 3, p. 342-348 https://doi.org/10.1002/aenm.201200650	journal	October 2012
Increasing the Thermoelectric Figure of Merit of Tetrahedrites by Co-Doping with Nickel and Zinc Lu, Xu; Morelli, Donald T.; Xia, Yi Chemistry of Materials, Vol. 27, Issue 2 https://doi.org/10.1021/cm502570b	journal	January 2015
Ultralow thermal conductivity and high thermoelectric figure of merit in SnSe crystals Zhao, Li-Dong; Lo, Shih-Han; Zhang, Yongsheng Nature, Vol. 508, Issue 7496, p. 373-377 https://doi.org/10.1038/nature13184	journal	April 2014
Phonon conduction in PbSe, PbTe, and PbTe 1 − x Se x from first-principles calculations Tian, Zhiting; Garg, Jivtesh; Esfarjani, Keivan Physical Review B, Vol. 85, Issue 18 https://doi.org/10.1103/PhysRevB.85.184303	journal	May 2012
The texture related anisotropy of thermoelectric properties in bismuth telluride based polycrystalline alloys Shen, J. J.; Hu, L. P.; Zhu, T. J. Applied Physics Letters, Vol. 99, Issue 12 https://doi.org/10.1063/1.3643051	journal	September 2011
Novel ternary sulfide thermoelectric materials from high throughput transport and defect calculations Bhattacharya, Sandip; Chmielowski, Radoslaw; Dennler, Gilles Journal of Materials Chemistry A, Vol. 4, Issue 28 https://doi.org/10.1039/C6TA04104C	journal	January 2016
Ultrahigh power factor and thermoelectric performance in hole-doped single-crystal SnSe Zhao, L.-D.; Tan, G.; Hao, S. Science, Vol. 351, Issue 6269, p. 141-144 https://doi.org/10.1126/science.aad3749	journal	November 2015
The effect of nickel doping on electron and phonon transport in the n-type nanostructured thermoelectric material CoSbS Liu, Zihang; Geng, Huiyuan; Shuai, Jing Journal of Materials Chemistry C, Vol. 3, Issue 40 https://doi.org/10.1039/C5TC01560J	journal	January 2015
Thermoelectric properties of CoSb3 Kawaharada, Yoshiyuki; Kurosaki, Ken; Uno, Masayoshi Journal of Alloys and Compounds, Vol. 315, Issue 1-2 https://doi.org/10.1016/S0925-8388(00)01275-5	journal	February 2001
Mechanochemical synthesis and thermoelectric properties of high quality magnesium silicide Bux, Sabah K.; Yeung, Michael T.; Toberer, Eric S. Journal of Materials Chemistry, Vol. 21, Issue 33 https://doi.org/10.1039/c1jm10827a	journal	January 2011
Multiple nanostructures in high performance Cu2S0.5Te0.5 thermoelectric materials Zhu, Chenxi; He, Ying; Lu, Ping Ceramics International, Vol. 43, Issue 10 https://doi.org/10.1016/j.ceramint.2017.03.103	journal	July 2017
Thermoelectric properties of p -type CuInSe 2 chalcopyrites enhanced by introduction of manganese Yao, Jinlei; Takas, Nathan J.; Schliefert, Megan L. Physical Review B, Vol. 84, Issue 7 https://doi.org/10.1103/PhysRevB.84.075203	journal	August 2011
High thermoelectric performance of mechanically robust n-type Bi ₂ Te _3−x Se _x prepared by combustion synthesis Zheng, Gang; Su, Xianli; Liang, Tao Journal of Materials Chemistry A, Vol. 3, Issue 12 https://doi.org/10.1039/C5TA00470E	journal	January 2015
Complex thermoelectric materials Snyder, G. Jeffrey; Toberer, Eric S. Materials for Sustainable Energy https://doi.org/10.1142/9789814317665_0016	book	October 2010
The panoscopic approach to high performance thermoelectrics Zhao, Li-Dong; Dravid, Vinayak P.; Kanatzidis, Mercouri G. Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE43099E	journal	January 2014
Effect of Isotopes on Low-Temperature Thermal Conductivity Slack, Glen A. Physical Review, Vol. 105, Issue 3 https://doi.org/10.1103/PhysRev.105.829	journal	February 1957
Suppressed intrinsic excitation and enhanced thermoelectric performance in Ag _x Bi _0.5 Sb _1.5−x Te ₃ Xing, Tong; Liu, Ruiheng; Hao, Feng Journal of Materials Chemistry C, Vol. 5, Issue 47 https://doi.org/10.1039/C7TC04573E	journal	January 2017
High thermoelectric performance of p-BiSbTe compounds prepared by ultra-fast thermally induced reaction Zheng, Gang; Su, Xianli; Xie, Hongyao Energy & Environmental Science, Vol. 10, Issue 12 https://doi.org/10.1039/C7EE02677C	journal	January 2017
Strained endotaxial nanostructures with high thermoelectric figure of merit Biswas, Kanishka; He, Jiaqing; Zhang, Qichun Nature Chemistry, Vol. 3, Issue 2 https://doi.org/10.1038/nchem.955	journal	January 2011
High Thermoelectric Performance in Electron-Doped AgBi ₃ S ₅ with Ultralow Thermal Conductivity Tan, Gangjian; Hao, Shiqiang; Zhao, Jing Journal of the American Chemical Society, Vol. 139, Issue 18 https://doi.org/10.1021/jacs.7b02399	journal	May 2017
Large enhancement of thermoelectric properties in n-type PbTe via dual-site point defects Fu, Liangwei; Yin, Meijie; Wu, Di Energy & Environmental Science, Vol. 10, Issue 9 https://doi.org/10.1039/C7EE01871A	journal	January 2017
Cooling, Heating, Generating Power, and Recovering Waste Heat with Thermoelectric Systems Bell, L. E. Science, Vol. 321, Issue 5895, p. 1457-1461 https://doi.org/10.1126/science.1158899	journal	September 2008
High-performance thermoelectric mineral Cu _{12− x} Ni _x Sb ₄ S ₁₃ tetrahedrite Suekuni, Koichiro; Tsuruta, Kojiro; Kunii, Masaru Journal of Applied Physics, Vol. 113, Issue 4 https://doi.org/10.1063/1.4789389	journal	January 2013
Effect of alloying on thermal conductivity and thermoelectric properties of CoAsS and CoSbS Kaur, Prabhjot; Bera, Chandan Physical Chemistry Chemical Physics, Vol. 19, Issue 36 https://doi.org/10.1039/C7CP05170K	journal	January 2017
Low effective mass and carrier concentration optimization for high performance p-type Mg _2(1−x) Li _2x Si _0.3 Sn _0.7 solid solutions Zhang, Qiang; Cheng, Long; Liu, Wei Phys. Chem. Chem. Phys., Vol. 16, Issue 43 https://doi.org/10.1039/C4CP03468F	journal	January 2014
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Real Structure and Thermoelectric Properties of GeTe-Rich Germanium Antimony Tellurides Rosenthal, Tobias; Schneider, Matthias N.; Stiewe, Christian Chemistry of Materials, Vol. 23, Issue 19 https://doi.org/10.1021/cm201717z	journal	October 2011
Thermal Conductivity Hawkins, Donald T. Physical and Chemical Properties of Water https://doi.org/10.1007/978-1-4684-1381-6_10	book	January 1976
Convergence of Conduction Bands as a Means of Enhancing Thermoelectric Performance of n -Type Mg 2 Si 1 − x Sn x Solid Solutions Liu, Wei; Tan, Xiaojian; Yin, Kang Physical Review Letters, Vol. 108, Issue 16 https://doi.org/10.1103/PhysRevLett.108.166601	journal	April 2012
The best thermoelectric. Mahan, G. D.; Sofo, J. O. Proceedings of the National Academy of Sciences, Vol. 93, Issue 15 https://doi.org/10.1073/pnas.93.15.7436	journal	July 1996
High ZT in p-Type (PbTe) _{1–2 x} (PbSe) _x (PbS) _x Thermoelectric Materials Korkosz, Rachel J.; Chasapis, Thomas C.; Lo, Shih-han Journal of the American Chemical Society, Vol. 136, Issue 8 https://doi.org/10.1021/ja4121583	journal	February 2014
New and Old Concepts in Thermoelectric Materials Sootsman, Joseph R.; Chung, Duck Young; Kanatzidis, Mercouri G. Angewandte Chemie International Edition, Vol. 48, Issue 46, p. 8616-8639 https://doi.org/10.1002/anie.200900598	journal	November 2009
Low-cost, abundant binary sulfides as promising thermoelectric materials Ge, Zhen-Hua; Zhao, Li-Dong; Wu, Di Materials Today, Vol. 19, Issue 4 https://doi.org/10.1016/j.mattod.2015.10.004	journal	May 2016
Lattice Thermal Conductivity of Disordered Semiconductor Alloys at High Temperatures Abeles, B. Physical Review, Vol. 131, Issue 5 https://doi.org/10.1103/PhysRev.131.1906	journal	September 1963
Chalcopyrite CuGaTe2: A High-Efficiency Bulk Thermoelectric Material Plirdpring, Theerayuth; Kurosaki, Ken; Kosuga, Atsuko Advanced Materials, Vol. 24, Issue 27 https://doi.org/10.1002/adma.201200732	journal	June 2012
Thermopower enhancement in Pb1−xMnxTe alloys and its effect on thermoelectric efficiency Pei, Yanzhong; Wang, Heng; Gibbs, Zachary M. NPG Asia Materials, Vol. 4, Issue 9 https://doi.org/10.1038/am.2012.52	journal	September 2012
Synergistic Strategy to Enhance the Thermoelectric Properties of CoSbS _{1– x} Se _x Compounds via Solid Solution Yao, Wei; Yang, Dingfeng; Yan, Yanci ACS Applied Materials & Interfaces, Vol. 9, Issue 12 https://doi.org/10.1021/acsami.6b12796	journal	March 2017
Strain field fluctuation effects on lattice thermal conductivity of ZrNiSn-based thermoelectric compounds Yang, J.; Meisner, G. P.; Chen, L. Applied Physics Letters, Vol. 85, Issue 7 https://doi.org/10.1063/1.1783022	journal	August 2004
Cu–Bi–Se-based pavonite homologue: a promising thermoelectric material with low lattice thermal conductivity Cho, Jung Young; Mun, Hyeona; Ryu, Byungki Journal of Materials Chemistry A, Vol. 1, Issue 34 https://doi.org/10.1039/c3ta11457k	journal	January 2013
High Thermoelectric Performance and Enhanced Mechanical Stability of p -type Ge _{1– x} Sb _x Te Perumal, Suresh; Roychowdhury, Subhajit; Negi, Devendra S. Chemistry of Materials, Vol. 27, Issue 20 https://doi.org/10.1021/acs.chemmater.5b03434	journal	October 2015
Non-equilibrium processing leads to record high thermoelectric figure of merit in PbTe–SrTe Tan, Gangjian; Shi, Fengyuan; Hao, Shiqiang Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12167	journal	July 2016
Point Defect Engineering of High-Performance Bismuth-Telluride-Based Thermoelectric Materials Hu, Lipeng; Zhu, Tiejun; Liu, Xiaohua Advanced Functional Materials, Vol. 24, Issue 33 https://doi.org/10.1002/adfm.201400474	journal	June 2014
The impact of neutral impurity concentration on charge drift mobility in p-type germanium Mei, H.; Mei, D. -M.; Wang, G. -J. Journal of Instrumentation, Vol. 11, Issue 12 https://doi.org/10.1088/1748-0221/11/12/P12021	journal	December 2016
WinPLOTR: A Windows Tool for Powder Diffraction Pattern Analysis Roisnel, T.; Rodríquez-Carvajal, Juan Materials Science Forum, Vol. 378-381 https://doi.org/10.4028/www.scientific.net/MSF.378-381.118	journal	October 2001
Effect of Point Imperfections on Lattice Thermal Conductivity Callaway, Joseph; von Baeyer, Hans C. Physical Review, Vol. 120, Issue 4 https://doi.org/10.1103/PhysRev.120.1149	journal	November 1960
Electronic and thermoelectric properties of CoSbS and FeSbS Parker, David; May, Andrew F.; Wang, Hsin Physical Review B, Vol. 87, Issue 4 https://doi.org/10.1103/PhysRevB.87.045205	journal	January 2013
Thermoelectric Transport in Cu ₇ PSe ₆ with High Copper Ionic Mobility Weldert, Kai S.; Zeier, Wolfgang G.; Day, Tristan W. Journal of the American Chemical Society, Vol. 136, Issue 34 https://doi.org/10.1021/ja5056092	journal	August 2014
Bulk nanostructured thermoelectric materials: current research and future prospects Minnich, A. J.; Dresselhaus, M. S.; Ren, Z. F. Energy & Environmental Science, Vol. 2, Issue 5 https://doi.org/10.1039/b822664b	journal	January 2009
Natural mineral tetrahedrite as a direct source of thermoelectric materials Lu, Xu; Morelli, Donald T. Physical Chemistry Chemical Physics, Vol. 15, Issue 16 https://doi.org/10.1039/c3cp50920f	journal	January 2013
Rationally Designing High-Performance Bulk Thermoelectric Materials Tan, Gangjian; Zhao, Li-Dong; Kanatzidis, Mercouri G. Chemical Reviews, Vol. 116, Issue 19 https://doi.org/10.1021/acs.chemrev.6b00255	journal	August 2016
Lower limit to the thermal conductivity of disordered crystals Cahill, David G.; Watson, S. K.; Pohl, R. O. Physical Review B, Vol. 46, Issue 10, p. 6131-6140 https://doi.org/10.1103/PhysRevB.46.6131	journal	September 1992
Microstructure and thermoelectric properties of CoSb2.75Ge0.25−xTex prepared by rapid solidification Su, Xianli; Li, Han; Yan, Yonggao Acta Materialia, Vol. 60, Issue 8 https://doi.org/10.1016/j.actamat.2012.02.034	journal	May 2012
Self-propagating high-temperature synthesis for compound thermoelectrics and new criterion for combustion processing Su, Xianli; Fu, Fan; Yan, Yonggao Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5908	journal	September 2014
Strong Reduction of Thermal Conductivity and Enhanced Thermoelectric Properties in CoSbS1-xSex Paracostibite Chmielowski, Radoslaw; Bhattacharya, Sandip; Jacob, Stéphane Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep46630	journal	April 2017
High Performance Thermoelectrics from Earth-Abundant Materials: Enhanced Figure of Merit in PbS by Second Phase Nanostructures Zhao, Li-Dong; Lo, Shih-Han; He, Jiaqing Journal of the American Chemical Society, Vol. 133, Issue 50 https://doi.org/10.1021/ja208658w	journal	December 2011
Extraordinary Thermoelectric Performance Realized in n-Type PbTe through Multiphase Nanostructure Engineering Zhang, Jian; Wu, Di; He, Dongsheng Advanced Materials, Vol. 29, Issue 39 https://doi.org/10.1002/adma.201703148	journal	August 2017
Weak electron-phonon coupling contributing to high thermoelectric performance in n-type PbSe Wang, H.; Pei, Y.; LaLonde, A. D. Proceedings of the National Academy of Sciences, Vol. 109, Issue 25 https://doi.org/10.1073/pnas.1111419109	journal	May 2012
Mechanical properties of nanostructured thermoelectric materials α-MgAgSb Liu, Zihang; Gao, Weihong; Meng, Xianfu Scripta Materialia, Vol. 127 https://doi.org/10.1016/j.scriptamat.2016.08.037	journal	January 2017
Thinking Like a Chemist: Intuition in Thermoelectric Materials Zeier, Wolfgang G.; Zevalkink, Alex; Gibbs, Zachary M. Angewandte Chemie International Edition, Vol. 55, Issue 24 https://doi.org/10.1002/anie.201508381	journal	April 2016
Optimized Thermoelectric Properties of Sb-Doped Mg _{2(1+ z )} Si _{0.5– y} Sn _0.5 Sb _y through Adjustment of the Mg Content Liu, Wei; Tang, Xinfeng; Li, Han Chemistry of Materials, Vol. 23, Issue 23 https://doi.org/10.1021/cm202445d	journal	December 2011
Complex thermoelectric materials Snyder, G. Jeffrey; Toberer, Eric S. Nature Materials, Vol. 7, Issue 2, p. 105-114 https://doi.org/10.1038/nmat2090	journal	February 2008
Band Engineering of Thermoelectric Materials Pei, Yanzhong; Wang, Heng; Snyder, G. J. Advanced Materials, Vol. 24, Issue 46 https://doi.org/10.1002/adma.201202919	journal	October 2012
Modification of the intermediate band and thermoelectric properties in Se-doped CoSbS _1−x Se _x compounds You, Yonghui; Su, Xianli; Liu, Wei RSC Advances, Vol. 7, Issue 55 https://doi.org/10.1039/C7RA05609E	journal	January 2017
All-scale hierarchical thermoelectrics: MgTe in PbTe facilitates valence band convergence and suppresses bipolar thermal transport for high performance Zhao, L. D.; Wu, H. J.; Hao, S. Q. Energy & Environmental Science, Vol. 6, Issue 11 https://doi.org/10.1039/c3ee42187b	journal	January 2013
The Scattering of Low-Frequency Lattice Waves by Static Imperfections Klemens, P. G. Proceedings of the Physical Society. Section A, Vol. 68, Issue 12 https://doi.org/10.1088/0370-1298/68/12/303	journal	December 1955
Synthesis, processing, and thermoelectric properties of bulk nanostructured bismuth telluride (Bi ₂ Te ₃ ) Saleemi, Mohsin; Toprak, Muhammet S.; Li, Shanghua J. Mater. Chem., Vol. 22, Issue 2 https://doi.org/10.1039/C1JM13880D	journal	January 2012
Intrinsic low thermal conductivity in weakly ionic rocksalt structures Zhang, Yi; Dong, Jianjun; Kent, Paul R. C. Physical Review B, Vol. 92, Issue 2 https://doi.org/10.1103/PhysRevB.92.020301	journal	July 2015
Enhanced thermoelectric properties of bismuth telluride bulk achieved by telluride-spilling during the spark plasma sintering process Ge, Zhen-Hua; Ji, Yi-Hong; Qiu, Yang Scripta Materialia, Vol. 143 https://doi.org/10.1016/j.scriptamat.2017.09.020	journal	January 2018
High thermoelectric performance of tellurium doped paracostibite Chmielowski, R.; Bhattacharya, S.; Xie, W. Journal of Materials Chemistry C, Vol. 4, Issue 15 https://doi.org/10.1039/C6TC00410E	journal	January 2016

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