skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Schiff-base coordination complexes with plutonium( iv ) and cerium( iv )

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/c8cc03571g· OSTI ID:1539983
 [1];  [1]; ORCiD logo [1];  [1]; ORCiD logo [1]
  1. Department of Chemistry and Biochemistry; Florida State University; Tallahassee; USA
+ Show Author Affiliations

The synthesis and characterization of a Pu(iv) salen complex reveals the stabilization of the +4 oxidation state with respect to that observed with Ce(iv).

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Actinide Science & Technology (CAST); Florida State Univ., Tallahassee, FL (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0016568
OSTI ID:
1539983
Journal Information:
ChemComm, Vol. 54, Issue 62; ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (19)

Recent developments in nonaqueous plutonium coordination chemistry journal June 2010
Metal–Salen Schiff base complexes in catalysis: practical aspects journal January 2004
Ion size dominated 1D and 2D Salen lanthanide coordination complexes and their luminescence journal November 2007
Crystal engineering of salen type cerium complexes tuned by various cerium counterions journal January 2013
Near-infrared luminescence and RNA cleavage ability of lanthanide Schiff base complexes derived from N,N′-bis(3-methoxysalicylidene)ethylene-1,2-diamine ligands journal October 2016
Structure and electrochemistry of salen type cerium (IV) complexes tuned by multiform counterions journal August 2013
Effect of alcohols on elution chromatography of trivalent actinides and lanthanides using tertiary pyridine resin with hydrochloric acid–alcohol mixed solvents journal July 2004
Experimental and Theoretical Comparison of Actinide and Lanthanide Bonding in M[N(EPR 2 ) 2 ] 3 Complexes (M = U, Pu, La, Ce; E = S, Se, Te; R = Ph, i Pr, H) journal January 2008
X-Ray Crystallographic Approach to the Design of Phenolic Schiff Base Reagents for the Mutual Separation of Lanthanoids. journal January 2001
Synthesis and Structure of the Cerium Schiff-Base Complexes [Ce(Salen′)2] and [(THF)2KCe(Salen′)2] journal March 2008
Synthesis, structure, and magnetic properties of a self-assembled salicylaldimine neodymium(III) nitrate coordination polymer journal October 2009
Th( iv ) and Ce( iv ) napthylsalophen sandwich complexes: characterization of unusual thorium fluorescence in solution and solid-state journal January 2017
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal September 1976
Th(VO 3 ) 2 (SeO 3 ) and Ln(VO 3 ) 2 (IO 3 ) (Ln = Ce, Pr, Nd, Sm, and Eu): unusual cases of aliovalent substitution journal January 2014
Deviation Between the Chemistry of Ce(IV) and Pu(IV) and Routes to Ordered and Disordered Heterobimetallic 4f/5f and 5f/5f Phosphonates journal June 2011
Self-assembly in lanthanum(III) and calcium(II) complexes of salicylaldimines derived from putrescine journal February 2008
Different supramolecular architectures in self-assembled praseodymium(III) and europium(III) complexes with rare coordination pattern of salicylaldimine ligand journal September 2015
X-ray crystal structure and nuclear Overhauser effect studies of cerium(IV) complexes with Schiff bases obtained from N,N′-(1R,2R)(−)-1,2-cyclohexanediamine and benzaldehyde derivatives journal February 2008
Multielectron redox chemistry of lanthanide Schiff-base complexes journal January 2012

Similar Records

Related Subjects

Chemistry