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Title: Schiff-base coordination complexes with plutonium( iv ) and cerium( iv )

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/C8CC03571G· OSTI ID:1460893
 [1];  [1]; ORCiD logo [1];  [1]; ORCiD logo [1]
  1. Department of Chemistry and Biochemistry, Florida State University, Tallahassee, USA
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The synthesis and characterization of a Pu( iv ) salen complex reveals the stabilization of the +4 oxidation state with respect to that observed with Ce( iv ).

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0016568
OSTI ID:
1460893
Journal Information:
ChemComm, Journal Name: ChemComm Vol. 54 Journal Issue: 62; ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English
Citation Metrics:
Cited by: 29 works
Citation information provided by
Web of Science

References (19)

Experimental and Theoretical Comparison of Actinide and Lanthanide Bonding in M[N(EPR 2 ) 2 ] 3 Complexes (M = U, Pu, La, Ce; E = S, Se, Te; R = Ph, i Pr, H) journal January 2008
Deviation Between the Chemistry of Ce(IV) and Pu(IV) and Routes to Ordered and Disordered Heterobimetallic 4f/5f and 5f/5f Phosphonates journal June 2011
Th( iv ) and Ce( iv ) napthylsalophen sandwich complexes: characterization of unusual thorium fluorescence in solution and solid-state journal January 2017
Th(VO 3 ) 2 (SeO 3 ) and Ln(VO 3 ) 2 (IO 3 ) (Ln = Ce, Pr, Nd, Sm, and Eu): unusual cases of aliovalent substitution journal January 2014
X-ray crystal structure and nuclear Overhauser effect studies of cerium(IV) complexes with Schiff bases obtained from N,N′-(1R,2R)(−)-1,2-cyclohexanediamine and benzaldehyde derivatives journal February 2008
Synthesis and Structure of the Cerium Schiff-Base Complexes [Ce(Salen′)2] and [(THF)2KCe(Salen′)2] journal March 2008
Different supramolecular architectures in self-assembled praseodymium(III) and europium(III) complexes with rare coordination pattern of salicylaldimine ligand journal September 2015
Metal–Salen Schiff base complexes in catalysis: practical aspects journal January 2004
Self-assembly in lanthanum(III) and calcium(II) complexes of salicylaldimines derived from putrescine journal February 2008
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal September 1976
Multielectron redox chemistry of lanthanide Schiff-base complexes journal January 2012
Ion size dominated 1D and 2D Salen lanthanide coordination complexes and their luminescence journal November 2007
Crystal engineering of salen type cerium complexes tuned by various cerium counterions journal January 2013
Near-infrared luminescence and RNA cleavage ability of lanthanide Schiff base complexes derived from N,N′-bis(3-methoxysalicylidene)ethylene-1,2-diamine ligands journal October 2016
Recent developments in nonaqueous plutonium coordination chemistry journal June 2010
Synthesis, structure, and magnetic properties of a self-assembled salicylaldimine neodymium(III) nitrate coordination polymer journal October 2009
X-Ray Crystallographic Approach to the Design of Phenolic Schiff Base Reagents for the Mutual Separation of Lanthanoids. journal January 2001
Structure and electrochemistry of salen type cerium (IV) complexes tuned by multiform counterions journal August 2013
Effect of alcohols on elution chromatography of trivalent actinides and lanthanides using tertiary pyridine resin with hydrochloric acid–alcohol mixed solvents journal July 2004

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