Interfacial Thermal Conductance between Mechanically Exfoliated Black Phosphorus and SiOx : Effect of Thickness and Temperature

Wang, Tianyu; Wang, Ridong; Yuan, Pengyu; Xu, Shen; Liu, Jing; Wang, Xinwei

doi:10.1002/admi.201700233

Interfacial Thermal Conductance between Mechanically Exfoliated Black Phosphorus and SiO_x : Effect of Thickness and Temperature

Journal Article · Mon Jul 10 00:00:00 EDT 2017 · Advanced Materials Interfaces

DOI:https://doi.org/10.1002/admi.201700233· OSTI ID:1533051

Wang, Tianyu ^[1]; Wang, Ridong ^[2]; Yuan, Pengyu ^[2]; Xu, Shen ^[3]; Liu, Jing ^[2]; ^[2]

Iowa State Univ., Ames, IA (United States); DOE/OSTI
Iowa State Univ., Ames, IA (United States)
Shanghai Univ. of Engineering Science, Shanghai (China)

Black phosphorus (BP) is one of new 2D materials that have attracted wide attention. This work reports the interfacial thermal conductance between BP flake and SiO_x using Raman spectroscopy. From 293 K down to the 223 K, eight BP flakes in a thickness range of 16.6–113.7 nm are characterized. At 293 K, the largest interfacial thermal conductance is 1.14 × 10⁸ W m⁻² K⁻¹ for a 82.1 nm thick BP flake, and the smallest one is 2.17 × 10⁷ W m⁻² K⁻¹ for a 26.6 nm thick BP flake. Such large interfacial thermal conductance can be attributed to the excellent interface contact and strong phonon coupling between BP and SiO_x. Furthermore, the measured interfacial thermal conductance has a one‐fold up to around four‐fold increase with decreased temperature from 293 to 223 K, which is a result of thermal‐expansion‐mismatch induced variation in the morphology of BP flakes. Additionally, it demonstrates no thickness‐dependent behavior. It is speculated the intrinsic thickness dependence is weak and is overshadowed by the large variation in the interface contact of different samples. As a new 2D material, BP shows great potential to be a thermal interface material for heat dissipation in electronics.

View Accepted Manuscript (DOE)

Research Organization:: Iowa State Univ., Ames, IA (United States)

Sponsoring Organization:: Iowa Energy Center; National Science Foundation (NSF); USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0007686; NE0000671

OSTI ID:: 1533051

Alternate ID(s):: OSTI ID: 1376746

Journal Information:: Advanced Materials Interfaces, Journal Name: Advanced Materials Interfaces Journal Issue: 16 Vol. 4; ISSN 2196-7350

Publisher:: Wiley-VCHCopyright Statement

Country of Publication:: United States

Language:: English

References (39)

Anisotropic Thermal Conductivity of Exfoliated Black Phosphorus Jang, Hyejin; Wood, Joshua D.; Ryder, Christopher R. Advanced Materials, Vol. 27, Issue 48 https://doi.org/10.1002/adma.201503466	journal	October 2015
Temperature Dependence of Anisotropic Thermal-Conductivity Tensor of Bulk Black Phosphorus Sun, Bo; Gu, Xiaokun; Zeng, Qingsheng Advanced Materials, Vol. 29, Issue 3 https://doi.org/10.1002/adma.201603297	journal	November 2016
Temperature and Thickness Dependences of the Anisotropic In-Plane Thermal Conductivity of Black Phosphorus Smith, Brandon; Vermeersch, Bjorn; Carrete, Jesús Advanced Materials, Vol. 29, Issue 5 https://doi.org/10.1002/adma.201603756	journal	November 2016
Micro/Nanoscale Spatial Resolution Temperature Probing for the Interfacial Thermal Characterization of Epitaxial Graphene on 4H-SiC Yue, Yanan; Zhang, Jingchao; Wang, Xinwei Small, Vol. 7, Issue 23 https://doi.org/10.1002/smll.201101598	journal	October 2011
Effects of substrate type and material-substrate bonding on high-temperature behavior of monolayer WS2 Su, Liqin; Yu, Yifei; Cao, Linyou Nano Research, Vol. 8, Issue 8 https://doi.org/10.1007/s12274-015-0775-1	journal	August 2015
Composition and structure of the native Si oxide by high depth resolution medium energy ion scatering Al-Bayati, Amir H.; Orrman-Rossiter, Kevin G.; van den Berg, J. A. Surface Science, Vol. 241, Issue 1-2 https://doi.org/10.1016/0039-6028(91)90214-D	journal	January 1991
Interfacial thermal conductance between few to tens of layered-MoS2 and c-Si: Effect of MoS2 thickness Yuan, Pengyu; Li, Chong; Xu, Shen Acta Materialia, Vol. 122 https://doi.org/10.1016/j.actamat.2016.09.045	journal	January 2017
Improved topological conformity enhances heat conduction across metal contacts on transferred graphene Huang, Bin; Koh, Yee Kan Carbon, Vol. 105 https://doi.org/10.1016/j.carbon.2016.04.005	journal	August 2016
Effects of temperature and disorder on thermal boundary conductance at solid–solid interfaces: Nonequilibrium molecular dynamics simulations Stevens, Robert J.; Zhigilei, Leonid V.; Norris, Pamela M. International Journal of Heat and Mass Transfer, Vol. 50, Issue 19-20 https://doi.org/10.1016/j.ijheatmasstransfer.2007.01.040	journal	September 2007
Molecular dynamics simulation of the interfacial thermal resistance between phosphorene and silicon substrate Zhang, Jingchao; Hong, Yang; Liu, Mengqi International Journal of Heat and Mass Transfer, Vol. 104 https://doi.org/10.1016/j.ijheatmasstransfer.2016.08.021	journal	January 2017
First-principles study of thermal expansion and thermomechanics of single-layer black and blue phosphorus Sun, Hongyi; Liu, Gang; Li, Qingfang Physics Letters A, Vol. 380, Issue 24 https://doi.org/10.1016/j.physleta.2016.04.021	journal	May 2016
Anisotropic Mechanical Properties of Black Phosphorus Nanoribbons Chen, Hao; Huang, Peng; Guo, Dan The Journal of Physical Chemistry C, Vol. 120, Issue 51 https://doi.org/10.1021/acs.jpcc.6b10644	journal	December 2016
Anisotropic Electron-Photon and Electron-Phonon Interactions in Black Phosphorus Ling, Xi; Huang, Shengxi; Hasdeo, Eddwi H. Nano Letters, Vol. 16, Issue 4 https://doi.org/10.1021/acs.nanolett.5b04540	journal	March 2016
Temperature-Dependent Thermal Properties of Supported MoS ₂ Monolayers Taube, Andrzej; Judek, Jarosław; Łapińska, Anna ACS Applied Materials & Interfaces, Vol. 7, Issue 9 https://doi.org/10.1021/acsami.5b00690	journal	February 2015
Five Orders of Magnitude Reduction in Energy Coupling across Corrugated Graphene/Substrate Interfaces Tang, Xiaoduan; Xu, Shen; Zhang, Jingchao ACS Applied Materials & Interfaces, Vol. 6, Issue 4 https://doi.org/10.1021/am405388a	journal	February 2014
Temperature Dependent Phonon Shifts in Few-Layer Black Phosphorus Late, Dattatray J. ACS Applied Materials & Interfaces, Vol. 7, Issue 10 https://doi.org/10.1021/am509056b	journal	March 2015
Optical Anisotropy of Black Phosphorus in the Visible Regime Mao, Nannan; Tang, Jingyi; Xie, Liming Journal of the American Chemical Society, Vol. 138, Issue 1 https://doi.org/10.1021/jacs.5b10685	journal	December 2015
Negative Thermal Expansion Coefficient of Graphene Measured by Raman Spectroscopy Yoon, Duhee; Son, Young-Woo; Cheong, Hyeonsik Nano Letters, Vol. 11, Issue 8 https://doi.org/10.1021/nl201488g	journal	August 2011
Fast and Broadband Photoresponse of Few-Layer Black Phosphorus Field-Effect Transistors Buscema, Michele; Groenendijk, Dirk J.; Blanter, Sofya I. Nano Letters, Vol. 14, Issue 6 https://doi.org/10.1021/nl5008085	journal	May 2014
Strain-Engineering the Anisotropic Electrical Conductance of Few-Layer Black Phosphorus Fei, Ruixiang; Yang, Li Nano Letters, Vol. 14, Issue 5 https://doi.org/10.1021/nl500935z	journal	April 2014
Effective Passivation of Exfoliated Black Phosphorus Transistors against Ambient Degradation Wood, Joshua D.; Wells, Spencer A.; Jariwala, Deep Nano Letters, Vol. 14, Issue 12 https://doi.org/10.1021/nl5032293	journal	November 2014
Phosphorene: An Unexplored 2D Semiconductor with a High Hole Mobility Liu, Han; Neal, Adam T.; Zhu, Zhen ACS Nano, Vol. 8, Issue 4 https://doi.org/10.1021/nn501226z	journal	March 2014
Rediscovering black phosphorus as an anisotropic layered material for optoelectronics and electronics Xia, Fengnian; Wang, Han; Jia, Yichen Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5458	journal	July 2014
High-mobility transport anisotropy and linear dichroism in few-layer black phosphorus Qiao, Jingsi; Kong, Xianghua; Hu, Zhi-Xin Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5475	journal	July 2014
Transport properties of pristine few-layer black phosphorus by van der Waals passivation in an inert atmosphere Doganov, Rostislav A.; O’Farrell, Eoin C. T.; Koenig, Steven P. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7647	journal	April 2015
Probing molecular dynamics at the nanoscale via an individual paramagnetic centre Staudacher, T.; Raatz, N.; Pezzagna, S. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9527	journal	October 2015
Anisotropic in-plane thermal conductivity of black phosphorus nanoribbons at temperatures higher than 100 K Lee, Sangwook; Yang, Fan; Suh, Joonki Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9573	journal	October 2015
Photooxidation and quantum confinement effects in exfoliated black phosphorus Favron, Alexandre; Gaufrès, Etienne; Fossard, Frédéric Nature Materials, Vol. 14, Issue 8 https://doi.org/10.1038/nmat4299	journal	May 2015
Black phosphorus field-effect transistors Li, Likai; Yu, Yijun; Ye, Guo Jun Nature Nanotechnology, Vol. 9, Issue 5 https://doi.org/10.1038/nnano.2014.35	journal	March 2014
Highly anisotropic and robust excitons in monolayer black phosphorus Wang, Xiaomu; Jones, Aaron M.; Seyler, Kyle L. Nature Nanotechnology, Vol. 10, Issue 6 https://doi.org/10.1038/nnano.2015.71	journal	April 2015
Dependence of coupling of quasi 2-D MoS ₂ with substrates on substrate types, probed by temperature dependent Raman scattering Su, Liqin; Zhang, Yong; Yu, Yifei Nanoscale, Vol. 6, Issue 9 https://doi.org/10.1039/C3NR06462J	journal	January 2014
Growth of native oxide on a silicon surface Morita, M.; Ohmi, T.; Hasegawa, E. Journal of Applied Physics, Vol. 68, Issue 3, p. 1272-1281 https://doi.org/10.1063/1.347181	journal	August 1990
Superior mechanical flexibility of phosphorene and few-layer black phosphorus Wei, Qun; Peng, Xihong Applied Physics Letters, Vol. 104, Issue 25 https://doi.org/10.1063/1.4885215	journal	June 2014
Recommended Values for the Thermal Expansivity of Silicon from 0 to 1000 K Swenson, C. A. Journal of Physical and Chemical Reference Data, Vol. 12, Issue 2 https://doi.org/10.1063/1.555681	journal	April 1983
Mechanical properties of single-layer black phosphorus Jiang, Jin-Wu; Park, Harold S. Journal of Physics D: Applied Physics, Vol. 47, Issue 38 https://doi.org/10.1088/0022-3727/47/38/385304	journal	August 2014
Deterministic transfer of two-dimensional materials by all-dry viscoelastic stamping Castellanos-Gomez, Andres; Buscema, Michele; Molenaar, Rianda 2D Materials, Vol. 1, Issue 1 https://doi.org/10.1088/2053-1583/1/1/011002	journal	April 2014
Isolation and characterization of few-layer black phosphorus Castellanos-Gomez, Andres; Vicarelli, Leonardo; Prada, Elsa 2D Materials, Vol. 1, Issue 2 https://doi.org/10.1088/2053-1583/1/2/025001	journal	June 2014
Thermal Transport across Solid Interfaces with Nanoscale Imperfections: Effects of Roughness, Disorder, Dislocations, and Bonding on Thermal Boundary Conductance Hopkins, Patrick E. ISRN Mechanical Engineering, Vol. 2013 https://doi.org/10.1155/2013/682586	journal	January 2013
Vacancy-defect–induced diminution of thermal conductivity in silicene Li, Hai-peng; Zhang, Rui-qin EPL (Europhysics Letters), Vol. 99, Issue 3 https://doi.org/10.1209/0295-5075/99/36001	journal	August 2012

Cited By (3)

Impact of Nanoscale Roughness on Heat Transport across the Solid–Solid Interface Wang, Jingwei; Zhang, Zhongwei; Shi, Run Advanced Materials Interfaces, Vol. 7, Issue 4 https://doi.org/10.1002/admi.201901582	journal	December 2019
Nonmonotonic thickness-dependence of in-plane thermal conductivity of few-layered MoS ₂ : 2.4 to 37.8 nm Yuan, Pengyu; Wang, Ridong; Wang, Tianyu Physical Chemistry Chemical Physics, Vol. 20, Issue 40 https://doi.org/10.1039/c8cp02858c	journal	January 2018
Size-dependent interface thermal conductance in black phosphorus/SiO ₂ heterojunctions Zhang, Liang; Ouyang, Gang Journal of Physics D: Applied Physics, Vol. 52, Issue 2 https://doi.org/10.1088/1361-6463/aae9bd	journal	November 2018

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Related Subjects

36 MATERIALS SCIENCE
Raman spectroscopy
black phosphorus
interfacial thermal conductance
thermal expansion