Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Low-temperature hydrocarbon production from oxygenated hydrocarbons

Patent ·
OSTI ID:1531496
;

Disclosed is a method of producing hydrocarbons from oxygenated hydrocarbon reactants, such as glycerol, glucose, or sorbitol. The method can take place in the vapor phase or in the condensed liquid phase (preferably in the condensed liquid phase). The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon having at least two carbon atoms, in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIIIB transitional metals, alloys thereof, and mixtures thereof. These metals are supported on supports that exhibit acidity or the reaction is conducted under liquid-phase conditions at acidic pHs. The disclosed method allows the production of hydrocarbon by the liquid-phase reaction of water with biomass-derived oxygenated compounds.

Research Organization:
Wisconsin Alumni Research Foundation, Madison, WI (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-84ER13183
Assignee:
Wisconsin Alumni Research Foundation (Madison, WI)
Patent Number(s):
6,953,873
Application Number:
10/435,208
OSTI ID:
1531496
Country of Publication:
United States
Language:
English

References (11)

Chemical Processing in High-Pressure Aqueous Environments. 6. Demonstration of Catalytic Gasification for Chemical Manufacturing Wastewater Cleanup in Industrial Plants journal March 1999
Acidity of Keggin-Type Heteropolycompounds Evaluated by Catalytic Probe Reactions, Sorption Microcalorimetry, and Density Functional Quantum Chemical Calculations
  • Bardin, Billy B.; Bordawekar, Shailendra V.; Neurock, Matthew
  • The Journal of Physical Chemistry B, Vol. 102, Issue 52, p. 10817-10825 https://doi.org/10.1021/jp982345y
journal December 1998
Gasification of Cellulose, Xylan, and Lignin Mixtures in Supercritical Water journal November 2001
Hydrogen Production from Cellulose in Hot Compressed Water Using Reduced Nickel Catalyst: Product Distribution at Different Reaction Temperatures. journal January 1998
Hydrogen Production from Wet Cellulose by Low Temperature Gasification Using a Reduced Nickel Catalyst journal October 1995
Selective Hydrogen Production from Cellulose at Low Temperature Catalyzed by Supported Group 10 Metal journal October 2000
Production of Hydrogen and Hydrocarbon from Cellulose and Water journal August 1981
Carbon-Halogen Bond Scission and Rearrangement of .beta.-Halohydrins on the Rh(111) Surface journal December 1994
Conversion of hydrocarbons and alcohols for fuel cells journal January 2001
Application of direct thermal liquefaction for the conversion of cellulosic biomass
  • Nelson, David A.; Molton, Peter M.; Russell, Janet A.
  • Industrial & Engineering Chemistry Product Research and Development, Vol. 23, Issue 3 https://doi.org/10.1021/i300015a029
journal September 1984
Catalytic steam reforming of biomass-derived oxygenates: acetic acid and hydroxyacetaldehyde journal August 1996

Similar Records

Low-temperature hydrogen production from oxygenated hydrocarbons
Patent · Mon Nov 16 23:00:00 EST 2009 · OSTI ID:1531612
Low-Temperature Catalytic Process To Produce Hydrocarbons From Sugars
Patent · Mon Nov 14 23:00:00 EST 2005 · OSTI ID:879874
Low-temperature hydrogen production from oxygenated hydrocarbons
Patent · Mon Mar 01 23:00:00 EST 2004 · OSTI ID:1531470

Related Subjects

08 HYDROGEN
09 BIOMASS FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY