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Low-Temperature Catalytic Process To Produce Hydrocarbons From Sugars

Patent ·
OSTI ID:879874

Disclosed is a method of producing hydrogen from oxygenated hydrocarbon reactants, such as methanol, glycerol, sugars (e.g. glucose and xylose), or sugar alcohols (e.g. sorbitol). The method takes place in the condensed liquid phase. The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIIIB transitional metals, alloys thereof, and mixtures thereof. The disclosed method can be run at lower temperatures than those used in the conventional steam reforming of alkanes.

Research Organization:
UNIVERSITY OF WISCONSIN
DOE Contract Number:
FG02-84ER13183
Assignee:
Wisconsin Alumni Research (Madison, WI)
Patent Number(s):
US 6,964,757
Application Number:
10/306258
OSTI ID:
879874
Country of Publication:
United States
Language:
English

References (8)

Hydrogen generation by steam reforming of methanol over copper-based catalysts for fuel cell applications journal September 2001
Catalytic steam reforming of biomass-derived oxygenates: acetic acid and hydroxyacetaldehyde journal August 1996
Hydrogen Production from Cellulose in Hot Compressed Water Using Reduced Nickel Catalyst: Product Distribution at Different Reaction Temperatures. journal January 1998
Production of Hydrogen and Hydrocarbon from Cellulose and Water journal August 1981
Hydrogen Production from Wet Cellulose by Low Temperature Gasification Using a Reduced Nickel Catalyst journal October 1995
Carbon-Halogen Bond Scission and Rearrangement of .beta.-Halohydrins on the Rh(111) Surface journal December 1994
Conversion of hydrocarbons and alcohols for fuel cells journal January 2001
Selective Hydrogen Production from Cellulose at Low Temperature Catalyzed by Supported Group 10 Metal journal October 2000

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