Two-Dimensional Holey Co3O4 Nanosheets for High-Rate Alkali-Ion Batteries: From Rational Synthesis to in Situ Probing
- Materials Science and Engineering Program and Department of Mechanical Engineering, The University of Texas at Austin, Austin, Texas 78712, United States; Department of Chemistry, Harbin Institute of Technology, Harbin, Heilongjiang 150001, People’s Republic of China
- Materials Science and Engineering Program and Department of Mechanical Engineering, The University of Texas at Austin, Austin, Texas 78712, United States
- Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439, United States; Mechanical and Industrial Engineering Department, University of Illinois at Chicago, Chicago, Illinois 60607, United States
- Department of Chemistry, Harbin Institute of Technology, Harbin, Heilongjiang 150001, People’s Republic of China
- Mechanical and Industrial Engineering Department, University of Illinois at Chicago, Chicago, Illinois 60607, United States
- Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439, United States
A general template-directed strategy is developed for the controlled synthesis of two-dimensional (2D) assembly of Co3O4 nanoparticles (ACN) with unique holey architecture and tunable hole sizes that enable greatly improved alkali-ion storage properties (demonstrated for both Li and Na ion storage). The as-synthesized holey ACN with 10 nm holes exhibit excellent reversible capacities of 1324 mAh/g at 0.4 A/g and 566 mAh/g at 0.1 A/g for Li and Na ion storage, respectively. The improved alkali-ion storage properties are attributed to the unique interconnected holey framework that enables efficient charge/mass transport as well as accommodates volume expansion. In situ TEM characterization is employed to depict the structural evolution and further understand the structural stability of 2D holey ACN during the sodiation process. The results show that 2D holey ACN maintained the holey morphology at different sodiation stages because Co3O4 are converted to extremely small interconnected Co nanoparticles and these Co nanoparticles could be well dispersed in a Na2O matrix. These extremely small Co nanoparticles are interconnected to provide good electron pathway. In addition, 2D holey Co3O4 exhibits small volume expansion (~6%) compared to the conventional Co3O4 particles. The 2D holey nanoarchitecture represents a promising structural platform to address the restacking and accommodate the volume expansion of 2D nanosheets for superior alkali-ion storage.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
- DOE Contract Number:
- AC02-06CH11357
- OSTI ID:
- 1530385
- Journal Information:
- Nano Letters, Vol. 17, Issue 6; ISSN 1530-6984
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
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