Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Probing the band alignment in rectifying SrIrO3/Nb:SrTiO3 heterostructures

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.5087956· OSTI ID:1528890
 [1];  [2];  [1];  [3];  [4]
  1. Stanford Univ., Stanford, CA (United States)
  2. Stanford Univ., Stanford, CA (United States); Univ. of Twente (The Netherlands)
  3. SLAC National Accelerator Lab., Menlo Park, CA (United States)
  4. Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
Here, we have examined the band alignment in SrIrO3/Nb:SrTiO3 (001) heterojunctions at room temperature using three independent techniques: current–voltage and capacitance–voltage measurements and internal photoemission spectroscopy. We find near-ideal rectifying behavior across the junction, which provides the opportunity to establish the band alignment via Schottky barrier height extractions in the metal-semiconductor junction approximation. The Schottky barrier height deduced from these measurements agrees well with each other within ~14%, with an average value of 1.44 ± 0.11 eV. These results provide a foundation for designing oxide heterostructures to harness the strong spin-orbit coupling and electrochemical properties of strontium iridate.
Research Organization:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-76SF00515
OSTI ID:
1528890
Alternate ID(s):
OSTI ID: 1505009
Journal Information:
Applied Physics Letters, Journal Name: Applied Physics Letters Journal Issue: 13 Vol. 114; ISSN 0003-6951
Publisher:
American Institute of Physics (AIP)Copyright Statement
Country of Publication:
United States
Language:
English

References (37)

Understanding and Controlling the Work Function of Perovskite Oxides Using Density Functional Theory journal May 2016
Recent advances in Schottky barrier concepts journal November 2001
Charge Transfer in Iridate-Manganite Superlattices journal March 2017
Emerging magnetism and anomalous Hall effect in iridate–manganite heterostructures journal September 2016
Spin injection and detection in lanthanum- and niobium-doped SrTiO3 using the Hanle technique journal July 2013
Resistive switching and its suppression in Pt/Nb:SrTiO3 junctions journal June 2014
Why some interfaces cannot be sharp journal January 2006
Ferroelectrically tunable magnetic skyrmions in ultrathin oxide heterostructures journal November 2018
Activation of ultrathin SrTiO 3 with subsurface SrRuO 3 for the oxygen evolution reaction journal January 2018
Schottky barrier heights of tantalum oxide, barium strontium titanate, lead titanate, and strontium bismuth tantalate journal February 1999
Bulk electronic structure of SrTiO3: Experiment and theory journal December 2001
Preparation of thermally stable TiO2-terminated SrTiO3(100) substrate surfaces journal July 2004
Characterization of the Schottky barrier in SrRuO3∕Nb:SrTiO3 junctions journal April 2007
Electrical transport across Au/Nb:SrTiO 3 Schottky interface with different Nb doping journal May 2012
The physics and chemistry of the Schottky barrier height journal January 2014
Metal insulator transitions in perovskite SrIrO 3 thin films journal December 2014
Thermodynamic guiding principles in selective synthesis of strontium iridate Ruddlesden-Popper epitaxial films journal March 2016
Epitaxial growth and thermodynamic stability of SrIrO 3 /SrTiO 3 heterostructures journal July 2016
Atomically engineered epitaxial anatase TiO 2 metal-semiconductor field-effect transistors journal March 2018
The capacitance of degenerate‐semiconductor Schottky barriers at low temperatures journal March 1980
The Analysis of Photoelectric Sensitivity Curves for Clean Metals at Various Temperatures journal July 1931
SrTi O 3 : An intrinsic quantum paraelectric below 4 K journal April 1979
Electron Tunneling and Band Structure of SrTi O 3 and KTa O 3 journal October 1970
Electron doping of cuprates via interfaces with manganites journal August 2007
Electronic transport in doped SrTiO 3 : Conduction mechanisms and potential applications journal April 2010
Interface band profiles of Mott-insulator / Nb : SrTiO 3 heterojunctions as investigated by optical spectroscopy journal November 2010
Balanced electron-hole transport in spin-orbit semimetal SrIrO 3 heterostructures journal February 2018
Interplay of Spin-Orbit Interactions, Dimensionality, and Octahedral Rotations in Semimetallic SrIrO 3 journal January 2015
Engineering a Spin-Orbital Magnetic Insulator by Tailoring Superlattices journal June 2015
Spin-Orbit Semimetal SrIrO 3 in the Two-Dimensional Limit journal December 2017
Dimensionality-Driven Metal-Insulator Transition in Spin-Orbit-Coupled SrIrO 3 journal December 2017
Fundamental Transition in the Electronic Nature of Solids journal June 1969
Relativistic G W +BSE study of the optical properties of Ruddlesden-Popper iridates journal July 2018
Band Alignment and Charge Transfer in Complex Oxide Interfaces journal March 2017
Interface-driven topological Hall effect in SrRuO 3 -SrIrO 3 bilayer journal July 2016
A highly active and stable IrO x /SrIrO 3 catalyst for the oxygen evolution reaction journal September 2016
Compressive strain-induced metal–insulator transition in orthorhombic SrIrO 3 thin films journal October 2014

Similar Records

Inhomogeneous barrier heights at dipole-controlled SrRuO3/Nb:SrTiO3 Schottky junctions
Journal Article · Tue Nov 27 19:00:00 EST 2018 · Applied Physics Letters · OSTI ID:1490455

Conduction band offset at the InN/GaN heterojunction
Journal Article · Sun Dec 02 23:00:00 EST 2007 · Applied Physics Letters · OSTI ID:21016198

A conductive scanning study of La{sub 0.67}Sr{sub 0.33}MnO{sub 3}/Nb:SrTiO{sub 3} hetero-junction
Journal Article · Sun Jan 31 23:00:00 EST 2016 · Applied Physics Letters · OSTI ID:22489396