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Ionic liquids as oil additives for lubricating oxygen-diffusion case-hardened titanium

Journal Article · · Tribology International
 [1];  [2];  [3];  [4];  [3];  [3];  [3]
  1. Wuhan Research Institute of Materials Protection, Hubei (China); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  2. Chinese Academy of Sciences, Gansu (China); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  4. Wuhan Research Institute of Materials Protection, Hubei (China)

This study attempts to use ionic liquids (ILs) as oil additives to lubricate oxygen-diffusion (OD) case-hardened titanium for improved friction and wear behavior. Four oil-soluble ILs were used as additives in a base oil for boundary lubrication of an OD-treated Ti-6Al-4V surface sliding against a bearing steel ball. The ILs improved the friction behavior to various extents and the two phosphate ILs clearly outperformed the conventional ZDDP. Unlike ZDDP that adversely caused a higher material loss, ILs exhibited excellent wear protection suggesting good material-chemical compatibility. Particularly, the carboxylate IL protected the OD-Ti surface from any measurable wear. As a result, the morphology and chemical composition of the worn surfaces and tribofilms were examined to gain insights of the anti-wear mechanism.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1523744
Alternate ID(s):
OSTI ID: 1513066
Journal Information:
Tribology International, Journal Name: Tribology International Journal Issue: C Vol. 136; ISSN 0301-679X
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

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