Sacrificial template synthesis of hollow C@MoS2@PPy nanocomposites as anodes for enhanced sodium storage performance

Wang, Guangming; Bi, Xuanxuan; Yue, Hailong; Jin, Rencheng; Wang, Qingyao; Gao, Shanmin; Lu, Jun

doi:10.1016/j.nanoen.2019.03.065

Sacrificial template synthesis of hollow C@MoS₂@PPy nanocomposites as anodes for enhanced sodium storage performance

Journal Article · Sat Mar 23 00:00:00 EDT 2019 · Nano Energy

DOI:https://doi.org/10.1016/j.nanoen.2019.03.065· OSTI ID:1523650

Wang, Guangming ^[1]; Bi, Xuanxuan ^[2]; Yue, Hailong ^[1]; Jin, Rencheng ^[1]; Wang, Qingyao ^[1]; Gao, Shanmin ^[1]; Lu, Jun ^[2]

Ludong Univ., Yantai (China)
Argonne National Lab. (ANL), Argonne, IL (United States)

Molybdenum disulfide (MoS₂) has become a potential anode material for sodium-ion batteries (SIBs) by showing decent cell performance but it suffers poor electronic conductivity and large volume expansion during sodiation. Here we design a nanocomposite with hollow nitrogen doped carbon and polypyrrole modified MoS₂ for improving the performance for SIBs. The designed nanocomposite shows a much-improved electronic conductivity and the design of the architecture provides sufficient channels for mass transport and accommodates large volume change. This C@MoS₂@PPy anode delivers a high specific capacity of 713 mAh g^-1 at 0.1 A g^-1 for 100 cycles, and an excellent rate capacity of 294 mAh g^-1 at 5 A g^-1 for 500 cycles. This specific architecture of C@MoS2@PPy could guide the future design of the electrode material in SIBs and its superior electrochemical performance indicates the great potential application for SIBs.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); USDOE Office of Energy Efficiency and Renewable Energy (EERE) - Office of Vehicle Technologies (VTO)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1523650

Journal Information:: Nano Energy, Journal Name: Nano Energy Journal Issue: C Vol. 60; ISSN 2211-2855

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

25 ENERGY STORAGE
anode
molybdenum disulfide
polymerization
polypyrrole
sodium ion batteries