(CrMnCoNiZn)3O4@PPy core-shell nanocomposite with excellent electrochemical performance as lithium-ion battery anode

Jin, Changqing; Wang, Yulong; Wei, Yongxing; Nan, Ruihua; Jian, Zengyun; Yang, Zhong; Ding, Qingping

doi:10.1016/j.jpowsour.2024.234926

(CrMnCoNiZn)₃O₄@PPy core-shell nanocomposite with excellent electrochemical performance as lithium-ion battery anode

Journal Article · Wed Jun 19 00:00:00 EDT 2024 · Journal of Power Sources

DOI:https://doi.org/10.1016/j.jpowsour.2024.234926· OSTI ID:2382778

^[1]; Wang, Yulong ^[1]; Wei, Yongxing ^[1]; Nan, Ruihua ^[1]; Jian, Zengyun ^[1]; Yang, Zhong ^[1]; ^[2]

Xi'an Technological University (China)
Ames Lab., and Iowa State Univ., Ames, IA (United States)

High entropy oxides (HEOs) have an excellent potential for use as electrode materials in lithium-ion batteries (LIBs) due to their high theoretical specific capacity. In this work, spinel-structured (CrMnCoNiZn)₃O₄ HEO nanoparticles with five elements in equal molar ratio is first generated by solution combustion method. (CrMnCoNiZn)₃O₄@polypyrrole (PPy) nanocomposites are prepared by in-situ polymerization method. As an anode for lithium-ion batteries, the electrochemical performance of the (CrMnCoNiZn)₃O₄@PPy composite outperforms that of (CrMnCoNiZn)₃O₄ nanoparticles. The capacity is 802 mAh/g after 100 cycles at a current density of 100 mA/g, 416 mAh/g after 1000 cycles at a high current density of 1 A/g, and 360 mAh/g rate capacity at 2 A/g. The excellent electrochemical performance of the composites is mainly due to the fact that the conductive and flexible PPy is encapsulated on the high-entropy oxides, which can alleviate the volume change triggered by extraction-insertion of lithium ions process, as well as enhance the electrical conductivity and reduce the occurrence of some side reactions. Finally, this method of compositing materials can also be used in other HEOs and conductive polymers, providing a new idea to enhance the electrochemical properties of HEOs.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 2382778

Alternate ID(s):: OSTI ID: 2375590

Report Number(s):: IS-J--11,369

Journal Information:: Journal of Power Sources, Journal Name: Journal of Power Sources Vol. 613; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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