Preparation and characterization of nanocellulose–polyvinyl alcohol multilayer film by layer-by-layer method

Hou, Qiupeng; Wang, Xiwen; Ragauskas, Arthur J.

doi:10.1007/s10570-019-02413-0

Preparation and characterization of nanocellulose–polyvinyl alcohol multilayer film by layer-by-layer method

Journal Article · Mon Apr 15 00:00:00 EDT 2019 · Cellulose

DOI:https://doi.org/10.1007/s10570-019-02413-0· OSTI ID:1515648

Hou, Qiupeng ^[1]; ^[1]; ^[2]

South China Univ. of Technology, Guangzhou (China)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Nanofibrillated cellulose (NFC) and polyvinyl alcohol (PVA) were alternately deposited on a NFC/polyethylene terephthalate (PET) substrate by the use of layer-by-layer (LBL) self-assembly technique. The results reveal that by adding a single PVA layer on the NFC/PET substrate, the surface exhibited more hydrophilic properties showing reduced contact area and excellent surface wettability. Moreover, the common FT-IR band for a carboxylic group was observed at 1535 cm^–1, which indicates that NFC treated by TEMPO oxidation was attached to the surface layer of cellulose mats. Moreover, the 10 layer LBL assembly of the NFC and PVA were spread out into a reticulate structure during the drying process, resulting in a much rougher surface than that of 1 LBL assemble on the NFC/PET film. Lastly, the thermal stability of the multilayer films had been significantly improved.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; National Natural Science Foundation of China

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1515648

Journal Information:: Cellulose, Journal Name: Cellulose Journal Issue: 8 Vol. 26; ISSN 0969-0239

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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42 ENGINEERING
Layer-by-layer self-assembly (LBL)
Nanofibrillated cellulose (NFC)
PVA
Surface Multilayer film

Preparation and characterization of nanocellulose–polyvinyl alcohol multilayer film by layer-by-layer method

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