Capable Cross-links: Polymersomes Reinforced with Catalytically Active Metal–Ligand Bonds

Henderson, Ian M.; Quintana, Hope A.; Martinez, Julio A.; Paxton, Walter F.

doi:10.1021/acs.chemmater.5b01677

Capable Cross-links: Polymersomes Reinforced with Catalytically Active Metal–Ligand Bonds

Journal Article · Wed Jun 17 00:00:00 EDT 2015 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.5b01677· OSTI ID:1512875

Henderson, Ian M. ^[1]; Quintana, Hope A. ^[2]; Martinez, Julio A. ^[2]; Paxton, Walter F. ^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Center for Integrated Nanotechnologies
New Mexico State Univ., Las Cruces, NM (United States). Dept. of Chemical & Materials Engineering

Polymersomes, hollow spherical nano-to-microscale polymer assemblies, have increasingly become important constructs in the development of biomimetic materials that expand the library of functional and robust analogs to lipid-based vesicles. As compared to liposomes, polymersomes possess superior physical properties and the nearly unlimited potential for synthetic fine-tuning. Here in this paper, we improve on the physical properties of these polymer vesicles by introducing platinum-based metal–ligand cross-links into the hydrophobic core, which gave the vesicles demonstrated resistance to destabilization by surfactants over un-cross-linked polymersomes. The formation of cross-links was capable of being selectively reversed by the addition of phosphines. In addition, the Pt(0) cross-links retained their catalytic activity for the hydrosilylation of alkenes.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1512875

Report Number(s):: SAND--2015-2925J; 662091

Journal Information:: Chemistry of Materials, Journal Name: Chemistry of Materials Journal Issue: 13 Vol. 27; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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