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Synthetic Routes for a 2D Semiconductive Copper Hexahydroxybenzene Metal–Organic Framework

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.8b06666· OSTI ID:1507097
 [1];  [1];  [2];  [1];  [3];  [1];  [1];  [2];  [1]
  1. Stanford Univ., Stanford, CA (United States)
  2. Stockholm Univ., Stockholm (Sweden)
  3. Argonne National Lab. (ANL), Lemont, IL (United States)
+ Show Author Affiliations
Conductive metal-organic frameworks (c-MOFs) have demonstrated outstanding performance in energy storage and electrocatalysis. Varying the bridging metal species and the coordinating atom are versatile approaches to tune their intrinsic electronic properties in c-MOFs. Herein we report the first synthesis of the oxygen analog of M3(C6X6)2 (X = NH, S) family using Cu(II) and hexahydroxybenzene (HHB), namely Cu-HHB [Cu3(C6O6)2], through a kinetically controlled approach with a competing coordination reagent. We also successfully demonstrate an economical synthetic approach using tetrahydroxyquinone as the starting material. Cu-HHB was found to have a partially eclipsed packing between adjacent 2D layers and a bandgap of approximately 1 eV. The addition of Cu-HHB to the family of synthetically realized M3(C6X6)2 c-MOFs will allow greater understanding of the influence of the organic linkers and metals, and further broadens the range of applications for these materials.
Research Organization:
Argonne National Lab. (ANL), Lemont, IL (United States)
Sponsoring Organization:
Camille and Henry Dreyfus Foundation; Knut and Alice Wallenberg Foundation; National Research Foundation (NRF) of Korea; National Science Foundation (NSF); Swedish Research Council; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1507097
Journal Information:
Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 44 Vol. 140; ISSN 0002-7863
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English

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Cited By (20)

Synthetic Route to a Triphenylenehexaselenol-Based Metal Organic Framework with Semi-conductive and Glassy Magnetic Properties journal January 2020
[Cu 3 (C 6 Se 6 )] n : The First Highly Conductive 2D π–d Conjugated Coordination Polymer Based on Benzenehexaselenolate journal March 2019
A Dual‐Ligand Porous Coordination Polymer Chemiresistor with Modulated Conductivity and Porosity journal November 2019
On‐surface Synthesis of a Semiconducting 2D Metal–Organic Framework Cu 3 (C 6 O 6 ) Exhibiting Dispersive Electronic Bands journal January 2020
A Redox‐Active 2D Metal–Organic Framework for Efficient Lithium Storage with Extraordinary High Capacity journal January 2020
Titelbild: A Redox‐Active 2D Metal–Organic Framework for Efficient Lithium Storage with Extraordinary High Capacity (Angew. Chem. 13/2020) journal January 2020
A Dual‐Ligand Porous Coordination Polymer Chemiresistor with Modulated Conductivity and Porosity journal January 2020
On‐surface Synthesis of a Semiconducting 2D Metal–Organic Framework Cu 3 (C 6 O 6 ) Exhibiting Dispersive Electronic Bands journal February 2020
A Redox‐Active 2D Metal–Organic Framework for Efficient Lithium Storage with Extraordinary High Capacity journal March 2020
Cover Picture: A Redox‐Active 2D Metal–Organic Framework for Efficient Lithium Storage with Extraordinary High Capacity (Angew. Chem. Int. Ed. 13/2020) journal March 2020
A Highly Conductive MOF of Graphene Analogue Ni 3 (HITP) 2 as a Sulfur Host for High‐Performance Lithium–Sulfur Batteries journal September 2019
Molecular understanding of charge storage and charging dynamics in supercapacitors with MOF electrodes and ionic liquid electrolytes journal February 2020
Synthesis of coordination polymer thin films with conductance-response to mechanical stimulation journal January 2019
Two unique copper cluster-based metal–organic frameworks with high performance for CO 2 adsorption and separation journal January 2019
Unique Schrödinger semimetal state in ternary Be 2 P 3 N honeycomb lattice journal January 2019
Two-dimensional magnetic materials of cobalt( ii ) triangular lattices constructed by a mixed benzimidazole–dicarboxylate strategy journal January 2019
Two-dimensional metal–organic frameworks and their derivatives for electrochemical energy storage and electrocatalysis journal January 2020
Solid–solid interface growth of conductive metal–organic framework nanowire arrays and their supercapacitor application journal January 2020
Ultrathin two-dimensional π–d conjugated coordination polymer Co 3 (hexaaminobenzene) 2 nanosheets for highly efficient oxygen evolution journal January 2020
2D coordination polymers: Design guidelines and materials perspective journal December 2019

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY