Linker Redox Mediated Control of Morphology and Properties in Semiconducting Iron‐Semiquinoid Coordination Polymers**

Wang, Lei; Papoular, Robert J.; Horwitz, Noah E.; Xie, Jiaze; Sarkar, Arup; Campisi, Dario; Zhao, Norman; Cheng, Baorui; Grocke, Garrett L.; Ma, Tengzhou; Filatov, Alexander S.; Gagliardi, Laura; Anderson, John S.

doi:10.1002/anie.202207834

Linker Redox Mediated Control of Morphology and Properties in Semiconducting Iron‐Semiquinoid Coordination Polymers**

Journal Article · Fri Oct 07 00:00:00 EDT 2022 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.202207834· OSTI ID:1891568

^[1]; ^[2]; Horwitz, Noah E. ^[1]; ^[1]; ^[1]; ^[1]; ^[1]; Cheng, Baorui ^[1]; ^[3]; ^[3]; ^[1]; ^[4]; ^[1]

Department of Chemistry University of Chicago 5735 S Ellis Ave Chicago IL 60637 USA
IRAMIS Leon Brillouin Laboratory CEA-Saclay 91191 Gif-sur-Yvette (France)
Pritzker School of Molecular Engineering University of Chicago 5735 S Ellis Ave Chicago IL 60637 USA
Department of Chemistry, Pritzker School of Molecular Engineering, James Franck Institute and Chicago Center for Theoretical Chemistry University of Chicago 5735 S Ellis Ave Chicago IL 60637 USA

Abstract

The emergence of conductive 2D and less commonly 3D coordination polymers (CPs) and metal–organic frameworks (MOFs) promises novel applications in many fields. However, the synthetic parameters for these electronically complex materials are not thoroughly understood. Here we report a new 3D semiconducting CP Fe ₅ (C ₆ O ₆ ) ₃ , which is a fusion of 2D Fe‐semiquinoid materials and 3D cubic Fe _x (C ₆ O ₆ ) _y materials, by using a different initial redox‐state of the C ₆ O ₆ linker. The material displays high electrical conductivity (0.02 S cm ⁻¹ ), broad electronic transitions, promising thermoelectric behavior ( S ² σ=7.0×10 ⁻⁹ W m ⁻¹ K ⁻² ), and strong antiferromagnetic interactions at room temperature. This material illustrates how controlling the oxidation states of redox‐active components in conducting CPs/MOFs can be a “pre‐synthetic” strategy to carefully tune material topologies and properties in contrast to more commonly encountered post‐synthetic modifications.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-06CH11357; SC0012702

OSTI ID:: 1891568

Alternate ID(s):: OSTI ID: 1896334
OSTI ID: 1901257

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 45 Vol. 61; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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