Role of sterics in phosphine-ligated gold clusters

Parrish, Katherine A.; King, Mary; Ligare, Marshall R.; Johnson, Grant E.; Hernández, Heriberto

doi:10.1039/C8CP04961K

Role of sterics in phosphine-ligated gold clusters

Journal Article · Mon Dec 31 23:00:00 EST 2018 · Physical Chemistry Chemical Physics. PCCP (Print)

DOI:https://doi.org/10.1039/C8CP04961K· OSTI ID:1506986

Parrish, Katherine A. ^[1]; King, Mary ^[2]; ^[3]; ^[3]; ^[1]

Department of Chemistry; Grinnell College; Grinnell; USA
Department of Chemistry; University of Texas at Austin; Austin; USA
Physical Sciences Division; Pacific Northwest National Laboratory; Richland; USA

This study examined the solution-phase exchange reactions of triphenylphosphine (PPh₃) ligands on Au₈L₇²⁺(L = PPh₃) gold clusters with three different tolyl ligands using electrospray ionization mass spectrometry to provide insight into how steric differences in the phosphines influence the extent of ligand exchange and the stability of the resulting mixed-phosphine clusters.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Workforce Development for Teachers and Scientists (WDTS) (SC-27); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1506986

Report Number(s):: PNNL-SA-134177

Journal Information:: Physical Chemistry Chemical Physics. PCCP (Print), Journal Name: Physical Chemistry Chemical Physics. PCCP (Print) Journal Issue: 4 Vol. 21; ISSN 1463-9076; ISSN PPCPFQ

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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