Role of sterics in phosphine-ligated gold clusters
Journal Article
·
· Physical Chemistry Chemical Physics. PCCP
- Department of Chemistry, Grinnell College, Grinnell, USA
- Department of Chemistry, University of Texas at Austin, Austin, USA
- Physical Sciences Division, Pacific Northwest National Laboratory, Richland, USA
This study examined the solution-phase exchange reactions of triphenylphosphine (PPh 3 ) ligands on Au 8 L 7 2+ (L = PPh 3 ) gold clusters with three different tolyl ligands using electrospray ionization mass spectrometry to provide insight into how steric differences in the phosphines influence the extent of ligand exchange and the stability of the resulting mixed-phosphine clusters.
- Sponsoring Organization:
- USDOE Office of Science (SC), Office of Workforce Development for Teachers & Scientists (WDTS); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI ID:
- 1474188
- Journal Information:
- Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Vol. 21 Journal Issue: 4; ISSN 1463-9076
- Publisher:
- Royal Society of Chemistry (RSC)Copyright Statement
- Country of Publication:
- United Kingdom
- Language:
- English
Cited by: 15 works
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