Polaronic effect in the x-ray absorption spectra of La1-xCaxMnO3 manganites

Huang, Shi Wen; Liu, Y. T.; Lee, J. M.; Chen, J. M.; Lee, J. F.; Schoenlein, R. W.; Chuang, Y. -D.; Lin, J. -Y

doi:10.1088/1361-648x/ab05a2

Polaronic effect in the x-ray absorption spectra of La_1-xCa_xMnO₃ manganites

Journal Article · Fri Mar 08 00:00:00 EST 2019 · Journal of Physics. Condensed Matter

DOI:https://doi.org/10.1088/1361-648x/ab05a2· OSTI ID:1505421

^[1]; Liu, Y. T. ^[2]; Lee, J. M. ^[3]; Chen, J. M. ^[4]; Lee, J. F. ^[4]; Schoenlein, R. W. ^[5]; Chuang, Y. -D. ^[6]; ^[2]

Lund Univ., Lund (Sweden); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
National Chiao Tung Univ., Hsinchu (Taiwan)
Lund Univ., Lund (Sweden); National Synchrotron Radiation Research Center, Hsinchu (Taiwan)
National Synchrotron Radiation Research Center, Hsinchu (Taiwan)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

X-ray absorption spectroscopy (XAS) is performed to study changes in the electronic structures of colossal magnetoresistance (CMR) and charged ordered (CO) La_1–xCa_xMnO₃ manganites with respect to temperature. The pre-edge features in O and Mn K-edge XAS spectra, which are highly sensitive to the local distortion of MnO₆ octahedral, exhibit contrasting temperature dependence between CMR and CO samples. The seemingly counter-intuitive XAS temperature dependence can be reconciled in the context of polarons. Furthermore these results help identify the most relevant orbital states associated with polarons and highlight the crucial role played by polarons in understanding the electronic structures of manganites.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-05CH11231; AC02-76SF00515

OSTI ID:: 1505421

Alternate ID(s):: OSTI ID: 1581602
OSTI ID: 23008970

Journal Information:: Journal of Physics. Condensed Matter, Journal Name: Journal of Physics. Condensed Matter Journal Issue: 19 Vol. 31; ISSN 0953-8984

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

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Non-Ohmic conduction in exfoliated La _0.7 Ca _0.3 MnO ₃ thin films Park, Jungsik; Shin, Jae Hoon; Song, Kyung Applied Physics Letters, Vol. 116, Issue 2 https://doi.org/10.1063/1.5127355	journal	January 2020

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Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
colossal magnetoresistance
polaron
x-ray absorption