Synthesis, characterization, and luminescent properties of two new Zr(IV) metal–organic frameworks based on anthracene derivatives

Rowe, Jennifer M.; Soderstrom, Erin M.; Zhu, Jie; Usov, Pavel M.; Morris, Amanda J.

doi:10.1139/cjc-2017-0445

Synthesis, characterization, and luminescent properties of two new Zr(IV) metal–organic frameworks based on anthracene derivatives

Journal Article · Thu Nov 08 00:00:00 EST 2018 · Canadian Journal of Chemistry

DOI:https://doi.org/10.1139/cjc-2017-0445· OSTI ID:1504920

Rowe, Jennifer M. ^[1]; Soderstrom, Erin M. ^[2]; Zhu, Jie ^[2]; Usov, Pavel M. ^[2]; Morris, Amanda J. ^[2]

Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Department of Chemistry and Macromolecules Innovation Institute, Virginia Tech, Blacksburg, VA 24061 (United States)
Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)

Metal–organic frameworks (MOFs) are crystalline materials constructed from metal ions or clusters, connected by multidentate organic ligands. Herein, we describe the synthesis and photophysical properties of two Zr-based, anthracene-containing MOFs, assembled from 2,6-anthracenedicarboxylic acid (2,6-ADCA and 2,6-MOF) and 1,4-anthracenedicarboxylic acid (1,4-ADCA and 1,4-MOF). The 2,6-ADCA analogue formed a highly crystalline octahedral structure that is isostructural with the well-known UiO-67 frameworks. Incorporation of the 1,4-ADCA ligand, on the other hand, resulted in large rod-shaped crystals. Both MOFs exhibit linker-based luminescence. The excited-state properties of the 2,6-MOF and 1,4-MOF were examined using stead-state diffuse reflectance and emission spectroscopies and time-correlated single photon counting (TCSPC) spectroscopy. The photophysical properties of the MOFs are compared with those of the corresponding ligand in solution.

View Accepted Manuscript (DOE)

Research Organization:: Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012446

OSTI ID:: 1504920

Journal Information:: Canadian Journal of Chemistry, Journal Name: Canadian Journal of Chemistry Journal Issue: 9 Vol. 96; ISSN 0008-4042

Publisher:: NRC Research PressCopyright Statement

Country of Publication:: United States

Language:: English

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Synthesis, characterization, and luminescent properties of two new Zr(IV) metal–organic frameworks based on anthracene derivatives

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