Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks

Rowe, Jennifer M.; Zhu, Jie; Soderstrom, Erin M.; Xu, Wenqian; Yakovenko, Andrey; Morris, Amanda J.

doi:10.1039/c8cc01893f

Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks

Journal Article · Tue Jun 19 00:00:00 EDT 2018 · ChemComm

DOI:https://doi.org/10.1039/c8cc01893f· OSTI ID:1473675

Rowe, Jennifer M. ^[1]; Zhu, Jie ^[1]; Soderstrom, Erin M. ^[1]; ^[2]; Yakovenko, Andrey ^[2]; ^[1]

Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States). Dept. of Chemistry and Macromolecules Innovation Inst.
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS), X-ray Science Division

Sensitized upconversion is explored in three metal–organic frameworks (MOFs) constructed from the anthracene dicarboxylate (ADC) derivatives and zirconium nodes, 9,10-ADC (9,10-MOF), 2,6-ADC (2,6-MOF) and 1,4-ADC (1,4-MOF). Selective excitation of surface-bound Pd(II) mesoporphyrin IX (PdMP) gives rise to delayed fluorescence (τ = 370 ± 30 ns) from anthracene in the 9,10-MOF. The overall upconversion efficiency of the Pd@9,10-MOF is 0.46 ± 0.05% with a threshold intensity of 104 ± 26 mW cm^-2.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-06CH11357; SC0012446

OSTI ID:: 1473675

Alternate ID(s):: OSTI ID: 1457465

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 56 Vol. 54; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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