Spin-optoelectronic devices based on hybrid organic-inorganic trihalide perovskites

Wang, Jingying; Zhang, Chuang; Liu, Haoliang; McLaughlin, Ryan; Zhai, Yaxin; Vardeny, Shai R.; Liu, Xiaojie; McGill, Stephen; Semenov, Dmitry; Guo, Hangwen; Tsuchikawa, Ryuichi; Deshpande, Vikram V.; Sun, Dali; Vardeny, Z. Valy

doi:10.1038/s41467-018-07952-x

Spin-optoelectronic devices based on hybrid organic-inorganic trihalide perovskites

Journal Article · Thu Jan 10 00:00:00 EST 2019 · Nature Communications

DOI:https://doi.org/10.1038/s41467-018-07952-x· OSTI ID:1494294

Wang, Jingying ^[1]; Zhang, Chuang ^[2]; ^[2]; McLaughlin, Ryan ^[2]; Zhai, Yaxin ^[2]; Vardeny, Shai R. ^[3]; Liu, Xiaojie ^[2]; McGill, Stephen ^[4]; Semenov, Dmitry ^[4]; Guo, Hangwen ^[5]; Tsuchikawa, Ryuichi ^[2]; Deshpande, Vikram V. ^[2]; Sun, Dali ^[6]; Vardeny, Z. Valy ^[2]

Univ. of Utah, Salt Lake City, UT (United States). Dept. of Physics & Astronomy; University of Utah
Univ. of Utah, Salt Lake City, UT (United States). Dept. of Physics & Astronomy
Univ. of Arizona, Tucson, AZ (United States). College of Optical Sciences
National High Magnetic Field Lab., Tallahassee, FL (United States)
Louisiana State Univ., Baton Rouge, LA (United States). Dept. of Physics & Astronomy
Univ. of Utah, Salt Lake City, UT (United States). Dept. of Physics & Astronomy; North Carolina State Univ., Raleigh, NC (United States). Dept. of Physics

Recently the hybrid organic-inorganic trihalide perovskites have shown remarkable performance as active layers in photovoltaic and other optoelectronic devices. However, their spin characteristic properties have not been fully studied, although due to the relatively large spin-orbit coupling these materials may show great promise for spintronic applications. Here we demonstrate spin-polarized carrier injection into methylammonium lead bromide films from metallic ferromagnetic electrodes in two spintronic-based devices: a ‘spin light emitting diode’ that results in circularly polarized electroluminescence emission; and a ‘vertical spin valve’ that shows giant magnetoresistance. In addition, we also apply a magnetic field perpendicular to the injected spins orientation for measuring the ‘Hanle effect’, from which we obtain a relatively long spin lifetime for the electrically injected carriers. Our measurements initiate the field of hybrid perovskites spin-related optoelectronic applications.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Hybrid Organic-Inorganic Semiconductors for Energy (CHOISE); Louisiana State Univ., Baton Rouge, LA (United States); National High Magnetic Field Lab., Tallahassee, FL (United States); Univ. of Utah, Salt Lake City, UT (United States)

Sponsoring Organization:: National Science Foundation (NSF) (United States); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0002136; SC0014579

OSTI ID:: 1494294

Journal Information:: Nature Communications, Journal Name: Nature Communications Vol. 10; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Spintronics of Hybrid Organic–Inorganic Perovskites: Miraculous Basis of Integrated Optoelectronic Devices Liao, Kun; Hu, Xiaoyong; Cheng, Yinke Advanced Optical Materials, Vol. 7, Issue 15 https://doi.org/10.1002/adom.201900350	journal	June 2019
Surface Chlorination of ZnO for Perovskite Solar Cells with Enhanced Efficiency and Stability Zhang, Dezhong; Zhang, Xindong; Bai, Sai Solar RRL, Vol. 3, Issue 8 https://doi.org/10.1002/solr.201900154	journal	May 2019
Circular photogalvanic spectroscopy of Rashba splitting in 2D hybrid organic–inorganic perovskite multiple quantum wells Liu, Xiaojie; Chanana, Ashish; Huynh, Uyen Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-019-14073-6	journal	January 2020
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Observation of long spin lifetime in MAPbBr ₃ single crystals at room temperature Yang, Shijia; Vetter, Eric; Wang, Tonghui Journal of Physics: Materials, Vol. 3, Issue 1 https://doi.org/10.1088/2515-7639/ab69b0	journal	January 2020

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