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Metal organic frameworks comprising a plurality of SBUS with different metal ions and/or a plurality of organic linking ligands with different functional groups

Patent ·
OSTI ID:1491835
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The disclosure provides for metal organic frameworks (MOFs) which comprise a plurality of SBUs comprising different metals or metal ions and/or a plurality of organic linking moieties comprising different functional groups.

Research Organization:
The Regents of the University of California, Oakland, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AR0000185
Assignee:
The Regents of the University of California (Oakland, CA)
Patent Number(s):
10,087,205
Application Number:
15/128,225
OSTI ID:
1491835
Country of Publication:
United States
Language:
English

References (263)

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Hydrothermal syntheses and structures of three novel coordination polymers assembled from 1,2,3-triazolate ligands journal January 2009
The pervasive chemistry of metal–organic frameworks journal January 2009
Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide journal January 2009
Metal–organic frameworks with designed chiral recognition sites journal January 2010
The remarkable catalytic activity of the saturated metal organic framework V-MIL-47 in the cyclohexene oxidation journal January 2010
Azulene based metal–organic frameworks for strong adsorption of H2 journal January 2010
Isoreticular synthesis and modification of frameworks with the UiO-66 topology journal January 2010
Mixed-component metal–organic frameworks (MC-MOFs): enhancing functionality through solid solution formation and surface modifications journal January 2011
Post-synthetic modification of the metal–organic framework compound UiO-66 journal January 2010
Asymmetric catalytic reactions by NbO-type chiral metal–organic frameworks journal January 2011
A zinc(ii) metal–organic framework based on triazole and dicarboxylate ligands for selective adsorption of hexane isomers journal January 2011
Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal–linker complexes journal January 2011
Metal–organic frameworks as heterogeneous catalysts for oxidation reactions journal January 2011
CH4 storage and CO2 capture in highly porous zirconium oxide based metal–organic frameworks journal January 2012
From MOFs to zeolites: zirconium sites for epoxide rearrangement journal January 2013
Highly porous and stable metal–organic frameworks for uranium extraction journal January 2013
An Efficient High Yielding Approach for the Homocoupling of Aryl Boronic Acids journal January 2002
Two Novel Triazole-Based Metal - Organic Frameworks Consolidated by a Flexible Dicarboxylate Co-ligand: Hydrothermal Synthesis, Crystal Structure, and Luminescence Properties journal January 2008
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks journal June 2006
Metal-organic frameworks with high capacity and selectivity for harmful gases journal August 2008
Geometric requirements and examples of important structures in the assembly of square building blocks journal April 2002
Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites journal November 2009
Positronium formation in porous materials for antihydrogen production journal April 2010
Three-periodic nets and tilings: regular and quasiregular nets journal December 2002
Three-periodic nets and tilings: semiregular nets journal October 2003
Three-periodic nets and tilings: edge-transitive binodal structures journal August 2006
Crystallography of metal–organic frameworks journal October 2014
Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores journal February 2001
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage journal January 2002
Hydrogen Storage in Microporous Metal-Organic Frameworks journal May 2003
Gas Adsorption Sites in a Large-Pore Metal-Organic Framework journal August 2005
Porous, Crystalline, Covalent Organic Frameworks journal November 2005
Designed Synthesis of 3D Covalent Organic Frameworks journal April 2007
High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO2 Capture journal February 2008
Docking in Metal-Organic Frameworks journal August 2009
Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks journal February 2010
Ultrahigh Porosity in Metal-Organic Frameworks journal July 2010
Large-Pore Apertures in a Series of Metal-Organic Frameworks journal May 2012
Mapping of Functional Groups in Metal-Organic Frameworks journal July 2013
Supertetrahedral Sulfide Crystals with Giant Cavities and Channels journal February 1999
Metal-organic frameworks—New materials for hydrogen storage journal April 2007
Interlacing molecular threads on transition metals journal January 1990
Open-Framework Solids with Diamond-Like Structures Prepared from Clusters and Metal-Organic Building Blocks journal January 1994
Synthesis and Structure of a Metal-Organic Solid Having the Cadmium(II) Sulfate Net journal January 1996
Reticular Chemistry and Metal-Organic Frameworks for Clean Energy journal September 2009
Rotaxanes and pseudorotaxanes with threads containing viologen units journal November 2012
Donor-acceptor rotaxanes with tetracationic cyclophane ring journal September 2012

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY