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Title: Metal organic frameworks comprising a plurality of SBUS with different metal ions and/or a plurality of organic linking ligands with different functional groups

Patent ·
OSTI ID:1491835

The disclosure provides for metal organic frameworks (MOFs) which comprise a plurality of SBUs comprising different metals or metal ions and/or a plurality of organic linking moieties comprising different functional groups.

Research Organization:
Univ. of California, Oakland, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
DE-AR0000185
Assignee:
The Regents of the University of California (Oakland, CA)
Patent Number(s):
10,087,205
Application Number:
15/128,225
OSTI ID:
1491835
Resource Relation:
Patent File Date: 2015 Mar 27
Country of Publication:
United States
Language:
English

References (342)

A homochiral metal–organic porous material for enantioselective separation and catalysis journal April 2000
1,2,3-triazole based metal-organic framework as photo-active materials patent-application November 2011
Supertetrahedral Sulfide Crystals with Giant Cavities and Channels journal February 1999
Synthesis and Structure of Chemically Stable Metal−Organic Polyhedra journal September 2009
Aryl−Aryl Bond Formation One Century after the Discovery of the Ullmann Reaction journal May 2002
High H2 Adsorption in a Microporous Metal-Organic Framework with Open Metal Sites journal July 2005
High gas adsorption in a microporous metal-organic framework with open-metal sites patent-application November 2006
Strategies for Hydrogen Storage in Metal-Organic Frameworks journal July 2005
Tailored Porous Materials journal October 1999
A Nearly Planar Water Sheet Sandwiched between Strontium−Imidazolium Carboxylate Coordination Polymers journal July 2005
Exceptional H2 Saturation Uptake in Microporous Metal−Organic Frameworks journal March 2006
Metal organic framework—polymer mixed matrix membranes patent December 2009
Ring-Opening Reactions within Porous Metal−Organic Frameworks journal July 2010
Implementation of a strategy for achieving extraordinary levels of surface area and porosity in crystals patent-application November 2004
Reticular Chemistry of Metal–Organic Polyhedra journal June 2008
Interlacing molecular threads on transition metals journal January 1990
Shaped bodies containing metal-organic frameworks patent-application December 2003
Mono- and diprotonation of the [(η5-C5H5)Ti(W5O18)]3- and [(η5-C5Me5)Ti(W5O18)]3- anions journal June 1992
Ultrahigh Porosity in Metal-Organic Frameworks journal July 2010
Metal–Organic Frameworks of Vanadium as Catalysts for Conversion of Methane to Acetic Acid journal August 2011
Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal−Organic Framework Functionalized with Ethylenediamine
  • Demessence, Aude; D’Alessandro, Deanna M.; Foo, Maw Lin
  • Journal of the American Chemical Society, Vol. 131, Issue 25, p. 8784-8786 https://doi.org/10.1021/ja903411w
journal July 2009
Construction of Porous Solids from Hydrogen-Bonded Metal Complexes of 1,3,5-Benzenetricarboxylic Acid journal January 1996
Synthetic Strategies, Structure Patterns, and Emerging Properties in the Chemistry of Modular Porous Solids journal August 1998
SHAPED BODIES CONTAINING METAL-ORGANIC FRAMEWORKS patent-application June 2009
Process for Manufacture of Olefin Oxides patent July 1954
Reticular Synthesis of Microporous and Mesoporous 2D Covalent Organic Frameworks
  • Côté, Adrien P.; El-Kaderi, Hani M.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 129, Issue 43, p. 12914-12915 https://doi.org/10.1021/ja0751781
journal October 2007
Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature patent-application March 2007
Metal-Organic Frameworks with Exceptionally Large Pore Aperatures patent-application April 2013
Metal–organic Frameworks: A tale of two entanglements journal February 2007
CH4 storage and CO2 capture in highly porous zirconium oxide based metal–organic frameworks journal January 2012
Transformation of Germanium Dioxide to Microporous Germanate 4-Connected Nets journal October 1998
Organic Porous Materials Comprising Shape-Persistent Three-Dimensional Molecular Cage Building Blocks patent-application February 2013
Hydrogen Sorption in Functionalized Metal−Organic Frameworks
  • Rowsell, Jesse L. C.; Millward, Andrew R.; Park, Kyo Sung
  • Journal of the American Chemical Society, Vol. 126, Issue 18, p. 5666-5667 https://doi.org/10.1021/ja049408c
journal May 2004
A metal–organic framework replete with ordered donor–acceptor catenanes journal January 2010
Metal–organic frameworks (MOFs) constructed from ZnII/CdII-2,2′-bipyridines and polycarboxylic acids: Synthesis, characterization and microstructural studies journal February 2009
Lewis acid-catalysed formation of two-dimensional phthalocyanine covalent organic frameworks journal June 2010
Transformation of a Metal−Organic Framework from the NbO to PtS Net journal January 2005
Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0 journal September 2008
Metal-organic framework materials for gaseous hydrocarbon storage patent-application August 2006
Nanoporous three-dimensional networks topologically related to Cooperite from the self-assembly of copper(I) centres and the "‘square-planar’' building block 1,2,4,5-tetracyanobenzene journal January 1999
Porous Germanates:  Synthesis, Structure, and Inclusion Properties of Ge7O14.5F2·[(CH3)2NH2]3(H2O)0.86 journal August 1998
Cu2O: A Versatile Reagent for Base-Free Direct Synthesis of NHC-Copper Complexes and Decoration of 3D-MOF with Coordinatively Unsaturated NHC-Copper Species journal April 2010
Topological Control in Heterometallic Metal−Organic Frameworks by Anion Templating and Metalloligand Design journal November 2006
Synthesis and Gas Sorption Properties of a Metal-Azolium Framework (MAF) Material journal November 2009
Concomitant Formation of N-Heterocyclic Carbene−Copper Complexes within a Supramolecular Network in the Self-Assembly of Imidazolium Dicarboxylate with Metal Ions journal July 2009
Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units journal February 2005
Metal–organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units journal November 2001
Gas Adsorption on Metal-Organic Frameworks patent-application March 2010
Metal-Organic Frameworks Based on Trigonal Prismatic Building Blocks and the New “acs” Topology journal May 2005
Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent August 2005
EDIBLE AND BIOCOMPATIBLE METAL-ORGANIC FRAMEWORKS patent-application November 2010
Adsorption of Harmful Organic Vapors by Flexible Hydrophobic Bis-pyrazolate Based MOFs journal March 2010
Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties journal March 2009
“Clickable” Metal−Organic Framework journal November 2008
Method of storing, uptaking, releasing of gases by novel framework materials patent August 2005
Large-Pore Apertures in a Series of Metal-Organic Frameworks journal May 2012
Rigid-Strut-Containing Crown Ethers and [2]Catenanes for Incorporation into Metal-Organic Frameworks journal November 2009
Secondary building units, nets and bonding in the chemistry of metal–organic frameworks
  • Tranchemontagne, David J.; Mendoza-Cortés, José L.; O’Keeffe, Michael
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1257-1283 https://doi.org/10.1039/b817735j
journal January 2009
A Metal–Organic Framework with a Hierarchical System of Pores and Tetrahedral Building Blocks journal April 2006
Framework mobility in the metal–organic framework crystal IRMOF-3: Evidence for aromatic ring and amine rotation journal October 2011
Exceptional ammonia uptake by a covalent organic framework journal February 2010
The pervasive chemistry of metal–organic frameworks journal January 2009
Isoreticular Metalation of Metal−Organic Frameworks
  • Doonan, Christian J.; Morris, William; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 131, Issue 27, p. 9492-9493 https://doi.org/10.1021/ja903251e
journal July 2009
Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores journal February 2001
Gas sensor incorporating a porous framework patent May 2014
Process for producing polyalkylene carbonates patent September 2003
Porous, Crystalline, Covalent Organic Frameworks journal November 2005
Raman spectra of hydrogen and deuterium adsorbed on a metal–organic framework journal August 2005
Process for preparing hydrogen peroxide from the elements patent-application March 2006
Dynamic Chirality in Donor−Acceptor Pretzelanes journal November 2005
A Crystalline Mesoporous Coordination Copolymer with High Microporosity journal January 2008
Determination of the hydrogen absorption sites in Zn4O(1,4-benzenedicarboxylate) by single crystal neutron diffraction journal January 2006
Porous organo-metallic skeleton material containing an additional polymer patent October 2010
Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent-application January 2003
Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5) journal November 2007
Systematic Functionalization of a Metal−Organic Framework via a Postsynthetic Modification Approach journal July 2008
Zeolite A imidazolate frameworks journal May 2007
Process for preparing hydrogen peroxide from the elements patent-application April 2004
A zinc(ii) metal–organic framework based on triazole and dicarboxylate ligands for selective adsorption of hexane isomers journal January 2011
Three-periodic nets and tilings: edge-transitive binodal structures journal August 2006
A metal–organic framework material that functions as an enantioselective catalyst for olefin epoxidation journal January 2006
Highly porous and stable metal–organic frameworks for uranium extraction journal January 2013
Chemical Modification of a Bridging Ligand Inside a Metal–Organic Framework while Maintaining the 3D Structure (Eur. J. Inorg. Chem. 10/2008) journal April 2008
Noncovalently Netted, Photoconductive Sheets with Extremely High Carrier Mobility and Conduction Anisotropy from Triphenylene-Fused Metal Trigon Conjugates journal June 2009
Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature journal December 2005
Implementation of a strategy for achieving extraordinary levels of surface area and porosity in crystals patent January 2010
Metal–Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water
  • Fracaroli, Alejandro M.; Furukawa, Hiroyasu; Suzuki, Mitsuharu
  • Journal of the American Chemical Society, Vol. 136, Issue 25, p. 8863-8866 https://doi.org/10.1021/ja503296c
journal June 2014
Adsorbing Agent, Dust Collection Chamber And Method For Adsorbing Odours patent-application January 2008
Non-carboxylate based metal-organic frameworks (MOFs) and related aspects journal June 2009
Computation of Aromatic C3N4 Networks and Synthesis of the Molecular Precursor N(C3N3)3Cl6 journal September 2003
Process for the alkoxylation of monools in the presence of metallo-organic framework materials patent April 2007
Thermal conductivity of a metal-organic framework (MOF-5): Part II. Measurement journal February 2007
Metal oxides from metal-organic framework materials patent August 2013
Synthesis of Metal−Organic Complex Arrays
  • Vairaprakash, Pothiappan; Ueki, Hisanori; Tashiro, Kentaro
  • Journal of the American Chemical Society, Vol. 133, Issue 4, p. 759-761 https://doi.org/10.1021/ja1097644
journal February 2011
Crystals as Molecules Postsynthesis Covalent Functionalization of Zeolitic Imidazolate Frameworks
  • Morris, William; Doonan, Christian J.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 130, Issue 38, p. 12626-12627 https://doi.org/10.1021/ja805222x
journal September 2008
Process for preparing porous metal-organic frameworks based on aluminum fumarate patent September 2013
Homocoupling of Arylboronic Acids Catalyzed by 1,10-Phenanthroline-Ligated Copper Complexes in Air journal March 2009
Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene patent-application November 2011
NMR and X-ray Study Revealing the Rigidity of Zeolitic Imidazolate Frameworks journal June 2012
Noninterpenetrating Indium Sulfide Supertetrahedral Cristobalite Framework journal June 1999
Introduction to Metal–Organic Frameworks journal September 2011
Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications journal July 2009
Method of using a metal organic frameworks based on aluminum fumarate patent August 2013
Mixed metal framework compositions for monoalkylene glycol production patent November 1991
Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach journal June 2008
Isomers of Metal–Organic Complex Arrays journal June 2012
Selective Bifunctional Modification of a Non-catenated Metal−Organic Framework Material via “Click” Chemistry
  • Gadzikwa, Tendai; Farha, Omar K.; Malliakas, Christos D.
  • Journal of the American Chemical Society, Vol. 131, Issue 38, p. 13613-13615 https://doi.org/10.1021/ja904189d
journal September 2009
Ligand-Directed Strategy for Zeolite-Type Metal–Organic Frameworks: Zinc(II) Imidazolates with Unusual Zeolitic Topologies journal February 2006
Covalent Organic Frameworks and Methods of Making Same patent-application May 2014
The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets journal December 2008
Adsorption Mechanism and Uptake of Methane in Covalent Organic Frameworks: Theory and Experiment
  • Mendoza-Cortés, José L.; Han, Sang Soo; Furukawa, Hiroyasu
  • The Journal of Physical Chemistry A, Vol. 114, Issue 40, p. 10824-10833 https://doi.org/10.1021/jp1044139
journal October 2010
Substituted benzazoloporphyrazines for polymerization and surface attachment and articles formed therefrom patent-application January 2011
PREPARATION OF FUNCTIONALIZED ZEOLITIC FRAMEWORKS patent-application July 2010
Hydrothermal syntheses and structures of three novel coordination polymers assembled from 1,2,3-triazolate ligands journal January 2009
Construction of Microporous Materials from Molecular Building Blocks book January 2002
Preparation of Single Crystals of Coordination Solids in Silica Gels: Synthesis and Structure of CuII(1,4-C4H4N2)(C4O4)(OH2)4 journal July 1995
Synthesis of a Zinc(II) Imidazolium Dicarboxylate Ligand Metal−Organic Framework (MOF): a Potential Precursor to MOF-Tethered N-Heterocyclic Carbene Compounds journal February 2010
Post-synthetic modification of the metal–organic framework compound UiO-66 journal January 2010
A Flexible Germanate Structure Containing 24-Ring Channels and with Very Low Framework Density journal December 2001
Metal-organic frameworks with high capacity and selectivity for harmful gases journal August 2008
Methane Storage in Metal–Organic Frameworks: Current Records, Surprise Findings, and Challenges
  • Peng, Yang; Krungleviciute, Vaiva; Eryazici, Ibrahim
  • Journal of the American Chemical Society, Vol. 135, Issue 32, p. 11887-11894 https://doi.org/10.1021/ja4045289
journal July 2013
Reversible oxygen sorbent compositions patent May 1993
Hydrogen Storage in New Metal–Organic Frameworks
  • Tranchemontagne, David J.; Park, Kyo Sung; Furukawa, Hiroyasu
  • The Journal of Physical Chemistry C, Vol. 116, Issue 24, p. 13143-13151 https://doi.org/10.1021/jp302356q
journal June 2012
Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework journal October 2007
Gas Adsorption Sites in a Large-Pore Metal-Organic Framework journal August 2005
Cu2(ATC)·6H2O:  Design of Open Metal Sites in Porous Metal−Organic Crystals (ATC:  1,3,5,7-Adamantane Tetracarboxylate) journal November 2000
Covalent Organic Frameworks with High Charge Carrier Mobility journal September 2011
Adsorption process with on-line adsorbent removal patent-application November 2006
Method of storing, uptaking, releasing of gases by novel framework materials patent-application August 2003
Three-periodic nets and tilings: semiregular nets journal October 2003
Two Novel Triazole-Based Metal - Organic Frameworks Consolidated by a Flexible Dicarboxylate Co-ligand: Hydrothermal Synthesis, Crystal Structure, and Luminescence Properties journal January 2008
Amphidynamic Character of Crystalline MOF-5: Rotational Dynamics of Terephthalate Phenylenes in a Free-Volume, Sterically Unhindered Environment
  • Gould, Stephanie L.; Tranchemontagne, David; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 130, Issue 11, p. 3246-3247 https://doi.org/10.1021/ja077122c
journal March 2008
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage journal January 2002
Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites journal November 2009
Separation of methane from higher carbon number hydrocarbons utilizing zeolitic imidazolate framework materials patent-application August 2009
A Metal−Organic Framework with Covalently Bound Organometallic Complexes journal July 2010
High gas adsorption metal-organic framework patent February 2010
Cu2[o-Br-C6H3(CO2)2]2(H2O)2·(DMF)8(H2O)2:  A Framework Deliberately Designed To Have the NbO Structure Type journal January 2002
NMR Studies on the Diffusion of Hydrocarbons on the Metal-Organic Framework Material MOF-5 journal March 2006
Geometric requirements and examples of important structures in the assembly of square building blocks journal April 2002
Frameworks for Extended Solids: Geometrical Design Principles journal June 2000
Metal–organic frameworks as heterogeneous catalysts for oxidation reactions journal January 2011
The remarkable catalytic activity of the saturated metal organic framework V-MIL-47 in the cyclohexene oxidation journal January 2010
ADSORPTIVE GAS SEPARATION OF MULTI-COMPONENT GASES patent-application June 2010
Metal–organic frameworks with designed chiral recognition sites journal January 2010
High Methane Storage Capacity in Aluminum Metal–Organic Frameworks journal February 2014
Positronium formation in porous materials for antihydrogen production journal April 2010
Asymmetric catalytic reactions by NbO-type chiral metal–organic frameworks journal January 2011
Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal–linker complexes journal January 2011
Synthesis and Characterization of Zirconogermanates journal September 2003
Syntheses and structural characterization of the one dimensional polymers: 1∞[Rh2 (OAc)4 (NCPhCN)·S]; S=CH3COCH3, CH3OH, C2H5OH, C4H8O and C6H6 journal November 1998
Hydrogen storage in metal-organic and covalent-organic frameworks by spillover journal January 2007
Mutually Interpenetrating Sheets and Channels in the Extended Structure of [Cu(4,4′-bpy)Cl] journal February 1995
Process for the alkoxylation of monools in the presence of metallo-organic framework materials patent-application January 2005
A Molecular Railroad with Large Pores:  Synthesis and Structure of Ni(4,4‘-bpy)2.5(H2O)2(ClO4)2·1.5(4,4‘-bpy)·2H2O journal September 1997
Shaped bodies containing metal-organic frameworks patent May 2005
The variety of conformational isomerism of a flexible organic linker induced by the position and amounts of aromatic carboxylic groups journal November 2014
A Belt-Shaped, Blue Luminescent, and Semiconducting Covalent Organic Framework journal November 2008
Design of Solids from Molecular Building Blocks: Golden Opportunities for Solid State Chemistry journal June 2000
From MOFs to zeolites: zirconium sites for epoxide rearrangement journal January 2013
Characterization of a New Porous Pt-Containing Metal-Organic Framework Containing Potentially Catalytically Active Sites:  Local Electronic Structure at the Metal Centers journal January 2007
Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
  • Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
  • Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871 https://doi.org/10.1021/ja8036096
journal August 2008
Covalently linked organic frameworks and polyhedra patent-application July 2006
Isoreticular MOFs based on a rhombic dodecahedral MOP as a tertiary building unit journal January 2014
Direction of unusual mixed-ligand metal–organic frameworks: a new type of 3-D polythreading involving 1-D and 2-D structural motifs and a 2-fold interpenetrating porous network journal January 2005
Metal-organic framework materials for gaseous hydrocarbon storage patent March 2008
Metal-Organic Frameworks Incorporating Copper-Complexed Rotaxanes journal January 2012
Water Adsorption in Porous Metal–Organic Frameworks and Related Materials journal March 2014
Facile Synthesis of a Highly Crystalline, Covalently Linked Porous Boronate Network journal October 2006
Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach journal June 2008
Synthesis, Structure Determination, and Hydrogen Sorption Studies of New Metal−Organic Frameworks Using Triazole and Naphthalenedicarboxylic Acid journal March 2007
Fluorinated metal-organic frameworks for gas storage patent January 2013
Crystallography of metal–organic frameworks journal October 2014
Metal catalyzed reactions patent February 2004
Chemical Reduction of Metal−Organic Framework Materials as a Method to Enhance Gas Uptake and Binding journal August 2007
Reversible Ethylene Oxide Capture in Porous Frameworks patent-application February 2012
Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks journal April 2001
Donor-acceptor rotaxanes with tetracationic cyclophane ring journal September 2012
Metal−Organic Frameworks As Templates for Nanoscale NaAlH4
  • Bhakta, Raghunandan K.; Herberg, Julie L.; Jacobs, Benjamin
  • Journal of the American Chemical Society, Vol. 131, Issue 37, p. 13198-13199 https://doi.org/10.1021/ja904431x
journal September 2009
A Combined Experimental−Computational Investigation of Carbon Dioxide Capture in a Series of Isoreticular Zeolitic Imidazolate Frameworks journal August 2010
Covalently linked organic frameworks and polyhedra patent September 2009
Hydrogen Storage in Microporous Metal-Organic Frameworks journal May 2003
Selective Guest Binding by Tailored Channels in a 3-D Porous Zinc(II)−Benzenetricarboxylate Network journal March 1997
Assembly of Metal−Organic Frameworks from Large Organic and Inorganic Secondary Building Units:  New Examples and Simplifying Principles for Complex Structures journal August 2001
Open-Framework Solids with Diamond-Like Structures Prepared from Clusters and Metal-Organic Building Blocks journal January 1994
Hydrothermal Synthesis of a Metal-Organic Framework Containing Large Rectangular Channels journal October 1995
Two new metal–triazole-benzenedicarboxylate frameworks affording an uncommon 3,4-connected net and unique 4,6-connected rod packing: hydrothermal synthesis, structure, thermostability and luminescence studies journal January 2009
Crystalline metal-organic microporous materials patent July 1997
New Porous Crystals of Extended Metal-Catecholates journal August 2012
Reversible ethylene oxide capture in porous frameworks patent April 2014
Gas storage system patent-application December 2004
Porous Metal−Organic Polyhedra:  25 Å Cuboctahedron Constructed from 12 Cu2(CO2)4 Paddle-Wheel Building Blocks journal May 2001
New Directions in Polyvanadate Chemistry: From Cages and Clusters to Baskets, Belts, Bowls, and Barrels journal January 1992
Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide journal January 2009
Bleaching composition for dry cleaning containing transition metal bleach catalyst patent November 2002
Design of New Materials for Methane Storage journal March 2004
A Metal-Organic Framework with the Zeolite MTN Topology Containing Large Cages of Volume 2.5 nm3 journal June 2005
Designing Porosity in Coordination Solids book January 1997
Process for the alkoxylation of organic compounds in the presence of novel framework materials patent-application December 2004
T-Shaped Molecular Building Units in the Porous Structure of Ag(4,4‘-bpy)·NO3 journal January 1996
Azulene based metal–organic frameworks for strong adsorption of H2 journal January 2010
Framework functionalisation triggers metal complex binding journal January 2008
Establishing Microporosity in Open Metal−Organic Frameworks:  Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate) journal August 1998
Preparation of metal-containing zeolite catalysts of increased stability and activity patent July 1985
Polymerisation and oligomerisation catalysts patent June 2007
Conversion of hydrogen-bonded manganese(II) and zinc(II) squarate (C4O42–) molecules, chains and sheets to three-dimensional cage networks journal January 1995
Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal−Organic Frameworks and Polyhedra journal September 2008
Reticular Chemistry and Metal-Organic Frameworks for Clean Energy journal September 2009
A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
  • Uribe-Romo, Fernando J.; Hunt, Joseph R.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 131, Issue 13, p. 4570-4571 https://doi.org/10.1021/ja8096256
journal April 2009
Porous, Conductive Metal-Triazolates and Their Structural Elucidation by the Charge-Flipping Method journal June 2012
Air Collector with Functionalized Ion Exchange Membrane for Capturing Ambient CO2 patent-application September 2007
Selective binding and removal of guests in a microporous metal–organic framework journal December 1995
Synthesis and Structure of a Metal-Organic Solid Having the Cadmium(II) Sulfate Net journal January 1996
Covalent Organic Framework Films, and Methods of Making and Uses of Same patent-application February 2014
Hyperpolarized 129Xe Nuclear Magnetic Resonance Studies of Isoreticular Metal-Organic Frameworks journal April 2007
CHEMICAL FRAMEWORK COMPOSITIONS AND METHODS OF USE patent-application June 2011
Advances in the chemistry of metal–organic frameworks journal January 2002
Process for the alkoxylation of organic compounds in the presence of novel framework materials patent October 2007
Crystal Growth of Extended Solids by Nonaqueous Gel Diffusion journal May 1997
Homogeneous and heterogenized Au(III) Schiff base-complexes as selective and general catalysts for self-coupling of aryl boronic acids journal January 2005
Gas sensor incorporating a porous framework patent July 2013
Three-periodic nets and tilings: regular and quasiregular nets journal December 2002
A Crystalline Mesoporous Coordination Copolymer with High Microporosity journal January 2008
1,4-Benzenedicarboxylate derivatives as links in the design of paddle-wheel units and metal–organic frameworks journal November 2001
Isoreticular synthesis and modification of frameworks with the UiO-66 topology journal January 2010
Evaluating metal–organic frameworks for natural gas storage journal January 2014
Metal Insertion in a Microporous Metal−Organic Framework Lined with 2,2′-Bipyridine journal October 2010
Isomeric Zinc(II) Triazolate Frameworks with 3-Connected Networks: Syntheses, Structures, and Sorption Properties journal April 2009
Mixed-component metal–organic frameworks (MC-MOFs): enhancing functionality through solid solution formation and surface modifications journal January 2011
Shaped bodies containing metal-organic frameworks patent April 2009
Design and synthesis of an exceptionally stable and highly porous metal-organic framework journal November 1999
Metal-organic frameworks—New materials for hydrogen storage journal April 2007
Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks journal January 2010
Porous Metal Organic Framework Based On Pyrroles And Pyridinones patent-application July 2009
Coordinatively Unsaturated Metal Centers in the Extended Porous Framework of Zn3(BDC)3·6CH3OH (BDC = 1,4-Benzenedicarboxylate) journal March 1998
Site-Specific CO2 Adsorption and Zero Thermal Expansion in an Anisotropic Pore Network journal December 2011
Polycatenation, polythreading and polyknotting in coordination network chemistry journal November 2003
What do we know about three-periodic nets? journal August 2005
Crystalline Covalent Organic Frameworks with Hydrazone Linkages
  • Uribe-Romo, Fernando J.; Doonan, Christian J.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 133, Issue 30, p. 11478-11481 https://doi.org/10.1021/ja204728y
journal August 2011
Crystal Structure, Dissolution, and Deposition of a 5 nm Functionalized Metal−Organic Great Rhombicuboctahedron journal July 2006
Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn4O(TCA)2] Having the Pyrite Topology journal August 2003
Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets journal September 2011
Raman Spectroscopic Investigation of CH4 and N2 Adsorption in Metal−Organic Frameworks journal July 2007
Process for the alkoxylation of organic compounds in the presence of novel framework materials patent-application April 2003
Docking in Metal-Organic Frameworks journal August 2009
Reticular Chemistry: Occurrence and Taxonomy of Nets and Grammar for the Design of Frameworks journal March 2005
Reticular synthesis and the design of new materials journal June 2003
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks journal June 2006
Oxidative Homo-Coupling Reactions of Aryl Boronic Acids Using a Porous Copper Metal-Organic Framework as a Highly Efficient Heterogeneous Catalyst patent-application May 2012
Four Novel Three-Dimensional Triazole-Based Zinc(II) Metal−Organic Frameworks Controlled by the Spacers of Dicarboxylate Ligands: Hydrothermal Synthesis, Crystal Structure, and Luminescence Properties journal October 2007
Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials journal September 2008
Reversible Interpenetration in a Metal-Organic Framework Triggered by Ligand Removal and Addition journal July 2012
From Condensed Lanthanide Coordination Solids to Microporous Frameworks Having Accessible Metal Sites journal March 1999
Postsynthetic Modification of a Metal–Organic Framework for Stabilization of a Hemiaminal and Ammonia Uptake journal August 2011
Process for the alkoxylation of monools in the presence of metallo-organic framework materials patent-application June 2006
Improved Designs of Metal-Organic Frameworks for Hydrogen Storage journal July 2007
Design, Synthesis, Structure, and Gas (N2, Ar, CO2, CH4, and H2) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra
  • Sudik, Andrea C.; Millward, Andrew R.; Ockwig, Nathan W.
  • Journal of the American Chemical Society, Vol. 127, Issue 19, p. 7110-7118 https://doi.org/10.1021/ja042802q
journal May 2005
Construction of a new open-framework solid from 1,3,5-cyclohexanetricarboxylate and zinc(II) building blocks
  • Yaghi, Omar M.; Jernigan, Ryan; Li, Hailian
  • Journal of the Chemical Society, Dalton Transactions, Vol. 0, Issue 14, p. 2383-2384 https://doi.org/10.1039/a702287e
journal January 1997
CRYSTALLINE 3D- AND 2D COVALENT ORGANIC FRAMEWORKS patent-application June 2010
Non-regenerating carbon monoxide sensor patent March 1998
High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO2 Capture journal February 2008
Zeolitic imidazolate framework materials: recent progress in synthesis and applications journal January 2014
Gas storage system patent December 2007
Syntheses, Structures, and Porous/Luminescent Properties of Silver 3-Alkyl-1,2,4-Triazolate Frameworks with Rare 3-Connected Topologies journal March 2011
A new structure type in polyoxoanion chemistry: synthesis and structure of the V5O143- anion journal June 1989
Communication system for connection to a base station of a multi-cellular wireless telephone system patent April 1997
MOFs as catalysts: Activity, reusability and shape-selectivity of a Pd-containing MOF journal September 2007
A Multiunit Catalyst with Synergistic Stability and Reactivity: A Polyoxometalate–Metal Organic Framework for Aerobic Decontamination journal October 2011
Polymer-Induced Heteronucleation for the Discovery of New Extended Solids journal April 2006
The First Dinitrile Frameworks of the Rare Earth Elements: 3[LnCl3(1,4-Ph(CN)2)] and 3[Ln2Cl6(1,4-Ph(CN)2)], Ln = Sm, Gd, Tb, Y; Access to Novel Metal-Organic Frameworks by Solvent Free Synthesis in Molten 1,4-Benzodinitrile journal November 2008
Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal−Organic Frameworks journal February 2006
A route to high surface area, porosity and inclusion of large molecules in crystals journal February 2004
Metal-organic frameworks based on iron oxide octahedral chains connected by benzenedicarboxylate dianions journal September 2005
Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature patent September 2010
A Microporous Metal–Organic Framework for Gas-Chromatographic Separation of Alkanes journal February 2006
Carbon Dioxide Capture and Storage Using Open Frameworks patent-application May 2012
Directed Transformation of Molecules to Solids: Synthesis of a Microporous Sulfide from Molecular Germanium Sulfide Cages journal January 1994
Strong and Reversible Binding of Carbon Dioxide in a Green Metal–Organic Framework
  • Gassensmith, Jeremiah J.; Furukawa, Hiroyasu; Smaldone, Ronald A.
  • Journal of the American Chemical Society, Vol. 133, Issue 39, p. 15312-15315 https://doi.org/10.1021/ja206525x
journal October 2011
Post-Synthetic Modification of Tagged Metal-Organic Frameworks journal October 2008
20 Å Cd4In16S3514- Supertetrahedral T4 Clusters as Building Units in Decorated Cristobalite Frameworks journal May 2001
Structural study of new hydrocarbon nano-crystals by energy-filtered electron diffraction journal January 2004
Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent March 2007
Characterization of H2 Binding Sites in Prototypical Metal−Organic Frameworks by Inelastic Neutron Scattering
  • Rowsell, Jesse L. C.; Eckert, Juergen; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 127, Issue 42, p. 14904-14910 https://doi.org/10.1021/ja0542690
journal October 2005
Metal-organic frameworks with exceptionally large pore aperatures patent July 2015
Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent-application September 2005
Bone graft composition patent-application October 2007
Metal-Organic Frameworks from Edible Natural Products journal August 2010
Isoreticular Expansion of Metal–Organic Frameworks with Triangular and Square Building Units and the Lowest Calculated Density for Porous Crystals journal September 2011
Gas Sensor Incorporating a Porous Framework patent-application February 2012
Understanding Inflections and Steps in Carbon Dioxide Adsorption Isotherms in Metal-Organic Frameworks journal January 2008
Ge2ZrO6F2·(H2DAB)H2O:1  A 4-Connected Microporous Material with “Bow Tie” Building Units and an Exceptional Proportion of 3-Rings journal December 2000
A Thermally Stable Pt/Y-Based Metal−Organic Framework:  Exploring the Accessibility of the Metal Centers with Spectroscopic Methods Using H2O, CH3OH, and CH3CN as Probes journal November 2006
The CdSO4, rutile, cooperite and quartz dual nets: interpenetration and catenation journal January 2003
Preparation of metal-catecholate frameworks patent June 2014
Metal–organic frameworks: a new class of porous materials journal August 2004
Ammonia Vapor Removal by Cu3(BTC)2 and Its Characterization by MAS NMR journal August 2009
Chemical Modification of a Bridging Ligand Inside a Metal–Organic Framework while Maintaining the 3D Structure journal April 2008
Synthesis and characterization of a soluble oxide inclusion complex, [CH3CNC(V12O324-)] journal July 1989
Novel Eclipsed 2D Cadmium(II) Coordination Polymers with Open-Channel Structure Constructed from Terephthalate and 3-(2-Pyridyl)pyrazole:  Crystal Structures, Emission Properties, and Inclusion of Guest Molecules journal August 2004
Robust dynamics journal May 2010
Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks journal June 2012
Exceptional Framework Flexibility and Sorption Behavior of a Multifunctional Porous Cuprous Triazolate Framework journal May 2008
Gas Odorous Substance Separation patent-application August 2008
[Cd16In64S134]44-: 31-Å Tetrahedron with a Large Cavity journal April 2003
Polymeric Foams with Nanocellular Morphology and Methods for Making Them patent-application October 2009
Late transition metal catalyst complexes and oligomers therefrom patent December 2002
One-Step Synthesis and Structure of an Oligo(spiro-orthocarbonate)
  • Vodak, David T.; Braun, Matthew; Iordanidis, Lykourgos
  • Journal of the American Chemical Society, Vol. 124, Issue 18, p. 4942-4943 https://doi.org/10.1021/ja017683i
journal May 2002
Hydrogen-Bonded Complexes of Aromatic Crown Ethers with (9-Anthracenyl)methylammonium Derivatives. Supramolecular Photochemistry and Photophysics. pH-Controllable Supramolecular Switching
  • Ashton, Peter R.; Ballardini, Roberto; Balzani, Vincenzo
  • Journal of the American Chemical Society, Vol. 119, Issue 44, p. 10641-10651 https://doi.org/10.1021/ja9715760
journal November 1997
MOF-74 building unit has a direct impact on toxic gas adsorption journal January 2011
Mapping of Functional Groups in Metal-Organic Frameworks journal July 2013
Metal-organic polyhedra patent-application June 2005
Process for the epoxidation of an organic compound with oxygen or an oxygen-delivering compounds using catalysts containing metal-organic frame-work materials patent September 2003
Crystalline membranes patent-application January 2005
Heterogeneity within Order in Crystals of a Porous Metal–Organic Framework journal August 2011
A General Thermolabile Protecting Group Strategy for Organocatalytic Metal−Organic Frameworks journal April 2011
Layered Structures Constructed from New Linkages of Ge7(O,OH,F)19 Clusters journal February 2003
Photoluminescent Metal−Organic Polymer Constructed from Trimetallic Clusters and Mixed Carboxylates journal February 2003
Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks journal February 2010
In Situ Hydrothermal Growth of Metal−Organic Framework 199 Films on Stainless Steel Fibers for Solid-Phase Microextraction of Gaseous Benzene Homologues journal December 2009
Mesh-Adjustable Molecular Sieve patent-application August 2008
Role of Copper Species in the Oxidative Dimerization of Arylboronic Acids: Synthesis of Symmetrical Biaryls journal December 2003
Rotaxanes as ligands: from molecules to materials journal January 2007
Process for preparing and organometallic framework material patent August 2008
Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs journal May 2008
A Catenated Strut in a Catenated Metal-Organic Framework journal August 2010
Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc) journal April 2012
Large Free Volume in Maximally Interpenetrating Networks:  The Role of Secondary Building Units Exemplified by Tb2(ADB)3[(CH3)2SO]4·16[(CH3)2SO]1 journal May 2000
Role of Exposed Metal Sites in Hydrogen Storage in MOFs journal July 2008
A High-Throughput Investigation of the Role of pH, Temperature, Concentration, and Time on the Synthesis of Hybrid Inorganic-Organic Materials journal November 2005
Reticular Synthesis of Covalent Organic Borosilicate Frameworks
  • Hunt, Joseph R.; Doonan, Christian J.; LeVangie, James D.
  • Journal of the American Chemical Society, Vol. 130, Issue 36, p. 11872-11873 https://doi.org/10.1021/ja805064f
journal September 2008
Rhenium-selenium-chlorine solid phases: cluster excision and core substitution reactions of molecular species journal November 1992
An Efficient High Yielding Approach for the Homocoupling of Aryl Boronic Acids journal January 2002
PREPARATION OF FUNCTIONALIZED ZEOLITIC FRAMEWORKS patent-application August 2007
A large-cavity zeolite with wide pore windows and potential as an oil refining catalyst journal August 2002
Designed Synthesis of 3D Covalent Organic Frameworks journal April 2007
Zeolite synthesis using an alcohol or like molecules patent November 1992
Taxonomy of periodic nets and the design of materials journal January 2007
Zeolite-like metal organic frameworks (ZMOFS): modular approach to the synthesis of organic-inorganic hybrid porous materials having a zeolite like topology patent-application December 2006
Highly Porous and Stable Metal−Organic Frameworks: Structure Design and Sorption Properties journal February 2000
Synthesis of inorganic membranes on supports patent July 1998
Process for preparing an organometallic framework material patent-application July 2005
Porous Metal−Organic Truncated Octahedron Constructed from Paddle-Wheel Squares and Terthiophene Links journal September 2005