A quaternary sodium superionic conductor - Na10.8Sn1.9PS11.8

Yu, Zhaoxin; Shang, Shun-Li; Gao, Yue; Wang, Daiwei; Li, Xiaolin; Liu, Zi-Kui; Wang, Donghai

doi:10.1016/j.nanoen.2018.01.046

A quaternary sodium superionic conductor - Na_10.8Sn_1.9PS_11.8

Journal Article · Tue May 01 04:00:00 EDT 2018 · Nano Energy

DOI:https://doi.org/10.1016/j.nanoen.2018.01.046· OSTI ID:1490320

Yu, Zhaoxin; Shang, Shun-Li; Gao, Yue; Wang, Daiwei; Li, Xiaolin; Liu, Zi-Kui; Wang, Donghai

Sulfide-based Na-ion conductors are promising candidates as solid-state electrolytes (SSEs) for fabrication of solid-state Na-ion batteries (NIBs) because of their high ionic conductivities and low grain boundary resistance. Currently, most of the sulfide-based Na-ion conductors with high conductivities are focused on Na₃PS₄ phases and its derivatives. It is desirable to develop Na-ion conductors with new composition and crystal structure to achieve superior ionic conductivities. Here we report a new quaternary Na-ion conductor, Na_10.8Sn_1.9PS_11.8, exhibiting a high ionic conductivity of 0.67mS cm^-1 at 25 °C. This high ionic conductivity originates from the presence of a large number of intrinsic Na-vacancies and three-dimensional Na-ion conduction pathways, which has been confirmed by single-crystal X-ray diffraction and first-principles calculations. The Na_10.8Sn_1.9PS_11.8 phase is further evaluated as an electrolyte in a Na-Sn alloy/TiS₂ battery, demonstrating its potential application in all-solid-state NIBs.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1490320

Report Number(s):: PNNL-SA-136565

Journal Information:: Nano Energy, Journal Name: Nano Energy Journal Issue: C Vol. 47; ISSN 2211-2855

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

References (51)

Flexible electrode for long-life rechargeable sodium-ion batteries: effect of oxygen vacancy in MoO _3−x Li, Yifei; Wang, Dandan; An, Qinyou Journal of Materials Chemistry A, Vol. 4, Issue 15 https://doi.org/10.1039/C6TA01342B	journal	January 2016
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data Momma, Koichi; Izumi, Fujio Journal of Applied Crystallography, Vol. 44, Issue 6 https://doi.org/10.1107/S0021889811038970	journal	October 2011
Na ₁₁ Sn ₂ PS ₁₂ : a new solid state sodium superionic conductor Zhang, Z.; Ramos, E.; Lalère, F. Energy & Environmental Science, Vol. 11, Issue 1 https://doi.org/10.1039/C7EE03083E	journal	January 2018
Thermoplastic Elastomer-Enabled Smart Electrolyte for Thermoresponsive Self-Protection of Electrochemical Energy Storage Devices Shi, Ye; Ha, Heonjoo; Al-Sudani, Atheer Advanced Materials, Vol. 28, Issue 36 https://doi.org/10.1002/adma.201602239	journal	July 2016
High temperature sodium batteries: status, challenges and future trends Hueso, Karina B.; Armand, Michel; Rojo, Teófilo Energy & Environmental Science, Vol. 6, Issue 3 https://doi.org/10.1039/c3ee24086j	journal	January 2013
First-principles calculations of lattice dynamics and thermal properties of polar solids Wang, Yi; Shang, Shun-Li; Fang, Huazhi npj Computational Materials, Vol. 2, Issue 1 https://doi.org/10.1038/npjcompumats.2016.6	journal	May 2016
Exceptionally High Ionic Conductivity in Na ₃ P _0.62 As _0.38 S ₄ with Improved Moisture Stability for Solid-State Sodium-Ion Batteries Yu, Zhaoxin; Shang, Shun-Li; Seo, Joo-Hwan Advanced Materials, Vol. 29, Issue 16 https://doi.org/10.1002/adma.201605561	journal	February 2017
Electrochemical Energy Storage for Green Grid Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W. Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613 https://doi.org/10.1021/cr100290v	journal	May 2011
Direct Observation of the Interfacial Instability of the Fast Ionic Conductor Li ₁₀ GeP ₂ S ₁₂ at the Lithium Metal Anode Wenzel, Sebastian; Randau, Simon; Leichtweiß, Thomas Chemistry of Materials, Vol. 28, Issue 7 https://doi.org/10.1021/acs.chemmater.6b00610	journal	March 2016
Electrical Energy Storage for the Grid: A Battery of Choices Dunn, B.; Kamath, H.; Tarascon, J. -M. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1212741	journal	November 2011
Bendable and Thin Sulfide Solid Electrolyte Film: A New Electrolyte Opportunity for Free-Standing and Stackable High-Energy All-Solid-State Lithium-Ion Batteries Nam, Young Jin; Cho, Sung-Ju; Oh, Dae Yang Nano Letters, Vol. 15, Issue 5 https://doi.org/10.1021/acs.nanolett.5b00538	journal	April 2015
Alkali metal crystalline polymer electrolytes Zhang, Chuhong; Gamble, Stephen; Ainsworth, David Nature Materials, Vol. 8, Issue 7 https://doi.org/10.1038/nmat2474	journal	July 2009
Li[sub 9]SiAlO[sub 8]: A Lithium Ion Electrolyte for Voltages above 5.4 V Neudecker, B. J. Journal of The Electrochemical Society, Vol. 143, Issue 7 https://doi.org/10.1149/1.1836980	journal	January 1996
High sodium ion conductivity of glass–ceramic electrolytes with cubic Na3PS4 Hayashi, Akitoshi; Noi, Kousuke; Tanibata, Naoto Journal of Power Sources, Vol. 258 https://doi.org/10.1016/j.jpowsour.2014.02.054	journal	July 2014
Glass-amorphous alkali-ion solid electrolytes and their performance in symmetrical cells Braga, M. Helena; Murchison, Andrew J.; Ferreira, Jorge A. Energy & Environmental Science, Vol. 9, Issue 3 https://doi.org/10.1039/C5EE02924D	journal	January 2016
An Air-Stable Na ₃ SbS ₄ Superionic Conductor Prepared by a Rapid and Economic Synthetic Procedure Wang, Hui; Chen, Yan; Hood, Zachary D. Angewandte Chemie International Edition, Vol. 55, Issue 30 https://doi.org/10.1002/anie.201601546	journal	June 2016
Negating interfacial impedance in garnet-based solid-state Li metal batteries Han, Xiaogang; Gong, Yunhui; Fu, Kun (Kelvin) Nature Materials, Vol. 16, Issue 5 https://doi.org/10.1038/nmat4821	journal	December 2016
Room-Temperature All-solid-state Rechargeable Sodium-ion Batteries with a Cl-doped Na3PS4 Superionic Conductor Chu, Iek-Heng; Kompella, Christopher S.; Nguyen, Han Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep33733	journal	September 2016
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
X-ray Crystal Structure Analysis of Sodium-Ion Conductivity in 94 Na ₃ PS ₄ ⋅6 Na ₄ SiS ₄ Glass-Ceramic Electrolytes Tanibata, Naoto; Noi, Kousuke; Hayashi, Akitoshi ChemElectroChem, Vol. 1, Issue 7 https://doi.org/10.1002/celc.201402016	journal	June 2014
Interfacial Reactivity Benchmarking of the Sodium Ion Conductors Na ₃ PS ₄ and Sodium β-Alumina for Protected Sodium Metal Anodes and Sodium All-Solid-State Batteries Wenzel, Sebastian; Leichtweiss, Thomas; Weber, Dominik A. ACS Applied Materials & Interfaces, Vol. 8, Issue 41 https://doi.org/10.1021/acsami.6b10119	journal	October 2016
Highly Stable Sodium Batteries Enabled by Functional Ionic Polymer Membranes Wei, Shuya; Choudhury, Snehashis; Xu, Jun Advanced Materials, Vol. 29, Issue 12 https://doi.org/10.1002/adma.201605512	journal	January 2017
In search of an optimized electrolyte for Na-ion batteries Ponrouch, Alexandre; Marchante, Elena; Courty, Matthieu Energy & Environmental Science, Vol. 5, Issue 9 https://doi.org/10.1039/c2ee22258b	journal	January 2012
Design and synthesis of the superionic conductor Na10SnP2S12 Richards, William D.; Tsujimura, Tomoyuki; Miara, Lincoln J. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11009	journal	March 2016
Electric Dipoles and Ionic Conductivity in a Na ⁺ Glass Electrolyte Braga, M. Helena; Ferreira, Jorge A.; Murchison, Andrew J. Journal of The Electrochemical Society, Vol. 164, Issue 2 https://doi.org/10.1149/2.0691702jes	journal	December 2016
Fuel pellets from biomass: The importance of the pelletizing pressure and its dependency on the processing conditions Stelte, Wolfgang; Holm, Jens K.; Sanadi, Anand R. Fuel, Vol. 90, Issue 11 https://doi.org/10.1016/j.fuel.2011.05.011	journal	November 2011
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Vacancy-Controlled Na ⁺ Superion Conduction in Na ₁₁ Sn ₂ PS ₁₂ Duchardt, Marc; Ruschewitz, Uwe; Adams, Stefan Angewandte Chemie International Edition, Vol. 57, Issue 5 https://doi.org/10.1002/anie.201712769	journal	January 2018
Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction Bachman, John Christopher; Muy, Sokseiha; Grimaud, Alexis Chemical Reviews, Vol. 116, Issue 1 https://doi.org/10.1021/acs.chemrev.5b00563	journal	December 2015
Ultrafine TiO ₂ Confined in Porous-Nitrogen-Doped Carbon from Metal–Organic Frameworks for High-Performance Lithium Sulfur Batteries An, Yongling; Zhang, Zhen; Fei, Huifang ACS Applied Materials & Interfaces, Vol. 9, Issue 14 https://doi.org/10.1021/acsami.6b16699	journal	March 2017
A review of energy storage technologies for wind power applications Díaz-González, Francisco; Sumper, Andreas; Gomis-Bellmunt, Oriol Renewable and Sustainable Energy Reviews, Vol. 16, Issue 4 https://doi.org/10.1016/j.rser.2012.01.029	journal	May 2012
Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries Hayashi, Akitoshi; Noi, Kousuke; Sakuda, Atsushi Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms1843	journal	January 2012
A Battery Made from a Single Material Han, Fudong; Gao, Tao; Zhu, Yujie Advanced Materials, Vol. 27, Issue 23 https://doi.org/10.1002/adma.201500180	journal	April 2015
Origin of Outstanding Phase and Moisture Stability in a Na ₃ P _{1– x} As _x S ₄ Superionic Conductor Shang, Shun-Li; Yu, Zhaoxin; Wang, Yi ACS Applied Materials & Interfaces, Vol. 9, Issue 19 https://doi.org/10.1021/acsami.7b03606	journal	May 2017
A lithium superionic conductor Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro Nature Materials, Vol. 10, Issue 9, p. 682-686 https://doi.org/10.1038/nmat3066	journal	July 2011
Main Challenges for High Performance NAS Battery: Materials and Interfaces Wen, Zhaoyin; Hu, Yingying; Wu, Xiangwei Advanced Functional Materials, Vol. 23, Issue 8 https://doi.org/10.1002/adfm.201200473	journal	May 2012
USPEX—Evolutionary crystal structure prediction Glass, Colin W.; Oganov, Artem R.; Hansen, Nikolaus Computer Physics Communications, Vol. 175, Issue 11-12 https://doi.org/10.1016/j.cpc.2006.07.020	journal	December 2006
Na ₃ SbS ₄ : A Solution Processable Sodium Superionic Conductor for All-Solid-State Sodium-Ion Batteries Banerjee, Abhik; Park, Kern Ho; Heo, Jongwook W. Angewandte Chemie International Edition, Vol. 55, Issue 33 https://doi.org/10.1002/anie.201604158	journal	July 2016
High-power all-solid-state batteries using sulfide superionic conductors Kato, Yuki; Hori, Satoshi; Saito, Toshiya Nature Energy, Vol. 1, Issue 4 https://doi.org/10.1038/nenergy.2016.30	journal	March 2016
Functional Materials for Rechargeable Batteries Cheng, Fangyi; Liang, Jing; Tao, Zhanliang Advanced Materials, Vol. 23, Issue 15 https://doi.org/10.1002/adma.201003587	journal	March 2011
Challenges and Perspectives for NASICON-Type Electrode Materials for Advanced Sodium-Ion Batteries Chen, Shuangqiang; Wu, Chao; Shen, Laifa Advanced Materials, Vol. 29, Issue 48 https://doi.org/10.1002/adma.201700431	journal	June 2017
High-Performance All-Inorganic Solid-State Sodium–Sulfur Battery Yue, Jie; Han, Fudong; Fan, Xiulin ACS Nano, Vol. 11, Issue 5 https://doi.org/10.1021/acsnano.7b01445	journal	April 2017
Na ₃ PSe ₄ : A Novel Chalcogenide Solid Electrolyte with High Ionic Conductivity Zhang, Long; Yang, Kun; Mi, Jianli Advanced Energy Materials, Vol. 5, Issue 24 https://doi.org/10.1002/aenm.201501294	journal	October 2015
The Emerging Chemistry of Sodium Ion Batteries for Electrochemical Energy Storage Kundu, Dipan; Talaie, Elahe; Duffort, Victor Angewandte Chemie International Edition, Vol. 54, Issue 11 https://doi.org/10.1002/anie.201410376	journal	February 2015
Li ₁₀ SnP ₂ S ₁₂ : An Affordable Lithium Superionic Conductor Bron, Philipp; Johansson, Sebastian; Zick, Klaus Journal of the American Chemical Society, Vol. 135, Issue 42 https://doi.org/10.1021/ja407393y	journal	October 2013
Conductivity measurements on nasicon and nasicon-modified materials Bohnke, O. Solid State Ionics, Vol. 122, Issue 1-4 https://doi.org/10.1016/S0167-2738(99)00062-4	journal	July 1999
Theoretical prediction of a highly conducting solid electrolyte for sodium batteries: Na ₁₀ GeP ₂ S ₁₂ Kandagal, Vinay S.; Bharadwaj, Mridula Dixit; Waghmare, Umesh V. Journal of Materials Chemistry A, Vol. 3, Issue 24 https://doi.org/10.1039/C5TA01616A	journal	January 2015
Reshaping Lithium Plating/Stripping Behavior via Bifunctional Polymer Electrolyte for Room-Temperature Solid Li Metal Batteries Zeng, Xian-Xiang; Yin, Ya-Xia; Li, Nian-Wu Journal of the American Chemical Society, Vol. 138, Issue 49 https://doi.org/10.1021/jacs.6b10088	journal	December 2016
First-principles thermodynamics from phonon and Debye model: Application to Ni and Ni3Al Shang, Shun-Li; Wang, Yi; Kim, DongEung Computational Materials Science, Vol. 47, Issue 4 https://doi.org/10.1016/j.commatsci.2009.12.006	journal	February 2010
Influence of annealing on ionic transfer and storage stability of Li2S–P2S5 solid electrolyte Wei, Junjun; Kim, Hyea; Lee, Dong-Chan Journal of Power Sources, Vol. 294 https://doi.org/10.1016/j.jpowsour.2015.06.074	journal	October 2015
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001

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Salt-Based Organic-Inorganic Nanocomposites: Towards A Stable Lithium Metal/Li ₁₀ GeP ₂ S ₁₂ Solid Electrolyte Interface Gao, Yue; Wang, Daiwei; Li, Yuguang C. Angewandte Chemie, Vol. 130, Issue 41 https://doi.org/10.1002/ange.201807304	journal	September 2018
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