Recent Progress on Dominant Sulfide‐Type Solid‐State Na Superionic Conductors for Solid‐State Sodium Batteries

Guo, Xiaolin; Halacoglu, Selim; Chen, Yan; Wang, Hui

doi:10.1002/smll.202311195

Recent Progress on Dominant Sulfide‐Type Solid‐State Na Superionic Conductors for Solid‐State Sodium Batteries

Journal Article · Wed May 22 00:00:00 EDT 2024 · Small

DOI:https://doi.org/10.1002/smll.202311195· OSTI ID:2352799

Guo, Xiaolin ^[1]; Halacoglu, Selim ^[1]; Chen, Yan ^[2]; ^[1]

Mechanical Engineering Department University of Louisville Louisville KY 40292 USA
Neutron Scattering Division Oak Ridge National Laboratory Oak Ridge TN 37830 USA

Abstract

Over the past decade, solid‐state batteries have garnered significant attentions due to their potentials to deliver high energy density and excellent safety. Considering the abundant sodium (Na) resources in contrast to lithium (Li), the development of sodium‐based batteries has become increasingly appealing. Sulfide‐based superionic conductors are widely considered as promising solid eletcrolytes (SEs) in solid‐state Na batteries due to the features of high ionic conductivity and cold‐press densification. In recent years, tremendous efforts have been made to investigate sulfide‐based Na‐ion conductors on their synthesis, compositions, conductivity, and the feasibility in batteries. However, there are still several challenges to overcome for their practical applications in high performance solid‐state Na batteries. This article provides a comprehensive update on the synthesis, structure, and properties of three dominant sulfide‐based Na‐ion conductors (Na ₃ PS ₄ , Na ₃ SbS ₄ , and Na ₁₁ Sn ₂ PS ₁₂ ), and their families that have a variety of anion and cation doping. Additionally, the interface stability of these sulfide electrolytes toward the anode is reviewed, as well as the electrochemical performance of solid‐state Na batteries based on different types of cathode materials (metal sulfides, oxides, and organics). Finally, the perspective and outlook for the development and practical utilization of sulfide‐based SE in solid‐state batteries are discussed.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0021257

OSTI ID:: 2352799

Journal Information:: Small, Journal Name: Small; ISSN 1613-6810

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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