Catalytic applications of enzymes encapsulated in metal–organic frameworks

Drout, Riki J.; Robison, Lee; Farha, Omar K.

doi:10.1016/j.ccr.2018.11.009

Title: Catalytic applications of enzymes encapsulated in metal–organic frameworks

Journal Article · Tue Dec 11 00:00:00 EST 2018 · Coordination Chemistry Reviews

DOI:https://doi.org/10.1016/j.ccr.2018.11.009· OSTI ID:1489652

Drout, Riki J. ^[1];

^[1]; Farha, Omar K. ^[1]

Northwestern Univ., Evanston, IL (United States)

Here, the global catalyst industry is valued at nearly 20 billion USD and demand continues to rise. Enzymes, biological macromolecules, are highly selective and efficient catalysts; however, their commercial implementation has been hindered due to their poor chemical and thermal stability and low reusability. Numerous strategies have been investigated to stabilize enzymes and improve their processability. Recently, metal–organic frameworks (MOFs) have been investigated as enzyme immobilization supports. Herein, we highlight the immobilization of enzymes in MOF cages and pores for catalysis applications and discuss the future of this enzyme encapsulation strategy.

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Research Organization:: Univ. of Notre Dame, IN (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0003763

OSTI ID:: 1489652

Alternate ID(s):: OSTI ID: 1636720

Journal Information:: Coordination Chemistry Reviews, Vol. 381, Issue C; ISSN 0010-8545

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 148 works

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Construction of Thermophilic Lipase-Embedded Metal–Organic Frameworks via Biomimetic Mineralization: A Biocatalyst for Ester Hydrolysis and Kinetic Resolution He, Hongming; Han, Haobo; Shi, Hui ACS Applied Materials & Interfaces, Vol. 8, Issue 37 https://doi.org/10.1021/acsami.6b05538	journal	September 2016
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Encapsulation of a Nerve Agent Detoxifying Enzyme by a Mesoporous Zirconium Metal–Organic Framework Engenders Thermal and Long-Term Stability Li, Peng; Moon, Su-Young; Guelta, Mark A. Journal of the American Chemical Society, Vol. 138, Issue 26 https://doi.org/10.1021/jacs.6b03673	journal	June 2016
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