BaFe4O7 and K0.22Ba0.89Fe4O7: Canted Antiferromagnetic Diferrites with Exceptionally High Magnetic Ordering Temperatures [BaFe4O7 and K0.22Ba0.89Fe4O7– New Canted Antiferromagnetic Diferrites with Exceptionally High Magnetic Ordering Temperatures]

Ferreira, Timothy; Morrison, Gregory; Chance, W. Michael; Calder, Stuart A.; Smith, Mark D.; zur Loye, Hans -Conrad

doi:10.1021/acs.chemmater.7b00580

BaFe₄O₇ and K_0.22Ba_0.89Fe₄O₇: Canted Antiferromagnetic Diferrites with Exceptionally High Magnetic Ordering Temperatures [BaFe₄O₇ and K_0.22Ba_0.89Fe₄O₇– New Canted Antiferromagnetic Diferrites with Exceptionally High Magnetic Ordering Temperatures]

Journal Article · Thu Mar 23 00:00:00 EDT 2017 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.7b00580· OSTI ID:1485320

Ferreira, Timothy ^[1]; ^[1]; Chance, W. Michael ^[1]; ^[2]; Smith, Mark D. ^[1]; ^[1]

Univ. of South Carolina, Columbia, SC (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Here, complex iron containing oxides, typically referred to as ferrites, have been extensively studied for their electronic and magnetic properties, including magnetotransport, ferromagnetism, ferroelectricity, and a combination of the latter two, known as multiferroism. The search for materials possessing simultaneous ferromagnetic and ferroelectric behavior is of significant interest both for the advancement of fundamental science and for applications in random access memory (RAM). Despite the great technological potential of multiferroics, one or both of the ferroic ordering temperatures tend to fall below room temperature, such as in the compositions TbMnO₃ and Ni₃V₂O₈, thus eliminating their practical utility for RAM applications. The scarcity of multiferroics possessing room temperature ferroic orderings continues to drive exploratory research in this field. For this reason, ferrites have garnered significant interest due to their often high ferroic ordering temperatures, for example in BiFeO₃. Among all ferrites, hexaferrites are the most studied prototypical examples and constitute a specific subclass of ferrites that follows the stoichiometry Ba_O–nFe₂O₃, in which the n value dictates the nomenclature, i.e., (n = 6) is a hexaferrite or (n = 1) is a monoferrite. This versatile class of materials encompasses a wide range of related structures best described by Pullar, serving as the motivation for this work.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Workforce Development for Teachers and Scientists (WDTS) (SC-27)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1485320

Journal Information:: Chemistry of Materials, Journal Name: Chemistry of Materials Journal Issue: 7 Vol. 29; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited By (3)

Neutron Instruments for Research in Coordination Chemistry: Neutron Instruments for Research in Coordination Chemistry Xue, Zi-Ling; Ramirez-Cuesta, Anibal J.; Brown, Craig M. European Journal of Inorganic Chemistry, Vol. 2019, Issue 8 https://doi.org/10.1002/ejic.201801076	journal	January 2019
Oxo-Hydroxoferrate K _{2− x} Fe ₄ O _{7− x} (OH) _x : Hydroflux Synthesis, Chemical and Thermal Instability, Crystal and Magnetic Structures Albrecht, Ralf; Hunger, Jens; Block, Theresa ChemistryOpen, Vol. 8, Issue 1 https://doi.org/10.1002/open.201800229	journal	January 2019
A suite-level review of the neutron powder diffraction instruments at Oak Ridge National Laboratory Calder, S.; An, K.; Boehler, R. Review of Scientific Instruments, Vol. 89, Issue 9 https://doi.org/10.1063/1.5033906	journal	September 2018

Figures / Tables (8)

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CCDC 1522091: Experimental Crystal Structure Determination: HAPGAJ : Non-CSD Structure Ferreira, Timothy; Morrison, Gregory; Chance, W. Michael https://doi.org/10.5517/ccdc.csd.cc1n2vq9 The current record is supplemented by this dataset	dataset	December 2016
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