Fundamental Understanding of Water‐Induced Mechanisms in Li–O 2 Batteries: Recent Developments and Perspectives

Dai, Alvin; Li, Qidong; Liu, Tongchao; Amine, Khalil; Lu, Jun

doi:10.1002/adma.201805602

Title: Fundamental Understanding of Water‐Induced Mechanisms in Li–O ₂ Batteries: Recent Developments and Perspectives

Journal Article · Tue Nov 27 00:00:00 EST 2018 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201805602· OSTI ID:1483429

Dai, Alvin ^[1]; Li, Qidong ^[2]; Liu, Tongchao ^[3]; Amine, Khalil ^[4];

^[1]

Chemical Sciences and Engineering Division Argonne National Laboratory 9700 South Cass Avenue Lemont IL 60439 USA
Chemical Sciences and Engineering Division Argonne National Laboratory 9700 South Cass Avenue Lemont IL 60439 USA, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing International School of Materials Science and Engineering Wuhan University of Technology Hubei Wuhan 430070 China
Chemical Sciences and Engineering Division Argonne National Laboratory 9700 South Cass Avenue Lemont IL 60439 USA, School of Advanced Materials Peking University Shenzhen Graduate School Shenzhen 518055 China
Chemical Sciences and Engineering Division Argonne National Laboratory 9700 South Cass Avenue Lemont IL 60439 USA, Material Science and Engineering Stanford University Stanford CA 94305 USA

Abstract Modern sustainability challenges in recent years have warranted the development of new energy storage technologies. Practical realization of the lithium–O ₂ battery holds great promise for revolutionizing energy storage as it holds the highest theoretical specific energy of any rechargeable battery yet discovered. However, the complete realization of Li–O ₂ batteries necessitates ambient air operations, which presents quite a few challenges, as carbon dioxide (CO ₂ ) and water (H ₂ O) contaminants introduce unwanted byproducts from side reactions that greatly affect battery performance. Although current research has thoroughly explored the beneficial incorporation of CO ₂ , much mystery remains over the inconsistent effects of H ₂ O. The presence of water in both the cathode and electrolyte has been observed to alter reaction mechanisms differently, resulting in a diverse range of effects on voltage, capacity, and cyclability. Moreover, recent preliminary research with catalysts and redox mediators has attempted to utilize the presence of water to the battery's benefit. Here, the key mechanism discrepancies of water‐afflicted Li–O ₂ batteries are presented, concluding with a perspective on future research directions for nonaqueous Li–O ₂ batteries.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: DE‐AC02‐06CH11357

OSTI ID:: 1483429

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Vol. 31 Journal Issue: 31; ISSN 0935-9648

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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