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Elastic properties of single crystal hydrogen sulfide: A Brillouin scattering study under high pressure-temperature

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.5040399· OSTI ID:1476093
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1]
  1. Jilin Univ., Changchun (China). State Key Lab. of Superhard Materials
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We have performed high pressure-temperature Brillouin scattering measurements on single crystal hydrogen sulfide using externally heated diamond anvil cell techniques. The pressure dependences of the acoustic velocities, isothermal elastic constants, and moduli of single crystal hydrogen sulfide have been determined along four isotherms. Both elastic constants and moduli increase monotonously with pressure along each isotherm, while they show a decreased tendency with temperature elevated under the same pressure points. The experimental equation of state of single crystal hydrogen sulfide is obtained by fitting with a third-order Birch-Murnaghan and Tait equation. It is proposed that the effect of hydrogen bonds contributes to the unique tendency of elastic anisotropy in single crystal hydrogen sulfide. Through our work, we have extended the melting curve and phase diagram of hydrogen sulfide up to 12 GPa and 580 K.
Research Organization:
Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)
Sponsoring Organization:
USDOE Office of Science (SC)
Grant/Contract Number:
AC02-06CH11357; FG02-94ER14466
OSTI ID:
1476093
Alternate ID(s):
OSTI ID: 1473737
Journal Information:
Journal of Applied Physics, Journal Name: Journal of Applied Physics Journal Issue: 12 Vol. 124; ISSN 0021-8979
Publisher:
American Institute of Physics (AIP)Copyright Statement
Country of Publication:
United States
Language:
ENGLISH

References (52)

Brillouin scattering at high pressure: an overview journal January 2003
Metal hydride materials for solid hydrogen storage: A review☆ journal June 2007
Deuteron and sulfur-33 NMR line-shape studies of the molecular motion in the liquid and solid phases of hydrogen sulfide and the solid II phase of hydrogen selenide journal October 1989
Structure and Phase Transition in Solid Hydrogen and Deuterium Sulphides journal November 1969
Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system journal August 2015
Quantum hydrogen-bond symmetrization in the superconducting hydrogen sulfide system journal March 2016
Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets journal May 2021
Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect journal February 2020
Pressure-induced metallization of dense (H2S)2H2 with high-Tc superconductivity journal November 2014
Metric-tensor flexible-cell algorithm for isothermal–isobaric molecular dynamics simulations journal January 2001
Order-disorder phase transition and dissociation of hydrogen sulfide under high pressure: Ab initio molecular dynamics study journal April 2010
Hydrogen bond symmetrization and superconducting phase of HBr and HCl under high pressure: An ab initio study journal August 2010
Pressure‐induced phase transition in solid hydrogen sulfide at 11 GPa journal August 1991
New method of high-pressure Brillouin studies for elastic properties of molecular single-crystals grown in a diamond-anvil cell conference January 1994
Brillouin scattering and x-ray diffraction of solid argon to 65 GPa and 700 K: Shear strength of argon at H P /H T journal September 2013
The metallization and superconductivity of dense hydrogen sulfide journal May 2014
Equations of state of ice VI and ice VII at high pressure and high temperature journal September 2014
Synthesis and stability of hydrogen selenide compounds at high pressure journal November 2017
Hydrogen storage in molecular compounds journal January 2004
Superconductivity at  100 K in dense SiH4(H2)2 predicted by first principles journal August 2010
Superconductive sodalite-like clathrate calcium hydride at high pressures journal April 2012
Development of low-temperature and high-pressure Brillouin scattering spectroscopy and its application to the solid I form of hydrogen sulphide journal October 2002
Special points for Brillouin-zone integrations journal June 1976
Ab initio molecular dynamics for open-shell transition metals journal November 1993
Projector augmented-wave method journal December 1994
Superconductivity up to 164 K in HgBa 2 Ca m − 1 Cu m O 2 m + 2 + δ ( m =1, 2, and 3) under quasihydrostatic pressures journal August 1994
Pressure-temperature phase diagram of solid hydrogen sulfide determined by Raman spectroscopy journal April 1995
High-pressure elastic properties of the VI and VII phase of ice in dense H 2 O and D 2 O journal March 1996
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal October 1996
Structures of H2S Phases I′ and IV under high pressure journal February 1998
From ultrasoft pseudopotentials to the projector augmented-wave method journal January 1999
Extended and accurate determination of the melting curves of argon, helium, ice ( H 2 O ) , and hydrogen ( H 2 ) journal March 2000
Pressure-induced phase transition of hydrogen sulfide at low temperature: Role of the hydrogen bond and short S-S contacts journal August 2001
Molecular dissociation and two low-temperature high-pressure phases of H 2 S journal June 2004
Pressure-induced decomposition of solid hydrogen sulfide journal May 2015
Van Hove singularities and spectral smearing in high-temperature superconducting H 3 S journal March 2016
Hydrogen sulfide at high pressure: Change in stoichiometry journal May 2016
Bulk moduli and equations of state of ice VII and ice VIII journal May 2017
First-Principles Simulations of Lithium Melting: Stability of the bcc Phase Close to Melting journal May 2010
Hydrogen Clathrate Structures in Rare Earth Hydrides at High Pressures: Possible Route to Room-Temperature Superconductivity journal September 2017
General, Closed-Form Expressions for Acoustic Waves in Cubic Crystals journal April 1979
Generalized Gradient Approximation Made Simple journal October 1996
Static Structure and Dynamical Correlations in High Pressure H 2 S journal September 1999
Pressure-Induced Hydrogen Bonding Structure of D2S Phase I′ journal July 2000
Facilities for high-pressure research with the diamond anvil cell at GSECARS journal August 2005
Hydrogen storage in molecular compounds journal August 2005
High-Pressure Brillouin Studies and Elastic Properties of Single-Crystal H2S Grown in a Diamond Cell journal July 1992
The solid phases of deuterium sulphide by powder neutron diffraction journal January 1990
The solid phases of deuterium sulphide by powder neutron diffraction journal January 1990
Hydrogen sulfide at high pressure: Change in stoichiometry text January 2016
Pressure-induced decomposition of solid hydrogen sulfide text January 2015
Hydrogen sulfide at high pressure: change in stoichiometry text January 2016

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Disorder–order structural transition of single crystal hydrogen chloride under high pressure–temperature journal January 2019

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Related Subjects

36 MATERIALS SCIENCE
Acoustical properties
Brillouin spectroscopy
Crystal structure
Diamond anvil cells
Elasticity
Equations of state
Light scattering
Phase transitions