Role of temperature and oxygen content on structural and electrical properties of LaBaCo2O5+δ thin films

Mace, Brennan; Harrell, Zach; Chen, Chonglin; Enriquez, Erik; Chen, Aiping; Jia, Quanxi

doi:10.1063/1.5009245

Title: Role of temperature and oxygen content on structural and electrical properties of LaBaCo₂O_5+δ thin films

Journal Article · Mon Feb 12 00:00:00 EST 2018 · Applied Physics Letters

DOI:https://doi.org/10.1063/1.5009245· OSTI ID:1471370

Mace, Brennan ^[1];

^[1]; Chen, Chonglin ^[1];

^[2];

^[2]; Jia, Quanxi ^[3]

Univ. of Texas at San Antonio, San Antonio, TX (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Univ. at Buffalo–the State Univ. of New York, Buffalo, NY (United States)

Here, the role of temperature and the oxygen content in the structural transformation and electrical conductivity of epitaxial double perovskite LaBaCo₂O_5+δ (0≤ δ ≤ 1) thin films was systematically investigated. Reciprocal space mapping and ω-2θ x-ray diffraction performed at different temperatures in vacuum indicate that oxygen vacancies in the films become ordered at high temperature in a reducing environment. The changes of the oxygen content and the degree of oxygen vacancy ordering in the films result in a strong in-plane anisotropic lattice deformation and a large thermal expansion coefficient along the c-axis direction. The electrical conductivity measurements reveal that these behaviors are related to the degree of oxygen vacancy formation and lattice deformation in the films.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC52-06NA25396; AC04-94AL85000

OSTI ID:: 1471370

Alternate ID(s):: OSTI ID: 1421308

Report Number(s):: LA-UR-18-28582

Journal Information:: Applied Physics Letters, Vol. 112, Issue 7; ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 7 works

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Title: Role of temperature and oxygen content on structural and electrical properties of LaBaCo2O5+δ thin films

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