One-Step Synthesis of Hybrid Core-Shell Metal-Organic Frameworks

Yang, Xinyu; Yuan, Shuai; Zou, Lanfang; Drake, Hannah; Zhang, Yingmu; Qin, Junsheng; Alsalme, Ali; Zhou, Hong-Cai

doi:10.1002/anie.201710019

Title: One-Step Synthesis of Hybrid Core-Shell Metal-Organic Frameworks

Journal Article · Fri Feb 16 00:00:00 EST 2018 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201710019· OSTI ID:1470334

Yang, Xinyu ^[1]; Yuan, Shuai ^[1]; Zou, Lanfang ^[1]; Drake, Hannah ^[1]; Zhang, Yingmu ^[1]; Qin, Junsheng ^[1]; Alsalme, Ali ^[2];

^[1]

Texas A & M Univ., College Station, TX (United States)
King Saud Univ., Riyadh (Saudi Arabia)

Abstract Epitaxial growth of MOF‐on‐MOF composite is an evolving research topic in the quest for multifunctional materials. In previously reported methods, the core–shell MOFs were synthesized via a stepwise strategy that involved growing the shell‐MOFs on top of the preformed core‐MOFs with matched lattice parameters. However, the inconvenient stepwise synthesis and the strict lattice‐matching requirement have limited the preparation of core–shell MOFs. Herein, we demonstrate that hybrid core–shell MOFs with mismatching lattices can be synthesized under the guidance of nucleation kinetic analysis. A series of MOF composites with mesoporous core and microporous shell were constructed and characterized by optical microscopy, powder X‐ray diffraction, gas sorption measurement, and scanning electron microscopy. Isoreticular expansion of microporous shells and orthogonal modification of the core was realized to produce multifunctional MOF composites, which acted as size selective catalysts for olefin epoxidation with high activity and selectivity.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Univ. of California, Berkeley (United States). Energy Frontier Research Center (EFRC) (United States) Center for Gas Separations Relevant to Clean Energy Technologies (CGS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office (HFTO); USDOE Office of Fossil Energy (FE)

Grant/Contract Number:: SC0001015; EE0007049; FE0026472

OSTI ID:: 1470334

Alternate ID(s):: OSTI ID: 1432067

Journal Information:: Angewandte Chemie (International Edition), Vol. 57, Issue 15; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 118 works

Citation information provided by
Web of Science

References (69)

MOF@MOF: microporous core–shell architectures Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J. Chemical Communications, Issue 41 https://doi.org/10.1039/b904526k	journal	January 2009
A Porous Metal–Organic Framework with Dynamic Pyrimidine Groups Exhibiting Record High Methane Storage Working Capacity Li, Bin; Wen, Hui-Min; Wang, Hailong Journal of the American Chemical Society, Vol. 136, Issue 17 https://doi.org/10.1021/ja501810r	journal	April 2014
A dual functional MOF as a luminescent sensor for quantitatively detecting the concentration of nitrobenzene and temperature Ma, Dingxuan; Li, Baiyan; Zhou, Xiaojing Chemical Communications, Vol. 49, Issue 79 https://doi.org/10.1039/c3cc44546a	journal	January 2013
Isotropic and Anisotropic Growth of Metal–Organic Framework (MOF) on MOF: Logical Inference on MOF Structure Based on Growth Behavior and Morphological Feature Choi, Sora; Kim, Taeho; Ji, Hoyeon Journal of the American Chemical Society, Vol. 138, Issue 43 https://doi.org/10.1021/jacs.6b08821	journal	October 2016
Gas storage in porous metal–organic frameworks for clean energy applications Ma, Shengqian; Zhou, Hong-Cai Chem. Commun., Vol. 46, Issue 1 https://doi.org/10.1039/B916295J	journal	January 2010
A High-Performance Gas-Separation Membrane Containing Submicrometer-Sized Metal-Organic Framework Crystals Bae, Tae-Hyun; Lee, Jong Suk; Qiu, Wulin Angewandte Chemie International Edition, Vol. 49, Issue 51, p. 9863-9866 https://doi.org/10.1002/anie.201006141	journal	November 2010
Molecular Encapsulation beyond the Aperture Size Limit through Dissociative Linker Exchange in Metal–Organic Framework Crystals Morabito, Joseph V.; Chou, Lien-Yang; Li, Zhehui Journal of the American Chemical Society, Vol. 136, Issue 36 https://doi.org/10.1021/ja5054779	journal	August 2014
Linker Installation: Engineering Pore Environment with Precisely Placed Functionalities in Zirconium MOFs Yuan, Shuai; Chen, Ying-Pin; Qin, Jun-Sheng Journal of the American Chemical Society, Vol. 138, Issue 28 https://doi.org/10.1021/jacs.6b04501	journal	July 2016
Dynamically controlled one-pot synthesis of heterogeneous core–shell MOF single crystals using guest molecules Wang, Lei; Yang, Weiting; Li, Yangxue Chem. Commun., Vol. 50, Issue 79 https://doi.org/10.1039/C4CC03588G	journal	January 2014
Porous metal–organic-framework nanoscale carriers as a potential platform for drug delivery and imaging Horcajada, Patricia; Chalati, Tamim; Serre, Christian Nature Materials, Vol. 9, Issue 2 https://doi.org/10.1038/nmat2608	journal	December 2009
Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function Hirai, Kenji; Furukawa, Shuhei; Kondo, Mio Chemical Communications, Vol. 48, Issue 52 https://doi.org/10.1039/c2cc31421e	journal	January 2012
A robust near infrared luminescent ytterbium metal–organic framework for sensing of small molecules Guo, Zhiyong; Xu, Hui; Su, Shengqun Chemical Communications, Vol. 47, Issue 19 https://doi.org/10.1039/c1cc10897b	journal	January 2011
Flexible Zirconium Metal-Organic Frameworks as Bioinspired Switchable Catalysts Yuan, Shuai; Zou, Lanfang; Li, Haixia Angewandte Chemie, Vol. 128, Issue 36 https://doi.org/10.1002/ange.201604313	journal	June 2016
Tunable Rare-Earth fcu-MOFs: A Platform for Systematic Enhancement of CO₂ Adsorption Energetics and Uptake Xue, Dong-Xu; Cairns, Amy J.; Belmabkhout, Youssef Journal of the American Chemical Society, Vol. 135, Issue 20, p. 7660-7667 https://doi.org/10.1021/ja401429x	journal	May 2013
Porous Zirconium Metal–Organic Framework Constructed from 2D → 3D Interpenetration Based on a 3,6-Connected kgd Net Wang, Rongming; Wang, Zhiying; Xu, Yuwen Inorganic Chemistry, Vol. 53, Issue 14 https://doi.org/10.1021/ic5012764	journal	June 2014
A Homochiral Porous Metal−Organic Framework for Highly Enantioselective Heterogeneous Asymmetric Catalysis Wu, Chuan-De; Hu, Aiguo; Zhang, Lin Journal of the American Chemical Society, Vol. 127, Issue 25 https://doi.org/10.1021/ja052431t	journal	June 2005
Metal–organic framework (MOF): lanthanide(iii)-doped approach for luminescence modulation and luminescent sensing Luo, Feng; Batten, Stuart R. Dalton Transactions, Vol. 39, Issue 19 https://doi.org/10.1039/c002822n	journal	January 2010
Flexible Porous Metal-Organic Frameworks for a Controlled Drug Delivery Horcajada, Patricia; Serre, Christian; Maurin, Guillaume Journal of the American Chemical Society, Vol. 130, Issue 21 https://doi.org/10.1021/ja710973k	journal	May 2008
Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials Cook, Timothy R.; Zheng, Yao-Rong; Stang, Peter J. Chemical Reviews, Vol. 113, Issue 1 https://doi.org/10.1021/cr3002824	journal	November 2012
Metal–organic framework (MOF): a novel sensing platform for biomolecules Zhu, Xi; Zheng, Hanye; Wei, Xiaofeng Chemical Communications, Vol. 49, Issue 13 https://doi.org/10.1039/c2cc36661d	journal	January 2013
Fabrication of ZIF-8@SiO ₂ Core-Shell Microspheres as the Stationary Phase for High-Performance Liquid Chromatography Fu, Yan-Yan; Yang, Cheng-Xiong; Yan, Xiu-Ping Chemistry - A European Journal, Vol. 19, Issue 40 https://doi.org/10.1002/chem.201301461	journal	August 2013
Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites Britt, D.; Furukawa, H.; Wang, B. Proceedings of the National Academy of Sciences, Vol. 106, Issue 49, p. 20637-20640 https://doi.org/10.1073/pnas.0909718106	journal	November 2009
Luminescent Functional Metal–Organic Frameworks Cui, Yuanjing; Yue, Yanfeng; Qian, Guodong Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200101d	journal	June 2011
A luminescent nanoscale metal–organic framework for sensing of nitroaromatic explosives Xu, Hui; Liu, Fu; Cui, Yuanjing Chemical Communications, Vol. 47, Issue 11 https://doi.org/10.1039/c0cc05166g	journal	January 2011
Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework Wang, Zhenqiang; Cohen, Seth M. Journal of the American Chemical Society, Vol. 129, Issue 41, p. 12368-12369 https://doi.org/10.1021/ja074366o	journal	October 2007
Flexible Zirconium Metal-Organic Frameworks as Bioinspired Switchable Catalysts Yuan, Shuai; Zou, Lanfang; Li, Haixia Angewandte Chemie International Edition, Vol. 55, Issue 36 https://doi.org/10.1002/anie.201604313	journal	June 2016
Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic Core-Shell Single Crystals with an In-Plane Rotational Epitaxial Relationship Furukawa, Shuhei; Hirai, Kenji; Nakagawa, Keiji Angewandte Chemie International Edition, Vol. 48, Issue 10, p. 1766-1770 https://doi.org/10.1002/anie.200804836	journal	February 2009
A High-Performance Gas-Separation Membrane Containing Submicrometer-Sized Metal-Organic Framework Crystals Bae, Tae-Hyun; Lee, Jong Suk; Qiu, Wulin Angewandte Chemie, Vol. 122, Issue 51 https://doi.org/10.1002/ange.201006141	journal	November 2010
Introduction to Metal–Organic Frameworks Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M. Chemical Reviews, Vol. 112, Issue 2, p. 673-674 https://doi.org/10.1021/cr300014x	journal	September 2011
Core–Shell Structures Arise Naturally During Ligand Exchange in Metal–Organic Frameworks Boissonnault, Jake A.; Wong-Foy, Antek G.; Matzger, Adam J. Journal of the American Chemical Society, Vol. 139, Issue 42 https://doi.org/10.1021/jacs.7b08349	journal	October 2017
Nanoscale Metal–Organic Frameworks for Biomedical Imaging and Drug Delivery Della Rocca, Joseph; Liu, Demin; Lin, Wenbin Accounts of Chemical Research, Vol. 44, Issue 10, p. 957-968 https://doi.org/10.1021/ar200028a	journal	October 2011
Metal–organic frameworks as selectivity regulators for hydrogenation reactions Zhao, Meiting; Yuan, Kuo; Wang, Yun Nature, Vol. 539, Issue 7627 https://doi.org/10.1038/nature19763	journal	October 2016
Single-Crystal-to-Single-Crystal Metalation of a Metal–Organic Framework: A Route toward Structurally Well-Defined Catalysts Gonzalez, Miguel I.; Bloch, Eric D.; Mason, Jarad A. Inorganic Chemistry, Vol. 54, Issue 6 https://doi.org/10.1021/acs.inorgchem.5b00096	journal	February 2015
Interconversion between Molecular Polyhedra and Metal−Organic Frameworks Li, Jian-Rong; Timmons, Daren J.; Zhou, Hong-Cai Journal of the American Chemical Society, Vol. 131, Issue 18 https://doi.org/10.1021/ja901731z	journal	May 2009
Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic Core-Shell Single Crystals with an In-Plane Rotational Epitaxial Relationship Furukawa, Shuhei; Hirai, Kenji; Nakagawa, Keiji Angewandte Chemie, Vol. 121, Issue 10 https://doi.org/10.1002/ange.200804836	journal	February 2009
Thermodynamically Guided Synthesis of Mixed-Linker Zr-MOFs with Enhanced Tunability Yuan, Shuai; Qin, Jun-Sheng; Zou, Lanfang Journal of the American Chemical Society, Vol. 138, Issue 20 https://doi.org/10.1021/jacs.6b03263	journal	May 2016
Bipyridine- and Phenanthroline-Based Metal–Organic Frameworks for Highly Efficient and Tandem Catalytic Organic Transformations via Directed C–H Activation Manna, Kuntal; Zhang, Teng; Greene, Francis X. Journal of the American Chemical Society, Vol. 137, Issue 7 https://doi.org/10.1021/ja512478y	journal	February 2015
Design and synthesis of squaramide-based MOFs as efficient MOF-supported hydrogen-bonding organocatalysts Zhang, Xiaoping; Zhang, Zhenjie; Boissonnault, Jake Chemical Communications, Vol. 52, Issue 55 https://doi.org/10.1039/C6CC03190K	journal	January 2016
Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks Deng, H.; Doonan, C. J.; Furukawa, H. Science, Vol. 327, Issue 5967, p. 846-850 https://doi.org/10.1126/science.1181761	journal	February 2010
Deciphering the Spatial Arrangement of Metals and Correlation to Reactivity in Multivariate Metal–Organic Frameworks Liu, Qi; Cong, Hengjiang; Deng, Hexiang Journal of the American Chemical Society, Vol. 138, Issue 42 https://doi.org/10.1021/jacs.6b08724	journal	October 2016
Size-Controlled Synthesis of Porphyrinic Metal–Organic Framework and Functionalization for Targeted Photodynamic Therapy Park, Jihye; Jiang, Qin; Feng, Dawei Journal of the American Chemical Society, Vol. 138, Issue 10 https://doi.org/10.1021/jacs.6b00007	journal	March 2016
Electrocatalytically Active Graphene–Porphyrin MOF Composite for Oxygen Reduction Reaction Jahan, Maryam; Bao, Qiaoliang; Loh, Kian Ping Journal of the American Chemical Society, Vol. 134, Issue 15 https://doi.org/10.1021/ja211433h	journal	April 2012
Funktionale poröse Koordinationspolymere Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro Angewandte Chemie, Vol. 116, Issue 18 https://doi.org/10.1002/ange.200300610	journal	April 2004
Core–Shell Catalysts of Metal Nanoparticle Core and Metal–Organic Framework Shell Hu, Pan; Morabito, Joseph V.; Tsung, Chia-Kuang ACS Catalysis, Vol. 4, Issue 12 https://doi.org/10.1021/cs5012662	journal	November 2014
Proton Conduction with Metal-Organic Frameworks Shimizu, G. K. H.; Taylor, J. M.; Kim, S. Science, Vol. 341, Issue 6144 https://doi.org/10.1126/science.1239872	journal	July 2013
Luminescent Open Metal Sites within a Metal–Organic Framework for Sensing Small Molecules Chen, B.; Yang, Y.; Zapata, F. Advanced Materials, Vol. 19, Issue 13 https://doi.org/10.1002/adma.200601838	journal	July 2007
Postsynthetic modification of metal–organic frameworks Wang, Zhenqiang; Cohen, Seth M. Chemical Society Reviews, Vol. 38, Issue 5 https://doi.org/10.1039/b802258p	journal	January 2009
Hybrid porous solids past, present, future Férey, Gérard Chem. Soc. Rev., Vol. 37, Issue 1, p. 191-214 https://doi.org/10.1039/B618320B	journal	January 2008
The pervasive chemistry of metal–organic frameworks Long, Jeffrey R.; Yaghi, Omar M. Chemical Society Reviews, Vol. 38, Issue 5, p. 1213-1214 https://doi.org/10.1039/b903811f	journal	January 2009
De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities Farha, Omar K.; Özgür Yazaydın, A.; Eryazici, Ibrahim Nature Chemistry, Vol. 2, Issue 11, p. 944-948 https://doi.org/10.1038/nchem.834	journal	September 2010
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong Angewandte Chemie, Vol. 124, Issue 41, p. 10453-10456 https://doi.org/10.1002/ange.201204475	journal	August 2012
Metal–organic framework nanosheets in polymer composite materials for gas separation Rodenas, Tania; Luz, Ignacio; Prieto, Gonzalo Nature Materials, Vol. 14, Issue 1 https://doi.org/10.1038/nmat4113	journal	November 2014
Imparting functionality to a metal–organic framework material by controlled nanoparticle encapsulation Lu, Guang; Li, Shaozhou; Guo, Zhen Nature Chemistry, Vol. 4, Issue 4, p. 310-316 https://doi.org/10.1038/nchem.1272	journal	February 2012
Homochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis Yoon, Minyoung; Srirambalaji, Renganathan; Kim, Kimoon Chemical Reviews, Vol. 112, Issue 2, p. 1196-1231 https://doi.org/10.1021/cr2003147	journal	September 2011
N-rich zeolite-like metal–organic framework with sodalite topology: high CO2 uptake, selective gas adsorption and efficient drug delivery Qin, Jun-Sheng; Du, Dong-Ying; Li, Wen-Liang Chemical Science, Vol. 3, Issue 6 https://doi.org/10.1039/c2sc00017b	journal	January 2012
Functional Porous Coordination Polymers Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro Angewandte Chemie International Edition, Vol. 43, Issue 18, p. 2334-2375 https://doi.org/10.1002/anie.200300610	journal	April 2004
Design and synthesis of an exceptionally stable and highly porous metal-organic framework Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe Nature, Vol. 402, Issue 6759, p. 276-279 https://doi.org/10.1038/46248	journal	November 1999
Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites Stock, Norbert; Biswas, Shyam Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200304e	journal	September 2011
Asymmetric olefin epoxidation with sodium hypochlorite catalyzed by easily prepared chiral manganese(III) salen complexes Zhang, Wei; Jacobsen, Eric N. The Journal of Organic Chemistry, Vol. 56, Issue 7 https://doi.org/10.1021/jo00007a012	journal	March 1991
Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn₄O(1,4-benzenedicarboxylate)₃ (MOF-5) Kaye, Steven S.; Dailly, Anne; Yaghi, Omar M. Journal of the American Chemical Society, Vol. 129, Issue 46, p. 14176-14177 https://doi.org/10.1021/ja076877g	journal	November 2007
Design and Preparation of a Core–Shell Metal–Organic Framework for Selective CO ₂ Capture Li, Tao; Sullivan, Jeanne E.; Rosi, Nathaniel L. Journal of the American Chemical Society, Vol. 135, Issue 27 https://doi.org/10.1021/ja403008j	journal	June 2013
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong Angewandte Chemie International Edition, Vol. 51, Issue 41 https://doi.org/10.1002/anie.201204475	journal	August 2012
Anhydrous proton conduction at 150 °C in a crystalline metal–organic framework Hurd, Jeff A.; Vaidhyanathan, Ramanathan; Thangadurai, Venkataraman Nature Chemistry, Vol. 1, Issue 9 https://doi.org/10.1038/nchem.402	journal	October 2009
Metal–organic framework composites Zhu, Qi-Long; Xu, Qiang Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C3CS60472A	journal	January 2014
UTSA-74: A MOF-74 Isomer with Two Accessible Binding Sites per Metal Center for Highly Selective Gas Separation Luo, Feng; Yan, Changsheng; Dang, Lilong Journal of the American Chemical Society, Vol. 138, Issue 17 https://doi.org/10.1021/jacs.6b02030	journal	April 2016
Stepwise Synthesis of Robust Metal–Organic Frameworks via Postsynthetic Metathesis and Oxidation of Metal Nodes in a Single-Crystal to Single-Crystal Transformation Liu, Tian-Fu; Zou, Lanfang; Feng, Dawei Journal of the American Chemical Society, Vol. 136, Issue 22 https://doi.org/10.1021/ja5023283	journal	May 2014
Functional Porous Coordination Polymers Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro ChemInform, Vol. 35, Issue 29 https://doi.org/10.1002/chin.200429230	journal	July 2004
Nanoscale Metal–Organic Frameworks for Biomedical Imaging and Drug Delivery Wenbin, Lin,; Joseph, Della Rocca,; Demin, Liu, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/q7c0-kf53	text	January 2011
Proton Conduction with Metal-Organic Frameworks Shimizu, George; Taylor, Jm; Kim, S. Science https://doi.org/10.11575/prism/35415	null	January 2013

Cited By (21)

Fabrication of Metal–Organic Framework Thin Films Using Programmed Layer‐by‐Layer Assembly Techniques Wang, Zhengbang; Wöll, Christof Advanced Materials Technologies, Vol. 4, Issue 5 https://doi.org/10.1002/admt.201800413	journal	December 2018
Structural Engineering of Low‐Dimensional Metal–Organic Frameworks: Synthesis, Properties, and Applications Liu, Wenxian; Yin, Ruilian; Xu, Xilian Advanced Science, Vol. 6, Issue 12 https://doi.org/10.1002/advs.201802373	journal	April 2019
Heteroepitaxial Growth of Multiblock Ln‐MOF Microrods for Photonic Barcodes Yao, Yinan; Gao, Zhenhua; Lv, Yuanchao Angewandte Chemie, Vol. 131, Issue 39 https://doi.org/10.1002/ange.201907433	journal	July 2019
Atypical Hybrid Metal–Organic Frameworks (MOFs): A Combinative Process for MOF‐on‐MOF Growth, Etching, and Structure Transformation Lee, Sujeong; Oh, Sojin; Oh, Moonhyun Angewandte Chemie, Vol. 132, Issue 3 https://doi.org/10.1002/ange.201912986	journal	December 2019
Heteroepitaxial Growth of Multiblock Ln‐MOF Microrods for Photonic Barcodes Yao, Yinan; Gao, Zhenhua; Lv, Yuanchao Angewandte Chemie International Edition, Vol. 58, Issue 39 https://doi.org/10.1002/anie.201907433	journal	September 2019
Atypical Hybrid Metal–Organic Frameworks (MOFs): A Combinative Process for MOF‐on‐MOF Growth, Etching, and Structure Transformation Lee, Sujeong; Oh, Sojin; Oh, Moonhyun Angewandte Chemie International Edition, Vol. 59, Issue 3 https://doi.org/10.1002/anie.201912986	journal	December 2019
In Operando Analysis of Diffusion in Porous Metal‐Organic Framework Catalysts Gao, Wen‐Yang; Cardenal, Ashley D.; Wang, Chen‐Hao Chemistry – A European Journal, Vol. 25, Issue 14 https://doi.org/10.1002/chem.201804490	journal	December 2018
Computer-aided discovery of connected metal-organic frameworks Kwon, Ohmin; Kim, Jin Yeong; Park, Sungbin Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11629-4	journal	August 2019
Seaming the interfaces between topologically distinct metal–organic frameworks using random copolymer glues Wang, Fang; Wang, Hongliang; Li, Tao Nanoscale, Vol. 11, Issue 5 https://doi.org/10.1039/c8nr09777a	journal	January 2019
Shape control of core–shell MOF@MOF and derived MOF nanocages via ion modulation in a one-pot strategy Wu, Shenjie; Zhuang, Guoxin; Wei, Jinxin Journal of Materials Chemistry A, Vol. 6, Issue 37 https://doi.org/10.1039/c8ta06809g	journal	January 2018
Atomic-layer-deposition-formed sacrificial template for the construction of an MIL-53 shell to increase selectivity of hydrogenation reactions Xu, Tiantian; Sun, Kai; Gao, Daowei Chemical Communications, Vol. 55, Issue 53 https://doi.org/10.1039/c9cc02727k	journal	January 2019
Design and assembly of a chiral composite metal–organic framework for efficient asymmertric sequential transformation of alkenes to amino alcohols Xia, Qingchun; Yuan, Chen; Li, Yongxin Chemical Communications, Vol. 55, Issue 62 https://doi.org/10.1039/c9cc04131a	journal	January 2019
A unique coordination-driven route for the precise nanoassembly of metal sulfides on metal–organic frameworks Lin, Xiang-Yu; Li, Yue-Hua; Qi, Ming-Yu Nanoscale Horizons, Vol. 5, Issue 4 https://doi.org/10.1039/c9nh00769e	journal	January 2020
Bi-metal–organic frameworks type II heterostructures for enhanced photocatalytic styrene oxidation Liu, Lulu; Zhang, Lei; Wang, Feng Nanoscale, Vol. 11, Issue 16 https://doi.org/10.1039/c9nr00790c	journal	January 2019
Recent advances in MOF-based photocatalysis: environmental remediation under visible light Wang, Qi; Gao, Qiaoyuan; Al-Enizi, Abdullah M. Inorganic Chemistry Frontiers, Vol. 7, Issue 2 https://doi.org/10.1039/c9qi01120j	journal	January 2020
Uncovering two kinetic factors in the controlled growth of topologically distinct core–shell metal–organic frameworks Wang, Fang; He, Sanfeng; Wang, Hongliang Chemical Science, Vol. 10, Issue 33 https://doi.org/10.1039/c9sc02576f	journal	January 2019
The synthesis and electrochemical applications of core–shell MOFs and their derivatives Zhao, Zhimin; Ding, Jiawei; Zhu, Rongmei Journal of Materials Chemistry A, Vol. 7, Issue 26 https://doi.org/10.1039/c9ta03833g	journal	January 2019
Core–shell metal–macrocycle framework (MMF): spatially selective dye inclusion through core-to-shell anisotropic transport along crystalline 1D-channels connected by epitaxial growth Tashiro, Shohei; Mitsui, Shinya; Burke, David W. CrystEngComm, Vol. 22, Issue 8 https://doi.org/10.1039/d0ce00120a	journal	January 2020
Reversible lithium storage in a porphyrin-based MOF (PCN-600) with exceptionally high capacity and stability Sun, Lin; Xie, Jie; Chen, Zhidong Dalton Transactions, Vol. 47, Issue 30 https://doi.org/10.1039/c8dt02161a	journal	January 2018
Unveiling the mechanism of lattice-mismatched crystal growth of a core–shell metal–organic framework Pambudi, Fajar I.; Anderson, Michael W.; Attfield, Martin P. Chemical Science, Vol. 10, Issue 41 https://doi.org/10.1039/c9sc03131f	journal	January 2019
Hierarchy in Metal–Organic Frameworks Feng, Liang; Wang, Kun-Yu; Willman, Jeremy ACS Central Science, Vol. 6, Issue 3 https://doi.org/10.1021/acscentsci.0c00158	journal	March 2020

Similar Records

One‐Step Synthesis of Hybrid Core–Shell Metal–Organic Frameworks

Journal Article · Mon Mar 12 00:00:00 EDT 2018 · Angewandte Chemie · OSTI ID:1470334

Yang, Xinyu; Yuan, Shuai; Zou, Lanfang; +5 more

Computational screening, synthesis and testing of metal–organic frameworks with a bithiazole linker for carbon dioxide capture and its green conversion into cyclic carbonates

Journal Article · Tue Jul 02 00:00:00 EDT 2019 · Molecular Systems Design & Engineering · OSTI ID:1470334

Müller, Philipp; Bucior, Benjamin; Tuci, Giulia; +6 more

Construction of hierarchically porous metal–organic frameworks through linker labilization

Journal Article · Thu May 25 00:00:00 EDT 2017 · Nature Communications · OSTI ID:1470334

Yuan, Shuai; Zou, Lanfang; Qin, Jun-Sheng; +8 more

Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
core–shell MOFs
nucleation kinetics
olefin epoxidation
size-selective catalyst

Title: One-Step Synthesis of Hybrid Core-Shell Metal-Organic Frameworks

Citation Formats

References (69)

Cited By (21)

Similar Records

Related Subjects